全文获取类型
收费全文 | 113804篇 |
免费 | 3454篇 |
国内免费 | 1586篇 |
专业分类
电工技术 | 2319篇 |
技术理论 | 2篇 |
综合类 | 4067篇 |
化学工业 | 16709篇 |
金属工艺 | 6665篇 |
机械仪表 | 5033篇 |
建筑科学 | 4572篇 |
矿业工程 | 1577篇 |
能源动力 | 1909篇 |
轻工业 | 5329篇 |
水利工程 | 1820篇 |
石油天然气 | 2455篇 |
武器工业 | 217篇 |
无线电 | 12448篇 |
一般工业技术 | 19897篇 |
冶金工业 | 4231篇 |
原子能技术 | 610篇 |
自动化技术 | 28984篇 |
出版年
2024年 | 123篇 |
2023年 | 577篇 |
2022年 | 928篇 |
2021年 | 1275篇 |
2020年 | 1061篇 |
2019年 | 798篇 |
2018年 | 15261篇 |
2017年 | 14238篇 |
2016年 | 10802篇 |
2015年 | 1780篇 |
2014年 | 1705篇 |
2013年 | 2019篇 |
2012年 | 5047篇 |
2011年 | 11302篇 |
2010年 | 9981篇 |
2009年 | 7219篇 |
2008年 | 8347篇 |
2007年 | 9304篇 |
2006年 | 1801篇 |
2005年 | 2607篇 |
2004年 | 2039篇 |
2003年 | 2025篇 |
2002年 | 1300篇 |
2001年 | 743篇 |
2000年 | 879篇 |
1999年 | 907篇 |
1998年 | 778篇 |
1997年 | 692篇 |
1996年 | 610篇 |
1995年 | 491篇 |
1994年 | 387篇 |
1993年 | 286篇 |
1992年 | 220篇 |
1991年 | 184篇 |
1990年 | 120篇 |
1989年 | 105篇 |
1988年 | 101篇 |
1987年 | 53篇 |
1986年 | 53篇 |
1968年 | 43篇 |
1967年 | 33篇 |
1966年 | 43篇 |
1965年 | 44篇 |
1960年 | 30篇 |
1959年 | 35篇 |
1958年 | 37篇 |
1957年 | 36篇 |
1956年 | 34篇 |
1955年 | 63篇 |
1954年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
951.
The removal of hydrogen sulfide (H2S) from simulated gas was carried out in a batch type fluidized-bed reactor using natural manganese ore (NMO), which consists
of several metal oxides (MnOx: 51.85%, FeOy: 3.86%, CaO: 0.11%). The H2S breakthrough curves were obtained by changing temperature, gas velocity, initial H2S concentration, and aspect ratio. Moreover, the effects of the particle size and the particle-mixing fraction on H2S removal were investigated in a binary system of different particle size. From this study, H2S removal efficiency increased with increasing temperature but decreased with increasing excess gas velocity. The breakthrough
time for H2S decreased as the gas velocity increased, which leads to reducing gas-solid contacting due to gas bypassing in a fluidized
bed reactor. Improvement of H2S removal efficiency in continuous process can be expected from the results of the binary particle system with different size
in a batch experiment. The NMO could be considered as a potential sorbent in H2S removal. 相似文献
952.
目的探讨高胆固醇兔脑组织RAAS与氧化应激的关系及培哚普利、缬沙坦的干预效果;方法:32只健康新西兰白兔随机分为4组:正常组,高脂组,培哚普利组,缬沙坦组。喂饲8周后,测定血清总胆固醇(Total cholesterol,TC)及低密度脂蛋白(Low den-sity lipoprotein,LDL)浓度。取脑组织测血管紧张素Ⅱ(AngiotensinⅡ,AngⅡ),血红素氧合酶(hemo oxygenase-1,HO-1)的表达及超氧化物岐化酶(SOD)活力,丙二醛(MDA)含量;结果:与正常组相比,高脂组AngⅡ,HO-1表达明显增强,SOD活力下降,MDA升高,培哚普利可降低AngⅡ,而缬沙坦不能,二者均可使HO-1表达上调,SOD活力升高,MDA降低;结论:1)高胆固醇血症时脑组织处于氧化应激状态,肾素血管紧张素醛固酮系统(Rennin-angiotensin-aldosterone system RAAS)激活;2)培哚普利和缬沙坦对组织具有抗氧化应激的保护作用。 相似文献
953.
Gabino A. Carriedo Francisco J. García Alonso Alejandro Presa Soto 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(2):399-406
The chiral phosphazene copolymers {[NP(O2C12H8)]0.9[NP(O2C20H12)]0.1} (1) and {[NP(O2C12H8)]0.9[NP(O2C20H10Br2)]0.1}
n
(2) [(O2C12H8) = 2,2′-dioxy-1,1′-biphenyl; (O2C20H12) = R-2,2′-dioxy-1,1′-binaphthyl and (O2C20H10Br2) = R-6,6′-dibromo-2,2′-dioxy-1,1′-binaphthyl] were prepared by sequential substitution from [NPCl2]
n
and the corresponding dihydroxy-biphenyl or binaphthyl reagents in the presence of Cs2CO3 and K2CO3. The reaction of (2) with tBuLi in THF, followed by addition of PPh2Cl and a treatment with SiHCl3/PPh3 to eliminate any oxidized OC6H4P(O)Ph2 groups, gave the phosphine containing copolymer {[NP(O2C12H8)]0.9[NP(O2C20H10[PPh2]2)]0.1}
n
(3), that was used as a chiral ligand to support [Ru(p-cymene)Cl] complexes. The resulting catalyst was active for hydrogen
transfer from isopropyl alcohol to acetophenone but the placement of the Ru centers in the 6,6′-positions of the binaphthoxyphosphazene
units induced no enantioselectivity.
Dedicated to Professor Christopher Allen. 相似文献
954.
介绍了高密度聚乙烯管材专用树脂6366M的结构特性、物理性能及其加工应用试验的情况。结果表明,6366M具有相对高的相对分子质量,其相对分子质量分布结构特性呈双峰分布。该材料具有优异的力学性能和耐环境应力开裂性能,而且加工性能较好,实现了刚性和韧性的平衡。成品管材的性能指标可以满足用户的需求。 相似文献
955.
利用ANSYS软件,模拟了振动诱导单螺杆挤出机熔体输送段中非牛顿幂律流体的三维脉动流场,得到了三维脉动流场的瞬时速度分布及螺槽中物料的流动轨迹。结果表明,在脉动流场作用下,非牛顿流体的瞬时速度响应与在驱动壁面上所施加的正弦形式的脉动驱动形式不同,横螺槽方向的环流中心位置受幂律指数影响,且发生周期性改变。振动的引入使得在相同的时间内,物料的流动路程增加,且可增大物料的平均停留时间,有利于改善混合效果。 相似文献
956.
An experimental study has been performed in order to determine the effect of humidity on the flow field and the flame stability
limit in turbulent non-premixed flame. Two-dimensional Particle Image Velocimetry (PIV) measurements were made to quantify
the velocity field, with and without steam injected. The results indicate the addition of steam decreases the recirculation
flow and reduces the distance between the forward and aft stagnation points. The detailed stabilization regimes show that
the critical fuel-to-air velocity ratios of the central fuel penetration in the humid air case are 16% to 22% lower, and the
partially quenching limits are at least 25% lower. The decreased penetration limit is due to a reduction in momentum of the
humid air. An analysis of flamelet concepts reveals that increased chemical reaction time leads to lower partially quenching
limits in the humid air combustion. 相似文献
957.
958.
Baoqing Deng Shanshan Kong Chang Nyung Kim 《Korean Journal of Chemical Engineering》2007,24(4):577-582
In this paper, a mathematical model is presented to describe the photocatalytic degradation of VOCs in a packed bed reactor.
Here, the adsorption of VOCs on the wall of the reactor is taken into account and the diffusion of VOCs in the axial direction
is neglected. First-order kinetics is used to describe the photocatalytic oxidation of VOCs. The analytical solution of the
present model is obtained by traveling wave method. The solution shows that the reactor performance is totally dependent on
the inlet concentration of VOCs when the time is large enough. The present model is validated through the experimental result
of the photocatalytic oxidation of trichloroethylene in a packed bed and the predicted results accord well with the experimental
data. The influence of flow rate and inlet concentration on the performance of the reactor is discussed in detail. High flow
rate offers high reaction rate and low conversion efficiency. The different inlet conditions and different reaction patterns
are also investigated. The model would be useful to estimate the rate constant and help to the design of the reactor. 相似文献
959.
960.
Kronkanok Hongthong Kejvalee Pruksathorn Pornpote Piumsomboon Paiboon Sripakagorn 《Korean Journal of Chemical Engineering》2007,24(4):612-617
This research focuses on the effect of the geometry and patterns of the gas flow channel on the PEM fuel cell performance.
Simulation was conducted and the results were verified by experiments. Three-dimensional, single phase, compressible and isothermal
models of 5 cm2 electrodes, anode and cathode, were developed and studied by utilizing a commercial Computational Fluid Dynamics (CFD) software,
FLUENT 4.5. Two types of gas flow channel were investigated: conventional and interdigitated. The results showed that the
flow channel pattern does not have a significant effect on the anode cell performance, whereas it has a strong effect/influence
on the cathode cell performance. The interdigitated design provides a higher limiting current density and cell performance
than the conventional design on the cathode side. Moreover, the cell performance does not depend on the inlet and outlet channel
widths. On the contrary, for the interdigitated design, it was influenced by the shoulder width. Finally, experiments were
conducted to validate the simulation results. 相似文献