Hydrogen absorption in Pd thin-films

Hydrogen absorption isotherms for Pd thin films were modeled at atomistic scale by Monte Carlo (MC) simulation in the TPμN ensamble and by Molecular Dynamics (MD) simulations at 300 K. The interaction among atoms was modeled by embedded atom method (EAM) potentials. Simulated samples consisted of monocrystalline nanofilms with different thickness (2–8 nm) and two crystallographic surface orientations, (001) and (111). The isotherms were compared to bulk Pd and a few available experimental results. Instead of the plateau corresponding to the α-β PdH equilibrium in the bulk, the isotherms at nano-films show a two-plateaux behavior: a small one corresponding to a surface–subsurface hydride formation, and a larger one for the subsequent bulk hydride formation. This is strongly correlated with the atomic stress distribution induced within the thin film. The equilibrium pressures at the isotherms depend on the thin-film thickness, with pressure being larger for thicker films. The isotherms of the (001) films display lower equilibrium pressures than those for (111) films.     

Partial Characterization of Ultrafiltrated Soy Protein Hydrolysates with Antioxidant and Free Radical Scavenging Activities

Soy protein isolate (SPI) was hydrolyzed with Flavourzyme® (SHF) or chymotrypsin (SHC). Hydrolysates were sequencially fractionated by ultrafiltration using different membrane pore sizes (50, 10, and 3 kDa). The antioxidant ability of each hydrolysate protein fraction was tested in a liposome oxidizing system and their free radical scavenging activity (FRSA) was evaluated with the DPPH method (diphenylpicrilhydrazine radical). Molecular weight (MW) distribution, solubility, surface hydrophobicity, and amino acid composition of each SPI hydrolysate fraction were measured and their effect on antioxidant and scavenging activities was established by multivariate correlation. The most active ultrafiltrated peptide fractions (P < 0.05), from SHF and SHC, had of MW of <3 kDa (F3 and C3, respectively). These fractions decreased liposome oxidation by 83.2% and 84.5%, respectively, and also showed the highest FRSA (F3: 21.3% and C3: 24.4%). In addition to molecular size, the antioxidant activity and FRSA of soy protein fractions were related to their amino acid composition, especially to an increased content of Phe and a lowered content of Lys. Also, hydrophobicity of ultrafiltrated peptide fractions was an important characteristic (P < 0.001) associated with their ability to trap free radicals. Ultrafiltered peptide fractions with low MW have a high potential to be used as natural alternatives to prevent lipid oxidation in foods.     

Classified JPEG coding of mixed document images for printing

This paper presents a modified JPEG coder that is applied to the compression of mixed documents (containing text, natural images, and graphics) for printing purposes. The modified JPEG coder proposed in this paper takes advantage of the distinct perceptually significant regions in these documents to achieve higher perceptual quality than the standard JPEG coder. The region-adaptivity is performed via classified thresholding being totally compliant with the baseline standard. A computationally efficient classification algorithm is presented, and the improved performance of the classified JPEG coder is verified.     

Spanish and European innovation diffusion: a structural hole approach in the input–output field

Input–output analysis is a powerful tool for in-depth study of the productive structure of economic space. Moreover, the sectoral network constitutes one of the possible determinants of the innovative capacity of a territory. The use of network theory in the input–output field supposes an interesting alternative that allows structural complexity, weakness and strength to be shown. Following this viewpoint, we analyse the relative position of each sector via the structural holes concept (Burt in Structural Holes, Cambridge University Press, Cambridge, 1992; Social Capital: Theory and Research. Aldine de Gruyter, New York, 2001; Am J Sociol 110:349–399, 2004) to offer an approach to knowledge generation and diffusion capacity within the economic network. The theoretical background is based on the opportunities afforded due to connexion with and proximity to sectoral structure for knowledge transmission and consequently innovation capacity. This novel proposal is applied to the analysis of European and Spanish economies in 1995.     

Oxidative status, in vitro iron-induced lipid oxidation and superoxide dismutase,catalase and glutathione peroxidase activities in rhea meat

Rhea (Rhea americana) muscles Obturatorius medialis (OM) Iliotibialis lateralis (IL) and Iliofibularis (I), obtained from farmed animals, were evaluated regarding their oxidative/antioxidant status. The mean level of thiobarbituric acid reactive substances (TBARS) expressed as malonaldehyde (MDA) content was of 0.84 mg MDA/kg wet tissue for the three muscles. TBARS level was significantly higher in IL than OM and I, with the two latter showing similar levels. The mean level of carbonyl proteins expressed as dinitrophenylhydrazine (DNPH) was 1.59 nmol DNPH mg⁻¹. Carbonyl protein levels were significantly different (P < 0.05) between the three muscles (IL > OM > I). Iron-induced TBARS generation was not significantly different between the three muscles at any time, nor for each muscle during the 5 h of the experiment. Superoxide dismutase activity in IL muscle was significantly higher (P < 0.05) than in I muscle. However, the difference between IL and OM muscles was not significant. The differences between the three muscles became not significant when the results were expressed by mg of protein contained in the extract, instead by g of wet tissue. No differences were found for catalase (μmol of discomposed H₂O₂ min⁻¹ g⁻¹ wet tissue or by mg of protein contained in the extract) and glutathione peroxidase (μmol of oxidized NADPH min⁻¹ g⁻¹ of wet tissue or by mg of protein contained in the extract) activities between the three muscles.     

Combining probabilistic algorithms, Constraint Programming and Lagrangian Relaxation to solve the Vehicle Routing Problem

This paper presents an original hybrid approach to solve the Capacitated Vehicle Routing Problem (CVRP). The approach combines a Probabilistic Algorithm with Constraint Programming (CP) and Lagrangian Relaxation (LR). After introducing the CVRP and reviewing the existing literature on the topic, the paper proposes an approach based on a probabilistic Variable Neighbourhood Search (VNS) algorithm. Given a CVRP instance, this algorithm uses a randomized version of the classical Clarke and Wright Savings constructive heuristic to generate a starting solution. This starting solution is then improved through a local search process which combines: (a) LR to optimise each individual route, and (b) CP to quickly verify the feasibility of new proposed solutions. The efficiency of our approach is analysed after testing some well-known CVRP benchmarks. Benefits of our hybrid approach over already existing approaches are also discussed. In particular, the potential flexibility of our methodology is highlighted.     

Reducing channel change delay in IPTV by predictive pre-joining of TV channels

One of the major concerns of IPTV network deployment is channel change delay (also known as zapping delay). This delay can add up to 2 s or more, and its main culprits are synchronisation and buffering of the media streams. Proving the importance of the problem is the already significant amount of literature addressing it. We start this paper with a survey of techniques proposed to reduce IPTV channel change delay.Then, by analysing an extensive dataset from an operational IPTV provider - comprising 255 thousand users, 150 TV channels, and covering a 6-month period - we have observed that most channel switching events are relatively predictable: users very frequently switch linearly, up or down to the next TV channel. This fact motivated us to use this dataset to analyse in detail a specific type of solutions to this problem, namely, predictive pre-joining of TV channels. In these schemes each set top box (STB) simultaneously joins additional multicast groups (TV channels) along with the one that is requested by the user. If the user switches to any of these channels the switching latency is virtually eliminated, not affecting therefore user's experience.We start by evaluating a simple scheme, where the neighbouring channels (i.e., channels adjacent to the requested one) are pre-joined by the STB during zapping periods. Notwithstanding the simplicity of this scheme, trace-driven simulations show that the zapping delay can be virtually eliminated for a significant percentage of channel switching requests. For example, when sending the previous and the next channel concurrently with the requested one, for only 1 min after a zapping event, switching delay is eliminated for close to half of all channel switching requests. Importantly, this result is achieved with a negligible increase of bandwidth utilisation in the access link. Other more complex schemes where user behaviour is tracked were also evaluated, but the improvement over the simple scheme was insignificant.     

A randomized, controlled trial of a behavioral intervention to prevent sexually transmitted disease among minority women

Using annual bite-wing radiographs, the incidence and progression of approximal caries (4d-7m) were assessed longitudinally in teenagers and adolescents whose treatment had been based on remineralizing rather than restorative strategies. A closed cohort of 536 children initially was followed from 11 to 22 years of age. The scoring system was: 0 = no visible radiolucency; 1-2 = radiolucency in the enamel up to the enamel-dentin border; 3 = radiolucency with a broken enamel-dentin border but with no obvious progression in the dentin; 4 = radiolucency with obvious spread in the outer half of the dentin, and 5 = radiolucency in the inner half of the dentin. Caries rates were estimated as the number of new lesions/100 tooth surface-years, and the Kaplan-Meier estimate was used to calculate the cumulative survival time of each approximal surface. Three events were used: the transitions from states 0 to 2, 2 to 4 and 3 to 4. The results showed a considerable variation between the surfaces in both caries rates and survival time. For all surfaces combined, the median caries rate from state 0 to 2 was 3.9 new lesions/100 tooth surface-years; from state 2 to 4, the rate was 5.4, and from state 3 to 4 it was 20.3. Of the sound surfaces (state 0), 75% survived 6.3 years without reaching state 2. Given state 2, 75% survived 4.8 years without reaching the outer half of the dentin (state 4), while given a lesion at the enamel-dentin border (state 3), 75% survived 1.3 years without doing the same. The median survival time of lesions from state 3 to 4 was 3.1 years. The group with DMFSappr>1 at the age of 11-12 years had a risk of new approximal enamel lesions (state 0-2) that was 2.5 times greater than that of the group with DMFSappr = 0-1.