Application of organic photovoltaic cell: poly(2-aminofluoren)/multi-walled carbon nanotube composites

Journal of Materials Science: Materials in Electronics - This work presents the 2-aminofluorene polymer matrix based on the multi-walled carbon nanotube module for an alternative energy conversion...     

Synergistic and selective extraction of Cd2+ from acidic solution containing Cd2+, Co2+, Ni2+ by triisooctylamine (TIOA) and tributyl phosphate (TBP)

Selective and synergistic extraction of cadmium from acidic iodine solutions containing Cd²⁺, Co²⁺ and Ni²⁺using solvent extraction (SX) technique is presented in this study. The study has highlighted the importance of main and synergistic extractants composition. The mixtures have evident synergistic effects on Cd²⁺ with a synergistic enhancement factor of 2.22. The various experimental parameters were studied to determine the optimum extraction and stripping conditions of Cd²⁺. Under optimum conditions, the maximum extraction efficiency (99.7%) was achieved when using 1.5% (v/v) TIOA and 0.5% (v/v) TBP in dichloromethane within 5 min. Extracted Cd²⁺ was stripped effectively from the organic phase using 2.0 mol/L NaOH solution.     

Investigation on colour,fastness properties and HPLC‐DAD analysis of silk fibres dyed with Rubia tinctorium L. and Quercus ithaburensis Decaisne

Silk fabric samples were dyed according to the various procedures using madder (Rubia tinctorium L.) and walloon oak (Quercus ithaburensis Decaisne) extracts. The colour coordinates, K/S, as well as wash, light, rub and perspiration fastness values were determined. A reversed‐phase high‐performance liquid chromatography with diode‐array detection was utilised for the identification of the components of dyes present in the dyed fabrics and in the plant extracts.     

Graphene reknits its holes

Nanoholes, etched under an electron beam at room temperature in single-layer graphene sheets as a result of their interaction with metal impurities, are shown to heal spontaneously by filling up with either nonhexagon, graphene-like, or perfect hexagon 2D structures. Scanning transmission electron microscopy was employed to capture the healing process and study atom-by-atom the regrown structure. A combination of these nanoscale etching and reknitting processes could lead to new graphene tailoring approaches.     

Determination of transmission factors of concretes with different water/cement ratio,curing condition,and dosage of cement and air entraining agent

This study focuses on determination of transmission factors of main parameters affecting the properties of both normal- and heavy-weight concrete in order to increase knowledge and understanding of radiation attenuation in concrete at a later age. Water/cement (W/C) ratio, curing condition, cement quantity and air entraining agent (AEA) were selected as the main parameters. Eight energy values have been selected within the energy interval of 30.85–383.85 keV to be used in the radiation source. The Taguchi Method was used as the method of optimization. It was determined in the study that the most important parameter affecting the attenuation of the radiation of the concrete is the W/C ratio and the concretes produced with the lowest level of W/C ratio absorb more radiation. However, it was also determined that there was a combined effect between the W/C ratio and the cement dosage.     

A spatial multicriteria decision-making method for natural gas transmission pipeline routing

In accordance with current demands, the natural gas transmission pipeline (NGTP) is one of the most appropriate methods used in the distribution of existing reserves. Construction of long-distance pipelines requires large expenditures. Decreasing the time and cost of such construction and minimising environmental damage depend upon identifying the optimum routes from the onset of the project. Route determination is one of the most important steps in NGTP projects. The route determination process requires obtaining the existing graphic and non-graphic data from different institutions and organisations, as well as gathering, storing, querying and analysing non-existing data in an appropriate and efficient manner. Accessing the correct results rapidly by analysing such large data-sets can be achieved with spatial multicriteria decision-making technologies based on the geographic information system as an effective decision support tool. In this study, three methods were implemented for two NGTP projects of 103.60 and 60.89 km in length. At the end of this study, it was concluded that Spatial technique for order preference by similarity to ideal solution was the most effective of the three pipeline routing methods and that it could reduce project costs by approximately 21%.     

Chiral recognition of proteins having L-histidine residues on the surface with lanthanide ion complex incorporated-molecularly imprinted fluorescent nanoparticles

In this study, lanthanide ion complex incorporated molecularly imprinted fluorescent nanoparticles were synthesized. A combination of three novel approaches was applied for the purpose. First, lanthanide ions [Terbium(III)] were complexed with N-methacryloyl-L-histidine (MAH), polymerizable derivative of L-histidine amino acid, in order to incorporate the complex directly into the polymeric backbone. At the second stage, L-histidine molecules imprinted nanoparticles were utilized instead of whole protein imprinting in order to avoid whole drawbacks such as fragility, complexity, denaturation tendency, and conformation dependency. At the third stage following the first two steps mentioned above, imprinted L-histidine was coordinated with cupric ions [Cu(II)] to conduct the study under mild conditions. Then, molecularly imprinted fluorescent nanoparticles synthesized were used for L-histidine adsorption from aqueous solution to optimize conditions for adsorption and fluorimetric detection. Finally, usability of nanoparticles was investigated for chiral biorecognition using stereoisomer, D-histidine, racemic mixture, D,L-histidine, proteins with surface L-histidine residue, lysozyme, cytochrome C, or without ribonuclease A. The results revealed that the proposed polymerization strategy could make significant contribution to the solution of chronic problems of fluorescent component introduction into polymers. Additionally, the fluorescent nanoparticles reported here could be used for selective separation and fluorescent monitoring purposes.     

Rule-based automatic segmentation of color images

A rule-based segmentation algorithm for color images has been presented in this paper. The proposed strategy is similar to region growing algorithm where the seed points are automatically selected and grown. The similarity percents of neighboring pixels are calculated by means of fuzzy reasoning rules, and the merging of the pixels with regions is performed by comparing the similarity percent with the similarity threshold value. The algorithm does not require any prior knowledge of the number of regions existing in the image and decreases the computational load required for the fuzzy c-means (FCM). Several computer simulations have been performed and the results have been discussed. The simulation results indicate that the proposed algorithm yields segmented color image of perfect accuracy.     

A numerical study of the influence of bump type triggers on the axial crushing of top hat thin-walled sections

This paper deals with the issue of a trigger design and its performance. In this respect, a numerical investigation is carried out to study the effects of the geometrical features of a bump type trigger on the crush behavior of an energy absorbing member subjected to axial impact loading. The member was constructed by joining a top hat profile with a flat lid. The trigger was considered to be a bump with a semi-circular cross section on the hat profile. The finite element solver, LS-DYNA was used in all crush simulations. As a result, the introduction of the trigger was found to be effective on the peak crush force and the energy absorption capability of the member under axial impact loading. It was also shown that the crush response could be controlled by varying the location and the geometry of the trigger.