Physical and mechanical properties of a poly-3-hydroxybutyrate-coated nanocrystalline hydroxyapatite scaffold for bone tissue engineering

A major challenge for tissue engineers is the design of scaffolds with appropriate physical and mechanical properties. The present research discusses the formation of ceramic scaffolding in tissue engineering. Hydroxyapatite (HAp) powder was made from bovine bone by thermal treatment at 900?°C; 40, 50 and 60%wt porous HAp was then produced using the polyurethane sponge replication method. Scaffolds were coated with poly-3-hydroxybutyrate (P3HB) for 30?s and 1?min in order to increase the scaffold??s mechanical properties. XRD, SEM and FT-IR were used to study phase structure, morphology and agent groups, respectively. In XRD and FT-IR data, established hydrogen bands between polymer and ceramic matrix confirm that the scaffold is formed as a composite. The scaffold obtained with 50%wt HAp and a 30?s coating was 90% porous, with an average diameter of 100?C400???m, and demonstrated a compressive strength and modulus of 1.46 and 21.27?MPa, respectively. Based on these results, this scaffold is optimised for the aforementioned properties and can be utilised in bone tissue engineering.     

Robust Diversity-based Sine-Cosine Algorithm for Optimizing Hydropower Multi-reservoir Systems

Hydropower energy generation depends on the available water resources. Therefore, planning and operation of the water resource systems are paramount tasks for energy management. Since reservoirs are one of the important components of water resources systems, extracting optimal operating policies for proper management of energy generated from these systems is an imperative step. Optimizing reservoir system operation (ORSO) is a non-linear, large-scale, and non-convex problem with a large number of constraints and decision variables. To solve ORSO problem effectively, a robust diversity-based, sine-cosine algorithm (RDB-SCA) is developed in the present study by introducing several strategies to balance the global exploration and local exploitation ability and to achieve accurate and reliable solutions. An efficient linear operation rule is coupled with the RDB-SCA to maximize the energy generation. The proposed method is then applied to a real-world, multi-reservoir system to extract optimal operational policies and, consequently, maximize the energy production. It is shown that the RDB-SCA is able to generate 24, 14, and 6% more energy than the original SCA, respectively for 2-, 3-, and 4-reservoir systems. The present findings are useful to suggest guidelines for efficient operation of hydropower multi-reservoir systems. This paper is supported by https://imanahmadianfar.com/codes.

     

Modification of poly(propylene) by grafted polyester‐amide‐based dendritic nanostructures with the aim of improving its dyeability

Fiber‐graded poly(propylene) was modified by polyester‐amide‐based dendritic nanostructures with the aim of improving its dyeability. Two different dendritic polymers were used and the dendritic nanostructures were formed in situ via reactive blending with maleic anhydride‐modified poly(propylene). Samples were chosen exploiting a 4‐component mixture design. Thermal, morphological, and rheological characterizations showed domains with different size and distribution were formed and primary properties of the dendritics determined the characteristics of the resulted domains. Morphological parameters were quantified by digital analysis of scanning electron microscope images. Thermal and rheological behavior also demonstrated good agreements with the inferred morphology of the formed dendritic domains. The modified samples were then dyed with dispersed dyestuffs. A variety of substantivities were obtained, and some of the modified samples showed a significant enhancement in dyeing properties. A predictive model was developed for K/S ratio, where K and S are absorption and scattering coefficients of the Kubelka‐Munk one constant theory, respectively. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Topology optimization of transient problem with maximum dynamic response constraint using SOAR scheme

Frontiers of Mechanical Engineering - This paper proposes a novel method for the continuum topology optimization of transient vibration problem with maximum dynamic response constraint. An...     

Synthesis of graphene-supported bimetallic nanoparticles for the sunlight photodegradation of Basic Green 5 dye in aqueous medium

Graphene nanosheets-supported Sn-Pt bimetallic nanoparticles (GNs/Sn-Pt) were prepared by precipitation method. The obtained GNs/Sn-Pt was used as a photocatalyst for photodegradation of Basic Green 5 (BG5) in aqueous solution under sunlight. The morphology and photodegradation study was performed by SEM and UV–VIS spectrophotometry, respectively. The SEM image showed the presence of Sn and Pt on GNs, being confirmed by energy dispersive X-ray (EDX) analysis. The photodegradation study of BG5 showed that the dye degradation increases as a function of irradiation time. The degradation of BG5 was found to be pH dependent and maximum degradation was found at higher pH.     

Influence of plasticizers and cryogenic grinding on the high‐cooling‐rate solidification behavior of PBT/PET blends

Two structurally different plasticizers (cyclic and linear) and the effect of cryogenic grinding on the solidification behavior at high cooling rates by a continuous cooling transformation approach of poly(butylene terephthalate)/poly(ethylene terephthalate), PBT/PET, blends are described. The solidification curve (density versus cooling rate) is confirmed as an effective tool to compare the differences in crystallization behavior under conditions mimicking processing. In comparison to the bulky cyclic plasticizer, the linear oligomeric one was found to have a more pronounced influence on the crystallization behavior. A 60/40 by weight PBT/PET blend shows a drop‐off of density at ～50 K/s. In the plasticized sample, the long‐range crystalline order appears up to a cooling rate of ～250K/s, making the blend comparable to pure PBT. Grinding the components before blending further improves crystallizability and synergy to the addition of the plasticizer. The results suggest the important role of local chain mobility in the solidification behavior at high cooling rates. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43083.     

Electrochemical Synthesis of Cu (II) Coordination Polymer Coatings Based on 2,2′-Thiodiacetic Acid and 1,2,4,5-Benzenetetracarboxylate

Electrochemical synthesis of coordination polymers of Cu(II), [Cu(TDA)]_n and [Cu₂(BTC)(H₂O)₆?6H₂O]_n in which H₂TDA is 2,2′-thiodiacetic acid and BTC stands for 1,2,4,5-benzenetetracarboxylate was carried out by the electrochemical oxidation of Cu anode in the presence of H₂TDA (a flexible ligand), and 1,2,4,5-benzentetracarboxylic acid (H₄BTC) (a rigid ligand) in aqueous solutions. The structure of coordination polymers were characterized by scanning electron microscopy, X-ray powder diffraction, elemental analysis, thermal gravimetric and differential thermal analyses. The crystal structure of the compounds consists of one-dimensional cubical crystal polymeric units of [Cu(TDA)]_n and [Cu₂(BTC)(H₂O)₆?6H₂O]_n. Furthermore, the coordination number of Cu (II) ions in synthesized coordination polymers to be found five. The main advantages of electrosynthesis are the minor synthesis time, the milder conditions and the facile synthesis of coordination polymer coatings.     

Synthesis and Spark Plasma Sintering of Mg2Si Nanopowder by Mechanical Alloying and Heat Treatment

In this investigation, a two‐step method for the preparation of magnesium silicide (Mg₂Si) nanopowder was studied. This method is known as mechanical alloying followed by heat treatment. The results showed that the compositions of the combustion products depended on the milling time, heat treatment temperature, and starting mixtures. Pure Mg₂Si nanopowder was formed after short milling time and heat treatment, from Mg and Si powders with the mole ratio of 2.1:1 (Mg:Si) at 500°C in Ar atmosphere. Using the Mg₂Si nanopowder, Mg₂Si ceramic was produced by spark plasma sintering at 800°C under 50 MPa for 15 min. Composition and structure of reactants and products were examined by X‐ray diffraction (XRD), field emission scanning electron microscopy (FE‐SEM) and high‐resolution transmission electron microscopy (HR‐TEM).     

Effect of plate-like glass fillers on the mechanical properties of dental nanocomposites

In this study, glass flakes were incorporated into the spherical nanosilica component of the dental composites and its effect on the mechanical properties of these composites was investigated. To achieve a good interfacial adhesion between matrix resin and fillers, the particles were surface treated with a silane coupling agent (γ-MPS). Composites with different plate-like and spherical nanoparticle contents were prepared and their mechanical properties, including flexural strength, flexural modulus and fracture toughness were measured. The morphology of the particles and fracture surface of the composites were studied by SEM. The distribution of the flakes in the composite was also monitored using EDXA. Statistical analysis of the data was performed with ANOVA and the Tukey’s post hoc test was at a significance level of 0.05. The results showed that the flexural modulus and fracture toughness of specimens were improved with increasing the glass flake content up to 15 vol % which then declined upon further increase due to the stacking of the flakes on each other. A good interfacial adhesion was observed between matrix resin and particles in the SEM micrographs. The results of this study suggest that incorporation of glass flakes into the dental composites containing spherical nanosilica particles may enhance their mechanical properties.