Biosynthesis of silver nanoparticles in collagen gel improves their medical use in periodontitis treatment

Silver nanoparticles (AgNP) suspensions were biosynthesized by silver ions reduction in the presence of collagen, a nontoxic, organic polymer, intending to improve their medical use in periodontitis treatment. Spectrophotometric measurements showed a time- and concentration-dependent increase of AgNP formation in each suspension variant. Transmission electron microscopy revealed spherical morphology of AgNP in collagen and their mean diameter size was around 30?nm. The particle size distribution and zeta potential values of AgNP in collagen were determined by dynamic light scattering measurements. The surface charge of AgNP in collagen was positive, while commercial AgNP stabilized in citrate had negative surface charge. In vitro cytotoxicity testing of AgNP in collagen showed that they were biocompatible with human gingival fibroblasts in a wider range of concentrations than commercial nanoparticles. The antibacterial activity of AgNP in collagen against two pathogenic strains present in the periodontal pocket was dose-dependent and higher than that of AgNP in citrate. All these results demonstrated that AgNP prepared in collagen gel had improved properties, like small diameter, positive surface charge, high biocompatibility in human gingival fibroblasts, efficiency against bacterial growth and, thus, better therapeutic potential in periodontal disease treatment.     

Influence of the Carbo-Chromization Process on the Microstructural,Hardness, and Corrosion Properties of 316L Sintered Stainless Steel

We report on the changes on the microstructural, hardness, and corrosion properties induced by carbo-chromization of 316L stainless steel prepared by Spark Plasma Sintering technique. The thermo-chemical treatments have been performed using pack cementation. The carburizing and chromization were carried out between 1153 K (880 °C)/4 h to 1253 K (980 °C)/12 h and 1223 K (950 °C)/6 h to 1273 K (1000 °C)/12 h in a solid powder mixture of charcoal/BaCO₃ and ferrochromium/alumina/NH₄Cl, respectively. The obtained layers were investigated using X-ray and electron diffraction, optical and scanning electron microscopies, Vickers micro-hardness, and potentiodynamic measurements. The thickness of the carbo-chromized layer ranges between 300 and 500 μm. Besides the host γ-phase, the layers are mainly constituted of carbides (Fe₇C₃, Cr₂₃C₆, Cr₇C₃, and Fe₃C) and traces of α′-martensite. The average hardness values decrease smoothly from 650 HV at the sample surface down to 200 HV at the center of the sample. The potentiodynamic tests revealed that the carbo-chromized samples have smaller corrosion resistance with respect to the untreated material. For strong chromization regimes, the corrosion rate is increased by a factor of four with respect to that of the untreated material, while the micro-hardness of the layer is three times larger. Such materials are suited to be used in environments where good corrosion resistance and wear properties are required.     

Multistage access network for bidirectional DWDM transmission using ASE-injected FP-LD

We propose a novel optical distribution network for multistage optical access network with multiple remote nodes (RNs) using 4skip0 filters. The system can be implemented by use of 1/spl times/N arrayed waveguide grating in the central office, cascaded RNs, and a plurality of optical network units (ONUs). It also employs colorless ONUs based on incoherent light injected Fabry-Pe/spl acute/rot laser diodes for low operation and maintenance cost. Experiment shows error-free transmission with simultaneous bidirectional 1.25 Gb/s per channel up to 20 km.     

The meta-stable dip (MSD) effect in SOI FinFETs

The meta-stable dip (MSD) effect is demonstrated and characterized in SOI FinFETs. With ascending scan of front-gate voltage (V_G1), the magnitude of drain current (I_D) tends to be fixed within a specific region of the front-gate voltage and this leads to a dip of transconductance (g_m). The dip width can be modulated through a control of bias condition or measurement speed such as back-gate voltage (V_G2), drain voltage (V_D) and step size of the front-gate voltage. From the dual-gate transient measurement, it is found that the MSD effect is highly dependent on the floating-body effect. In SOI FinFETs, the MSD effect is significantly affected by the fin width due to the fringing electric field of the lateral gates.     

Generic fitted shapes (GFS): Volumetric object segmentation in service robotics

In this paper, a simultaneous 3D volumetric segmentation and reconstruction method, based on the so-called Generic Fitted Shapes (GFS) is proposed. The aim of this work is to cope with the lack of volumetric information encountered in visually controlled mobile manipulation systems equipped with stereo or RGB-D cameras. Instead of using primitive volumes, such as cuboids or cylinders, for approximating objects in point clouds, their volumetric structure has been estimated based on fitted generic shapes. The proposed GFSs can capture the shapes of a broad range of object classes without the need of large a-priori shape databases. The fitting algorithm, which aims at determining the particular geometry of each object of interest, is based on a modified version of the active contours approach extended to the 3D Cartesian space. The proposed volumetric segmentation system produces comprehensive closed object surfaces which can be further used in mobile manipulation scenarios. Within the experimental setup, the proposed technique has been evaluated against two state-of-the-art methods, namely superquadrics and 3D Object Retrieval (3DOR) engines.     

Relaxing PWQ Lyapunov stability criteria for PWA systems

The note addresses the calculation of piecewise quadratic (PWQ) Lyapunov functions for PWA (piecewise affine) systems. New LMI relaxations are proposed. These relaxations have been found to be effective in cases where the traditional relaxations fail.     

A patchy approximation of explicit model predictive control

The explicit solution of multi-parametric optimisation problems (MPOP) has been used to construct an off-line solution to relatively small- and medium-sized constrained control problems. The control design principles are based on receding horizon optimisation and generally use linear prediction models for the system dynamics. In this context, it can be shown that the optimal control law is a piecewise linear (PWL) state feedback defined over polytopic cells of the state space. However, as the complexity of the related optimisation problems increases, the memory footprint and implementation of such explicit optimal solution may be burdensome for the available hardware, principally due to the high number of polytopic cells in the state-space partition. In this article we provide a solution to this problem by proposing a patchy PWL feedback control law, which intend to approximate the optimal control law. The construction is based on the linear interpolation of the exact solution at the vertices of a feasible set and the solution of an unconstrained linear quadratic regulator (LQR) problem. With a hybrid patchy control implementation, we show that closed-loop stability is preserved in the presence of additive measurement noise despite the existence of discontinuities at the switch between the overlapping regions in the state-space partition.     

Vertically oriented nickel nanorod/carbon nanofiber core/shell structures synthesized by plasma-enhanced chemical vapor deposition

Plasma-enhanced chemical vapor deposition, without a nickel-containing gaseous precursor, was used to synthesize continuous nickel (Ni) nanorods inside the hollow cavity of carbon nanofibers (CNFs), thus forming vertically aligned Ni/CNF core/shell structures. Scanning and transmission electron microscopic images indicate that the elongated Ni nanorods originate from the catalyst particles at the tips of the CNFs and that their formation is due to the effect of extrusion induced by the compressive force of the graphene layers during growth. Different from previous work, each vertically-aligned core/shell structure reported is totally isolated from its neighbors. Continuous Ni nanorods are found to separate into smaller ones with increasing growth time, which was ascribed to (i) the limited amount of Ni available in the tip of the CNF, (ii) the polycrystalline nature of the Ni nanorods and (iii) the combined effects of the compressive stresses on the side of the Ni nanorods and of the tensile stress along their axis.     

Chemomechanical Systems: Study of Contraction and Mechanical Work of Poly(Acrylonitrile) Gel Fibers

Poly(acrylonim1e) fibers were preoxidated under stress, in the presence of air, then saponified by boiling in alkaline solutions. The chemomechani-cal behavior of these fibers, expressed as contraction and mechanical work, under different loads and in different solvent-nonsolvent and/or base-acid systems were investigated. Total nitrogen content, carboxyl groups content, tensile strength, and cross-link density were determined. Both contraction and mechanical work were expressed as functions of applied load in every studied system. The results of chemomechanical measurements were connected to those of chemical and physical investigations. Significant differences in chemomechanical behavior were found to be the result of different stress conditions during the preoxidation stage.     

Tunable single-mode fiber reflective grating filter

A single-mode fiber tunable reflective filter is demonstrated by translating a fan-shaped grating structure through the evanescent field of a side-polished fiber. Filter linewidths of about 1 nm were measured over tuning ranges in excess of 65 nm. Reflectivities as high as 88 percent were observed. Using the fiber filter as a feedback element, a multimode semiconductor laser was observed to oscillate in a single mode which could be discretely turned over a wavelength range of 26 nm.