Nucleoside‐Based Diarylethene Photoswitches: Synthesis and Photochromic Properties

Diarylethene photoswitches based on the natural nucleoside deoxyadenosine were designed and synthesized. In aqueous solution, some of them exhibited good photochromic properties, including clear changes in color upon irradiation at 365 nm, red‐shifts of the absorption wavelength, with good fatigue resistance, thermal stability, conversion efficiency, and base‐pairing properties.     

Structural synthesis of a class of 2R2T hybrid mechanisms

Conventional overconstrained parallel manipulators have been widely studied both in industry and academia, however the structural synthesis of hybrid mechanisms with additional constraints is seldom studied, especially for the four degrees of freedom(DOF) hybrid mechanisms. In order to develop a manipulator with additional constraints, a class of important spatial mechanisms with coupling chains(CCs) whose motion type is two rotations and two translations(2R2T) is presented. Based on screw theory, the combination of different types of limbs which are used to construct parallel mechanisms and coupling chains is proposed. The basic types of the general parallel mechanisms and geometric conditions of the kinematic chains are given using constraint synthesis method. Moreover, the 2R2T motion pattern hybrid mechanisms which are derived by adding coupling chains between different serial kinematic chains(SKCs) of the corresponding parallel mechanisms are presented. According to the constraint analysis of the mechanisms, the movement relationship of the moving platform and the kinematic chains is derived by disassembling the coupling chains. At last, fourteen novel hybrid mechanisms with two or three serial kinematic chains are presented. The proposed novel hybrid mechanisms and construction method enrich the family of the spatial mechanisms and provide an instruction to design more complex hybrid mechanisms.     

基于动态数据挖掘的热力参数传感器故障诊断

针对火电机组热力参数动态数据的海量、高维特点,提出了一种基于动态数据挖掘的热力参数传感器故障诊断新方法。该方法通过对热力参数信号进行经验模态分解,获得一系列平稳的本征模态函数(intrinsic mode function,简称IMF)分量和一个趋势余量,实现传感器故障特征信息的动态挖掘。以各IMF分量和趋势余量的方差作为特征向量构建欧氏距离判别函数,结合径向基函数神经网络确认传感器是否发生故障。根据专家经验得到的规则分析传感器测量值与理论值之间的差值,判别传感器的故障类型。以某电厂600MW火电机组实时运行数据为基础进行仿真实验,结果表明:该方法能够仅使用热力参数传感器正常状态下的样本,有效区分传感器故障造成的信号变化与机组本身正常负荷波动造成的信号变化,实现快速准确地对热力参数传感器的工作状态和故障类型进行判别。     

Three-dimensional stability prediction and chatter analysis in milling of thin-walled plate

Stability lobe diagram can be used for selecting proper milling parameters to perform chatter-free operations and improve productivity during milling of thin-walled plates. This paper studies the machining stability in milling of thin-walled plates and develops a three-dimensional stability lobe diagram of the spindle speed, tool position, and axial depth of cut. The workpiece-holder system is modeled as a 2-degree-of-freedom system considering that the tool system is much more rigid than the thin-walled plate, and dynamic equations of motion described for the workpiece-holder system are solved numerically in time domain to compute the dynamic displacements of the thin-walled plate. Statistical variances of the dynamic displacements are then employed as a chatter detection criterion to acquire the stability lobe diagram. The experimentally obtained stability limits correspond well with the predicted stability limits. In addition, influence of feed rate on stability limits is also investigated. By performing frequency analysis of the measured cutting forces to judge if chatter occurs, it is found that feed per tooth has little influence on the stability limits. However, feed per tooth impacts the machined surface quality. The results show that the surface quality drops by increasing feed per tooth.     

压力对水下焊条局部干法焊接电弧稳定性的影响

在压力舱中进行不同压力下的水下焊条局部干法焊接试验,采用统计分析和快速傅立叶变换研究了压力对水下电弧稳定性的影响.结果表明,铁粉低氢钾型焊条焊接主要进行粗熔滴短路过渡,随着压力的增加,短路时间由常压焊接的5~7 ms增加到8~10 ms,表明熔滴的平均尺寸增大.压力环境下,焊条熔化速度增大,弧压反馈调节系统的工作点上移,电弧电压增大.傅里叶变换结果表明,常压电弧电压信号的主要特征频率低于10 Hz,压力下电压信号的频谱图中出现大量高于10 Hz的谱线,说明信号突变性更强,电弧稳定性降低.     

Pd-Pt-Ce/Al_2O_3催化剂在VOC净化处理中的催化性能

采用浸渍法制备Pd-Pt-Ce/Al_2O_3催化剂,考察贵金属Pd和Pt负载量、助剂种类及负载量、空速对催化甲苯燃烧活性的影响。结果表明,适宜的贵金属负载量和助剂可极大提高Pd-Pt/Al_2O_3催化剂活性,当Pd和Pt质量分数分别为0.05%和0.005%、助剂Ce质量分数为1%时,Pd-Pt-Ce/Al_2O_3催化剂在低温条件下表现出较好的催化性能。空速对催化剂的催化活性影响较为明显,适宜的空速低于20 000 h-1。     

超声微波耦合催化合成蔗糖脂肪酸酯

通过超声微波耦合作用,采用无溶剂法制备蔗糖脂肪酸酯,研究催化剂类型、催化剂用量、超声微波功率、酯糖物质的量比和反应温度对蔗糖脂肪酸酯产率的影响。结果表明,超声微波耦合对蔗糖与脂肪酸甲酯的酯交换反应具有良好的促进作用,超声微波耦合作用下,蔗糖和脂肪酸甲酯能够形成较为良好的乳化状态。有机钛催化剂对蔗糖与脂肪酸甲酯的酯交换反应具有极佳的催化性能,与碱催化剂相比,具有用量少和活性高的特点。以钛酸四异丙酯为催化剂,在超声微波耦合体系中,蔗糖脂肪酸酯最高产率可达86.6%,其中,产品单酯含量为92.7%。     

硝盐浴淬火烈度的计算及分析

通过对20Cr Mn Mo钢试棒进行渗碳后在不同温度和含水量硝盐浴中的淬火试验,得到和端淬距离对应的心部硬度值,进而计算出硝盐浴的淬火烈度,分析了影响硝盐浴淬火烈度的因素以及淬火烈度对渗碳淬火工件临界碳含量的影响。结果表明,在盐浴温度为170~200℃范围内,硝盐浴温度越高,淬火烈度越低;在含水量为0.7%~0.9%范围内,含水量越高,淬火烈度越高;盐浴搅拌速度越快,淬火烈度越高。随着硝盐浴淬火烈度提高,20Cr Mn Mo钢渗碳淬火工件临界碳含量降低。     

高密度块状钐铁氮磁体制备的研究进展

钐铁氮化合物(Sm₂Fe₁₇N₃)因具有比钕铁硼(Nd₂Fe₁₄B)更高的磁晶各向异性场和居里温度值及更少的稀土含量,成为新型稀土永磁材料研究热点。但是,由于钐铁氮在600℃左右会分解导致永磁性能消失,因此常规的高温烧结工艺并不适用于钐铁氮烧结磁体的制备,现只能将其与高分子材料复合用作塑磁材料,这就导致Sm₂Fe₁₇N₃的磁学性能无法得到充分发挥。因此,开发低温成型工艺制备全金属高密度块状磁体是获取高性能钐铁氮磁体的关键。经过30多年的努力,科研人员已开发出多种制备钐铁氮磁体的低温快速成型工艺,并获得最大磁能积达到199 k J/m³的高性能磁体。本研究将从磁体的制备方法出发,总结当前块状钐铁氮磁体的研究现状及面临的问题,尤其针对不同成型方法出现矫顽力下降的现象提出分析,并对其今后的发展做出展望。