Synthesis,characterization, and redox and electrochromic behaviors of poly(3-n-octyloxythiophene)

Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

白云鄂博主矿开拓运输工艺转换有关问题的探讨

本文对白云鄂博主矿采场铁公路联合运输向公路运输转换位置是否确定为1638m水平以及运输工艺转换过程中相关问题进行分析论证，提出主矿采场铁路至少可向下延深一个水平，技术上可行，节约运费千万元以上。     

Preparation and Characterization of Carboxymethyl Chitosan and β-Cyclodextrin Microspheres by Spray Drying

Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios.     

星型聚合物中间体环硅氧烷核的合成研究

以甲基二氯硅烷、四甲基四乙烯基环四硅氧烷(DVi4)为原料,采用硅氢加成反应合成了星型聚合物的中问体环硅氧烷核,并用红外光谱和核磁共振谱进行了表征.反应的最佳条件是:采用预先活化、反应温度72℃、催化荆与DVi4的量之比为1.0×10-4,反应转化率可达95%,且选择性很好,产物主要为β-加成产物.     

云台山隧道进口黄土段施工技术

从防排水、边仰坡支护、洞口加固、洞内超前支护、钢拱架锚喷联合支护等方面详细介绍了云台山隧道进口黄土段的施工技术,总结了该隧道的施工效果,强调了黄土隧道施工中防排水超前支护预注浆、施工监控的作用,积累了隧道施工经验.     

东丽湖邻里中心

在承接这个项目之前，我们不知道天津东部还有东丽湖这么一大片保存完好的湿地，夕阳映照着辽阔的水面，芦苇中闪现着轻盈的水鸟。邻里中心——作为这片宝地旁边200hm^2大型低密度社区第一个登台亮相的小组团，对参与其中的所有人来说，既有动人的诱惑，又有切实的压力。     

10MeV中子引起的~（238）U，~（209）Bi，Fe和~9Be的次级中子

１０ＭｅＶ中子引起的￣（２３８）Ｕ，￣（２０９）Ｂｉ，Ｆｅ和￣９Ｂｅ的次级中子双微分截面测量祁步嘉，唐洪庆，周祖英，周陈维，沈冠仁，柯尊建，孙振强，夏海鸿（中国原子能科学研究院核物理所，北京２７５－４６信箱，１０２４１３）次级中子双微分截面是核工程设...     

Generating topological structures for surface models

Rapid prototyping has imposed new requirements on the processing of CAD models. To manufacture an object directly, the model must correspond to a real object and thus represent a closed volume. Its boundary must be continuous and closed, and no cracks or improper intersections are allowed. CAD models cannot always meet these requirements, especially when they are constructed by a surface modeler. The algorithm discussed analyzes surface models and generates a topological structure for them that meets rapid prototyping requirements for a closed volume with a continuous, closed boundary