硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

Hydrothermal products of the C3MS2-C12A7-MgO system

The autoclave products of reduced steel-slag of an electronic furnace mainly containing C₃MS₂ phase were detected. The hydrothermal products of this slag included calcio-chondrodite, brucite, and hydrogarnet phases. When suitable (CaO + MgO)/SiO₂ molar ratios were chosen, C₃MS₂ can react with SiO₂ to produce calcium silicate hydrates tobermorite, xonotlite, gyrolite, and truscottite phases with different saturated water vapor pressures. The phase brucite was present along with tobermorite, whereas phases Mg-xonotlite, Mg-gyrolite, and Mg-truscottite can rarely coexist with brucite. Hydrogarnet phase disappeared when Mg-truscottite was formed.     

聚丙烯结构壁管专用料的开发

阐述了塑料结构壁管的基本情况和国内外现状．重点就扬子石油化工股份有限公司研究院研制的聚丙烯结构壁管专用料的情况进行了介绍。     

15%田草灵高效液相色谱分析

采用Ｎｏｖａ－Ｐａｋ Ｃ１８不锈钢色谱柱进行反相液相色谱分析，以甲醇：水＝６５：３５（Ｖ／Ｖ）为注动相，以邻苯二甲醇二乙酯为内标物，用内标法测定田草灵除草剂中苄嘧黄隆和异丙甲草胺的含量，结果表明，各有效成分与内标物色谱峰分离完全，杂质无干扰，测定结果，苄嘧黄隆和异丙甲草胺的变异系数分别为０．７４％和１．０７％，回收率分别为９９．４％￣１００．８％和９９．１％￣１０１．３％。     

Multi-label core vector machine with a zero label

Multi-label core vector machine (Rank-CVM) is an efficient and effective algorithm for multi-label classification. But there still exist two aspects to be improved: reducing training and testing computational costs further, and detecting relevant labels effectively. In this paper, we extend Rank-CVM via adding a zero label to construct its variant with a zero label, i.e., Rank-CVMz, which is formulated as the same quadratic programming form with a unit simplex constraint and non-negative ones as Rank-CVM, and then is solved by Frank–Wolfe method efficiently. Attractively, our Rank-CVMz has fewer variables to be solved than Rank-CVM, which speeds up training procedure dramatically. Further, the relevant labels are effectively detected by the zero label. Experimental results on 12 benchmark data sets demonstrate that our method achieves a competitive performance, compared with six existing multi-label algorithms according to six indicative instance-based measures. Moreover, on the average, our Rank-CVMz runs 83 times faster and has slightly fewer support vectors than its origin Rank-CVM.     

Dynamic response of Ti3SiC2 under shock compression up to 112 GPa

Ti₃SiC₂ is of interest due to its unique dual nature reminiscent of both brittle ceramics and ductile metals at ambient conditions. In this work, plate-impact experiments have been performed to study the dynamic behavior of Ti₃SiC₂ under shock compression up to 112 GPa by using laser velocity interferometer and electric pin techniques. Hugoniot elastic limits (HEL), spall strength, and Hugoniot equations of state have been obtained based on measured particle velocity profiles and shock wave velocities. The ratio of spall strength to HEL for Ti₃SiC₂ is larger than brittle ceramics but smaller than metals. This result indicates that the dual nature of Ti₃SiC₂ remains at least up to 10 GPa. On the other hand, the linearity of the Hugoniot equation of state, $D=6.9\text{0}1(22)+1.153(53)u_{\text{p}}$, suggests that the initial structure of Ti₃SiC₂ should be stable up to 112 GPa, in contrast to the result reported by Jordan et al. [J. Appl. Phys., 93 (2003) 9639].     

Synthesis of carbon nanocapsules containing Fe, Ni or Co by arc discharge in aqueous solution

A simple, inexpensive and one-step synthesis method of metal-containing carbon nanocapsules using an arc discharge in aqueous solution is reported. It was found that Ni, Co and Fe nanoparticles could be in situ encapsulated in carbon shells when the arc was performed respectively in aqueous solutions of NiSO₄, CoSO₄ and FeSO₄. Transmission electron microscopy, energy dispersive X-ray spectroscopy and electron diffraction patterns of selected areas were used to determine the crystalline phase of the metal cores. To explain the formation mechanism of metal-containing carbon nanocapsules, a model of discharge in solution is proposed. This result presents a simply controllable way to synthesize metal-containing carbon nanocapsules.