Synthesis and characterization of Cu-doped ceria nanopowders

Nanopowdered solid solution Ce_1−xCu_xO_2−γ samples (0 ≤ x ≤ 0.15) were synthesized by self-propagating room temperature synthesis (SPRT). Raman spectroscopy and XRD at room temperature were used to study the vibration properties of these materials as well as the Cu solubility in ceria lattice. The solubility limit of Cu²⁺ in CeO₂ lattice was found to be lower than published in the literature. Results show that obtained powders with low dopant concentration are solid solutions with a fluorite-type crystal structure. However, with Cu content higher than 7.5 mass%, the phase separation was observed and two oxide phases, CeO₂ and CuO, coexist. All powders were nanometric in size with high specific surface area.     

Reaction kinetics of metal deposition via surface limited red-ox replacement of underpotentially deposited metal monolayers

The study of the kinetics of metal deposition via surface limited red-ox replacement of underpotentially deposited metal monolayers is presented. The model system was Pt submonolayer deposition on Au(1 1 1) via red-ox replacement of Pb and Cu UPD monolayers on Au(1 1 1). The kinetics of a single replacement reaction was studied using the formalism of the comprehensive analytical model developed to fit the open circuit potential transients from deposition experiments. The practical reaction kinetics parameters like reaction half life, reaction order and reaction rate constant are determined and discussed with their relevance to design and control of deposition experiments. The effects of transport limitation and the role of the anions/electrolyte on deposition kinetics are investigated and their significance to design of effective deposition process is discussed.     

CuO–CeO2 mixed oxide catalysts for the selective oxidation of carbon monoxide in excess hydrogen

A series of mixed oxide CuO–CeO₂ catalysts were prepared by coprecipitation and tested for the selective oxidation of carbon monoxide in the presence of excess hydrogen. These catalysts were found to be very active and exceptionally selective for this reaction and exhibited a good resistance towards CO₂ and H₂O. The catalytic performance of these non-noble metal containing catalysts is compared with that of other selective CO oxidation catalysts reported in literature.     

Synthesis and characterization of interpenetrating polymer networks with hyperbranched polymers through thermal-UV dual curing

The aim of this study was to investigate the possibility of using acrylated hyperbranched polyesters (HBP) as UV curable component in dual curing automotive applications. Dual curing is one of possible ways to obtain fast curing, scratch resistant coatings for use in OEM and car refinish applications. Dual curing systems, upon hardening, can give interpenetrating networks (IPNs).     

Simple broadband cylindrical antenna with quasidistributed capacitive loading

A cylindrical antenna with easily adjustable quasidistributed capacitive loading is described, which is convenient for experimental investigation of such structures. Some experimental results for admittances are presented, showing excellent broadband properties of the antenna and a satisfactory agreement with theoretical values.     

A novel split-and-merge algorithm for hierarchical clustering of Gaussian mixture models

The paper presents a novel split-and-merge algorithm for hierarchical clustering of Gaussian mixture models, which tends to improve on the local optimal solution determined by the initial constellation. It is initialized by local optimal parameters obtained by using a baseline approach similar to k-means, and it tends to approach more closely to the global optimum of the target clustering function, by iteratively splitting and merging the clusters of Gaussian components obtained as the output of the baseline algorithm. The algorithm is further improved by introducing model selection in order to obtain the best possible trade-off between recognition accuracy and computational load in a Gaussian selection task applied within an actual recognition system. The proposed method is tested both on artificial data and in the framework of Gaussian selection performed within a real continuous speech recognition system, and in both cases an improvement over the baseline method has been observed.     

Exploring the Impact of Social Networking on Communication in Organizations

ABSTRACT

Social networking technology has the potential to transform how organizations communicate, cooperate, and connect with key stakeholders. Our research explores how social networking technologies are deployed within organizations and how the use of these technologies is related to effectiveness in organizational communication and promotion. We also identify the facilitating factors and constraints around the use of social networking tools for communication. To examine these questions, we conducted interviews with 131 senior level executives across a broad range of organizations and employed both quantitative and qualitative methods of analysis. The executives were asked to rate numerically and then discuss in narrative form a series of questions about IT strategy and issues affecting social networking in their organization. We find important differences both in the types of tools used as well as how they are used and discuss the implications of our findings for companies seeking to more effectively harness social networking technologies.     

Variable neighborhood search algorithm for heterogeneous traveling repairmen problem with time windows

The focus of this paper is generalized traveling repairman problem (TRP), a special case of the well known and well studied traveling salesman problem (TSP). Because of its specific objective function, that minimizes the sum of overall time all clients wait for until the end of a service, TRP has great applicability potential in client oriented practical problems. Therefore it has been known in literature as traveling deliveryman problem, minimum latency problem and cumulative capacitated vehicle routing problem. However, most studies that have treated TRP related problems have implied that only one repairman is present in the system and/or that all clients are available for service at the beginning of the planning horizon. In this paper we consider a TRP with a heterogeneous fleet of repairmen serving a set of clients whose arrival times are distributed over a planning horizon, i.e. heterogeneous TRPTW (hetTRPTW). For the hetTRPTW we present a mixed integer linear programming model, and a heuristic algorithm based on a variable neighborhood search (VNS) framework. Additionally, we propose a reduction strategy for neighborhoods in the VNS algorithm and test efficiency of implemented algorithms on four benchmark sets of problem instances. Results show that proposed algorithms could be used in real systems for solving small and moderate problem instances.     

Applications of -Matrix Techniques in Micromagnetics

The variational model by Landau and Lifshitz is frequently used in the simulation of stationary micromagnetic phenomena. We consider the limit case of large and soft magnetic bodies, treating the associated Maxwell equation exactly via an integral operator . In numerical simulations of the resulting minimization problem, difficulties arise due to the imposed side-constraint and the unboundedness of the domain. We introduce a possible discretization by a penalization strategy. Here the computation of is numerically the most challenging issue, as it leads to densely populated matrices. We show how an efficient treatment of both and the corresponding bilinear form can be achieved by application of -matrix techniques.