吐丝圈径对大规格高碳盘条组织性能的影响

计算与分析了斯太尔摩冷线上盘条的吐丝圈径、搭接密度及"佳灵"装置横向布风曲线之间的关系,研究了吐丝圈径的大小对大规格82B盘条组织和性能的影响,确定了大规格82B盘条最小吐丝圈径应为980mm.     

网络化制造中基于STEP-NC的编程方法

STEP-NC是由欧美提出的新的数控接口标准，目的是取代旧的数控标准ISO6983。本文首先分析了STEP-NC的两种应用标准：ISO14649（ARM）和STEPAP238（AIM），并且分析了Part21和Part28的应用领域及Part21文件格式和其中的信息产生方法。然後介绍了ST-Developer环境下ROSEC＋＋颠库编程接口及其应用程序的早、晚编联方式，并且以此为基础设计了整个程序的编程流程，重点介绍了工艺规划设计。最后给出了在C＋＋编程环境下利用ROSE库函数写入形成STEP AP238文件的方法。     

Interface characteristics and mechanical properties of carbon fibre reinforced copper composites

Interface characteristics of carbon fibre reinforced copper matrix composites materials with various interface states and their effect on the flexural strength of composites have been studied. Interfacial states are mechanical bonding, dissolution bonding and reaction bonding. To a certain extent, raising the interfacial strength enables an increase in the flexural strength due to prevention of carbon fibre being pulled out under low stress during fracture process of composites. Raising the interfacial bondage strength, causes the brittleness of composites to increase; the fracture surface of composites is converted from a fibre pull-out model to a fibre even model. While strengthening the interface bondage, the extent of chemical reaction and dissolution at the interface must be controlled to avoid degrading the carbon fibre.     

High-resolution electron microscopy of the twinning and intergrowth in Ca4Al6SO16 and Ca3SrAl6SO16

The microstructures of unhydrated calcium aluminosulphate Ca₄Al₆SO₁₆ and Ca₃SrAl₆SO₁₆ have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca₃SrAl₆SO₁₆ and another phase, possibly Sr₃Al₂O₆ existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced.     

乙烯装置中汽油分馏塔设计浅析

对汽油分馏塔的技术特点进行了分析,对急冷油系统的设计和汽油分馏塔的内件选择和设计进行了分析和讨论.     

Slow eroding biodegradable multiblock poloxamer copolymers

Biodegradable multiblock poloxamers (BMPs) with gel duration of 8 h to several weeks were prepared by varying their molecular weights from 4000 to 40 000 g mol^?1. The molecular weight of the BMP was controlled by changing the poloxamer to coupling agent ratio. Assuming a micelle packing model of the BMP gel, as in the case of a poloxamer gel, the micelle properties and critical gel concentration of BMPs were investigated on the basis of the scaling concept. The findings suggest that the control of molecular weight by hydrolyzable groups can be a facile approach to optimize the gel properties for biomedical applications. Copyright © 2005 Society of Chemical Industry     

Synthesis and characterization of an interpenetrating polymer network composed of poly(methacrylic acid) and poly(vinyl alcohol)

Temperature and pH‐responsive interpenetrating polymer network (IPN) hydrogels, constructed with poly(methacrylic acid) (PMAA) and poly(vinyl alcohol) (PVA), by a sequential IPN method, were studied. The characterization of IPN hydrogels was investigated by Fourier‐transform infrared spectroscopy, differential scanning calorimetry (DSC) and swelling under various conditions. The IPN hydrogels exhibited relatively high swelling ratios, in the range 230–380 %, at 25 °C. The swelling ratios of the PMAA/PVA IPN hydrogels were pH and temperature dependent. DSC was used for the quantitative determination of the amounts of freezing and non‐freezing water. The amount of free water increased with increasing PMAA content in the IPN hydrogels. Copyright © 2004 Society of Chemical Industry     

Colour Centres and Energy Transfer in BaF2-xClx:Eu2+ Phosphors

The optical absorption spectra of BaF2-xClx:Eu2 after ultraviolet (UV) light excitation were investigated.The differences between the absorption spectra after and before excitation (DAS) were observed.The DAS increase at both the high and the low energy side of F band in BaF2-xClx:Eu2 after 245 nm UV light excitation.The bleach effect of UV light and the absorption of electrons in the valence band may account for the former and the formation of Fa centres (association of F(Cl-) centres), whose absorption band matches the HeNe laser better, may explain the latter.In the write-in process, the transfer of electrons is via tunneling.In the readout process, the transfer of electrons captured in F(F-) and Fa centres is more likely via tunneling, and that of F(Cl-) centres is more likely via conduction band.