Spiral growth of one dimensional titania nanostructures using anodic oxidation

One dimensional spiral titania nanostructures were obtained by anodization of pure titanium from fluoride containing solutions of phosphoric acid. The formation of nanotubes was found to be dependant on current density. Field Emission Scanning Electron Microscopy (FESEM) shows the diameter of tubes around 70-100 nm which is consistent with the High Resolution Transmission Electron Micrographs (HRTEM) and Atomic Force Microscopy (AFM) images. HRTEM showed the one dimensional growth as spiral in nature which was also supported by AFM images. This anisotropic growth is compared with the possible growth mechanisms.     

Steady Mixed Convection in Power-Law Fluids from a Heated Triangular Cylinder

The steady mixed convective transport from a heated triangular cylinder immersed in power-law fluids in an unconfined vertical domain is investigated numerically. Two different configurations of the cylinder are chosen; one when the base of the cylinder is facing the flow and the other when the apex of the triangle is facing the flow. The simulation is performed for: Reynolds number (1 to 35), Richardson number (0 to 2), power law index (0.4 to 1.8) and Prandtl number, 50. The flow and thermal fields are visualized through the streamlines and isotherm contours at the close proximity of the heated object for various Reynolds numbers, Richardson numbers and power law indices. The distributions of the surface pressure coefficient and local Nusselt number provide further insight of the hydrodynamic and thermal characteristics. Finally, the total drag coefficient and average Nusselt numbers on the surface of the cylinder are computed to explore the overall macroscopic behavior of the involved thermo-hydrodynamics. The flow separation is observed to be more when the apex of the cylinder is facing the flow. The average heat transfer, measured in terms of the Nusselt number, and the total drag on the cylinder are also found higher for that configuration.     

Effect of Rolling and Subsequent Annealing on Microstructure,Microtexture, and Properties of an Experimental Duplex Stainless Steel

A lean duplex stainless steel (LDSS) has been prepared with low-N content and processed by different thermo-mechanical schedules, similar to the industrial processing that comprised hot-rolling, cold-rolling, and annealing treatments. The microstructure developed in the present study on low-N LDSS has been compared to that of high-N LDSS as reported in the literature. As N is an austenite stabilizer, lower-N content reduced the stability of austenite and the austenite content in low-N LDSS with respect to the conventional LDSS. Due to low stability of austenite in low-N LDSS, cold rolling resulted in strain-induced martensitic transformation and the reversion of martensite to austenite during subsequent annealing contributed to significant grain refinement within the austenite regions. δ-ferrite grains in low-N LDSS, on the other hand, are refined by extended recovery mechanism. Initial solidification texture (mainly cube texture) within the δ-ferrite region finally converted into gamma-fiber texture after cold rolling and annealing. Although MS-brass component dominated the austenite texture in low-N LDSS after hot rolling and cold rolling, that even transformed into alpha-fiber texture after the final annealing. Due to the significant grain refinement and formation of beneficial texture within both austenite and ferrite, good combination of strength and ductility has been achieved in cold-rolled and annealed sample of low-N LDSS steel.     

Forced Convection Heat Transfer in Power-Law Fluids Around a Semicircular Cylinder at Incidence

Two-dimensional steady flow and convective heat transfer of power-law fluids past a semicircular cylinder are investigated in the reported work. The heated semicircular cylinder is placed in an unconfined domain at different angles facing the incoming free-stream flow of power-law fluids having a generalized Prandtl number (Pr) = 100. Particular emphasis is given to studying the effect of angle of incidence (0 ≤ α ≤ 180°) on fluid dynamics and thermal transport around the semicircular object for varying Reynolds number (10 ≤ Re ≤ 40) and power-law index (0.4 ≤ n ≤ 1.8). A finite volume-based method is adopted for the numerical computation. The flow and heat transfer phenomena are visualized through the streamline and isotherm profiles at various operating conditions. Also, the pressure coefficient, drag coefficient, and Nusselt number on the surface of the object are presented and discussed.     

A facile synthesis of PLGA encapsulated cerium oxide nanoparticles: release kinetics and biological activity

In the present article a facile synthesis of cerium oxide nanoparticles (CNPs) encapsulated in PLGA microparticles is reported. The release kinetics of the CNPs from the PLGA matrix was investigated under acidic, basic and near-neutral pH. A diffusion model was applied to determine the diffusivity of the CNPs from the PLGA matrix. The morphology of the degraded PLGA particles was characterized by high resolution SEM. Superoxide dismutase (SOD) mimetic activity was retained in released CNPs for a longer period of time (～90 days) under different pH. PLGA encapsulated CNP showed excellent biocompatibility. This study demonstrates a potential strategy to deliver CNPs using biodegradable PLGA that ensures a slow release of the CNPs over a long period of time. Thus, the synthesized PLGA encapsulated CNPs could find potential applications in tissue engineering like bone remodelling and regeneration, and protection from disorders caused by neurodegeneration.     

3D Coordination Network of Ag(I) Ions with μ 3 -Bridging Melamine Ligands

Abstract  

A new 3D silver complex [Ag(mela)(H₂O)(NO₃)]_n (1) (mela = melamine or 2,4,6-triaminotriazine) is synthesized and characterized by single crystal X-ray diffraction, IR, and elemental analysis. The structural characterization shows that the compound crystallizes in space group C c, a = 8.181(2), b = 10.269(3) c = 11.347(3) ?, β = 105.88(2)°, Z = 4. Out of several structurally characterized transition metal compounds comprising melamine, the titled complex represents a rare example of μ ₃ -melamine coordination mode realized through the heterocycle nitrogen donors. The fluorescent property of complex 1 was investigated and the mechanism was validated by means of a density functional theory (DFT) calculation.     

纤维横截面对环锭纱和喷气纱织物舒适性的影响

描述了纤维横截面形状对涤棉和涤粘环锭纱织物及喷气纱织物的影响.纱线结构在影响衣服舒适性的众多因素中扮演着重要角色.事实证明用喷气纱制成的面料在透气性、透湿性和吸湿性方面优于环锭纱面料.非圆形截面的涤纶纤维制成的面料具有较好的透气性、导湿性、吸湿性、绝热性和芯吸性.除了绝热性能外涤粘混纺面料的其他各项性能均比涤棉混纺面料好.     

DE-ASHING OF COALS WITH HIGH GRADIENT MAGNETIC SEPARATION USING ENHANCEMENT OF MAGNETIC PROPERTY.

ABSTRACT

De-ashing of Indian coal samples from Bhojudih, Mandaman and Kusumunda has been studied using High Gradient Magnetic Separation (HGMS(. Coating of the ash particles with magnetite or blue dust brings down the operating magnetic field considerably. The flow velocity has a significant effect on the removal as well as Heat Value Recovery (HVR).     

Regulation of mesangial cell ion channels by insulin and angiotensin II. Possible role in diabetic glomerular hyperfiltration

We used patch clamp methodology to investigate how glomerular mesangial cells (GMC) depolarize, thus stimulating voltage-dependent Ca2+ channels and GMC contraction. In rat GMC cultures grown in 100 mU/ml insulin, 12% of cell-attached patches contained a Ca(2+)-dependent, 4-picosiemens Cl- channel. Basal NPo (number of channels times open probability) was < 0.1 at resting membrane potential. Acute application of 1-100 nM angiotensin II (AII) or 0.25 microM thapsigargin (to release [Ca2+]i stores) increased NPo. In GMC grown without insulin, Cl- channels were rare (4%) and unresponsive to AII or thapsigargin in cell-attached patches, and less sensitive to [Ca2+]i in excised patches. GMC also contained 27-pS nonselective cation channels (NSCC) stimulated by AII, thapsigargin, or [Ca2+]i, but again only when insulin was present. In GMC grown without insulin, 15 min of insulin exposure increased NPo (insulin > or = 100 microU/ml) and restored AII and [Ca2+]i responsiveness (insulin > or = 1 microU/ml) to both Cl- and NSCC. GMC AII receptor binding studies showed a Bmax (binding sites) of 2.44 +/- 0.58 fmol/mg protein and a Kd (binding dissociation constant) of 3.02 +/- 2.01 nM in the absence of insulin. Bmax increased by 86% and Kd was unchanged after chronic (days) insulin exposure. In contrast, neither Kd nor Bmax was significantly affected by acute (15-min) exposure. Therefore, we concluded that: (a) rat GMC cultures contain Ca(2+)-dependent Cl- and NSCC, both stimulated by AII. (b) Cl- efflux and cation influx, respectively, would promote GMC depolarization, leading to voltage-dependent Ca2+ channel activation and GMC contraction. (c) Responsiveness of Cl- and NSCC to AII is dependent on insulin exposure; AII receptor density increases with chronic, but not acute insulin, and channel sensitivity to [Ca2+]i increases with both acute and chronic insulin. (d) Decreased GMC contractility may contribute to the glomerular hyperfiltration seen in insulinopenic or insulin-resistant diabetic patients.     

A review of power electronics interfaces for distributed energy systems towards achieving low-cost modular design

Due to increased attention towards clean and sustainable energy, distributed energy (DE) systems are gaining popularity all over the world. Power electronics are an integral part of these energy systems being able to convert generated electricity into consumer usable and utility compatible forms. But the addition of power electronics adds costs to the DE capital investments along with some reliability issues. Therefore, widespread use of distributed energy requires power electronics topologies that are less expensive and more dependable. Use of modular power electronics is a way to address these issues. Adoption of functional building blocks that can be used for multiple applications results in high volume production and reduced engineering effort, design testing, onsite installation and maintenance work for specific customer applications. In this paper, different power electronics topologies are reviewed that are typically used with distributed energy systems. The integrated power electronics module (IPEM) based back-to-back converter topologies are found to be most suitable interface that can operate with different DE systems with small or no modifications. Also the requirements for a hierarchical control structure with standardized power and communication interfaces are addressed in the paper along with some discussion on future design possibilities for the IPEM-based power electronics topologies. It is expected that modular and flexible power electronics and standardized controls and interfaces, will provide commonality in hardware and software for the power electronics interfaces, thus will enable their volume production and decrease their cost share in distributed energy applications.