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Hematite solid spindles and hollow spindles have been selectively synthesized by a template-free, economical hydrothermal method, using FeCl3·6H2O as the starting materials and NaOH as the homogeneous precipitant. XRD analyses indicated that the products consisted of α-Fe2O3. SEM and TEM measurements showed that the morphologies of products were in the shape of solid spindles and hollow spindles, respectively. A possible formation process based on the nucleation-oriented aggregation-recrystallization mechanism is proposed. Moreover, the as-prepared hollow spindle-like α-Fe2O3 exhibits a good response and reversibility to some organic gas, such as 2-propanol and acetone. Compared with other hematite nanostructures, the porous hollow hematite spindles show outstanding performance in gas sensing due to their large surface area and porous hollow structure. Because of the unique porous hollow structures of the samples, the photocatalytic property of the spindle-like α-Fe2O3 was also investigated. 相似文献
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随着我国高等教育走向大众化,人才培养目标发生了根本性的变革.传统的学生学习质量观及评价方式与标准,已不利于具有竞争力的创新型人才的培养.因此,高校应该借鉴国外的成功经验,建立以市场为导向、以人的知识、能力,素质协调发展为目标的新型学生学习质量观及相应的学习效果评价体系与标准,推动应用型人才的培养. 相似文献
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Chen Xiuqing Ma Kai Geng Deqin Zhai Jingxuan Liu Wei Zhang Hongwei Zhu Tingting Piao Xue 《Wireless Personal Communications》2019,109(3):1747-1767
Wireless Personal Communications - In order to support robust implementation of IoT, many schemes have been done to provide privacy, anonymity, scalability and customizability. Ray et al.’s... 相似文献
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Xuqiu Yang Lisheng Liu Qingjie Zhang Pengcheng Zhai 《Journal of Electronic Materials》2011,40(5):489-492
Molecular dynamics simulations of the structural and mechanical properties of single-crystalline CoSb3 have been carried out at room temperature. Special emphasis was given to the surface effect. Four different boundary conditions were applied to represent a wide range of surface-atom fractions. The LAMMPS program in conjunction with a multibody potential was employed. First, free relaxation was performed to obtain the corresponding stable configurations. The atomic rearrangements and energy distributions were observed. Then, uniaxial tensile deformation was simulated at a constant strain rate. The stress–strain responses and structural evolutions were examined during the process. Comparison of simulation results between different boundary conditions was carefully made. It was found that, when the scale of the single-crystalline CoSb3 model becomes nanometric and the fraction of the surface atoms increases, the mechanical performance becomes substantially worse. Nonetheless, the deformation mechanism and intrinsic mechanical nature are very similar. 相似文献
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Improving Transport Layer Performance in Multihop Ad Hoc Networks by Exploiting MAC Layer Information 总被引:2,自引:0,他引:2
The traditional TCP congestion control mechanism encounters a number of new problems and suffers a poor performance when the IEEE 802.11 MAC protocol is used in multihop ad hoc networks. Many of the problems result from medium contention at the MAC layer. In this paper, we first illustrate that severe medium contention and congestion are intimately coupled, and TCP's congestion control algorithm becomes too coarse in its granularity, causing throughput instability and excessively long delay. Further, we illustrate TCP's severe unfairness problem due to the medium contention and the tradeoff between aggregate throughput and fairness. Then, based on the novel use of channel busyness ratio, a more accurate metric to characterize the network utilization and congestion status, we propose a new wireless congestion control protocol (WCCP) to efficiently and fairly support the transport service in multihop ad hoc networks. In this protocol, each forwarding node along a traffic flow exercises the inter-node and intra-node fair resource allocation and determines the MAC layer feedback accordingly. The end-to-end feedback, which is ultimately determined by the bottleneck node along the flow, is carried back to the source to control its sending rate. Extensive simulations show that WCCP significantly outperforms traditional TCP in terms of channel utilization, delay, and fairness, and eliminates the starvation problem 相似文献
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采用磁控溅射法,以Si粉和溅金Si(111)为原料,加入C粉,在Si(111)衬底上制备无定形SiO2纳米线。首先,在Si(111)衬底上分别溅射厚度为18和36 nm的Au。然后,在1 100℃条件下处理80 min。用扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、傅里叶红外光谱(FTIR)和X射线衍射方法 (XRD)等测试手段对退火后的SiO2纳米线的表面相貌、微观结构进行分析。结果表明,反应后有大量长而直的SiO2纳米线生成。而且随着溅射Au厚度的增加,SiO2纳米线的数量增多,且长度更长。这表明,SiO2纳米线的生长与溅射Au的厚度密切相关。 相似文献
20.
Yang Cao Qing Zhang Yaqing Wei Yanpeng Guo Zewen Zhang William Huang Kaiwei Yang Weihua Chen Tianyou Zhai Huiqiao Li Yi Cui 《Advanced functional materials》2020,30(7)
Layered transition metal (TM) oxides of the stoichiometry NaxMO2 (M = TM) have shown great promise in sodium‐ion batteries (SIBs); however, they are extremely sensitive to moisture. To date, most reported titanium‐based layered anodes exhibit a P2‐type structure. In contrast, O3‐type compounds are rarely investigated and their synthesis is challenging due to their higher percentage of unstable Ti3+ than the P2 type. Here, a pure phase and highly crystalline O3‐type Na0.73Li0.36Ti0.73O2 with high performance is successfully proposed in SIBs. This material delivers a reversible capacity of 108 mAh g?1 with a stable and safe potential of 0.75 V versus Na/Na+. In situ X‐ray diffraction reveals that this material does not undergo any phase transitions and exhibits a near‐zero volume change upon Na+ insertion/de‐insertion, which ensures exceptional long cycle life over 6000 cycles. Importantly, it is found that this O3‐Na0.73Li0.36Ti0.73O2 shows superior moisture stability, even when immersed into water, which are both elusive for conventional layered TM oxides in SIBs. It is believed that the small interlayer distance and high occupation of interlayer vacancy promise such unprecedented water stability. 相似文献