Phosphate-hydroxyquinoline method for separation and volumetric determination of zirconium

The proposed method consists of a combination of the well-known phosphate method for separation of zirconium, and determination of zirconium as the hydroxyquinolate. The separation of zirconium hydroxyquinolate from an oxalate medium after solution of the phosphate preccipitate in oxalic acid has been used for the first time. The conditions of separation of zirconium from titanium and thorium in the phosphate precipitation, and from niobium and tantalum in precipitation of the hydroxyquinolate, have been studied. By this method it is possible to separate zirconium in practice from all accompanying elements (except hafnium), and to determine small amounts of zirconium (2–5 mg) by a volumetric method to an accuracy of ± 2–4%.     

Antimony Mobilization through Two Contrasting Gold Ore Processing Systems,New Zealand

Antimony, a toxic metalloid similar to arsenic, is present at variable levels in most gold-bearing rocks. Antimony is soluble in the surface environment, so antimony (Sb) mobilization in mine waters is an environmental issue around gold mines. The Reefton gold mine was originally developed in gold-bearing quartz veins; Sb concentrations were low (<100 mg/kg) compared to arsenic (As) concentrations (>1,000 mg/kg), and the mine waters had low dissolved Sb (<0.1 mg/L). A second stage of gold mineralization at Reefton involved brecciation and cataclasis of quartz veins and wall rocks, with addition of stibnite (Sb₂S₃). Processing of this ore has resulted in higher dissolved Sb in mine waters (0.1–1 mg/L), even after water treatment that removes most dissolved As (to 0.01 mg/L) by adsorption to suspended iron oxyhydroxide. Competition between As and Sb for adsorption sites on iron oxyhydroxide particles may have resulted in partial exclusion of the more weakly adsorbed Sb. The high rainfall (2,000 mm/year) at Reefton ensures adequate dilution of mine waters after discharge. The Macraes gold mine has no stibnite, and most Sb is in solid solution in the abundant arsenopyrite (Sb up to 2,000 mg/kg). Pit waters have both Sb and As dissolved up to 0.1 mg/L, partly because of evaporative concentration in a low-rainfall environment. Macraes tailings waters have high As (up to 3 mg/L) but negligible Sb (<0.001 mg/L). Reefton mine gold-bearing concentrate, containing stibnite, is transported 700 km to be processed by autoclave oxidation and cyanidation at the Macraes mine. This introduction of additional Sb to the Macraes site substantially increases the Sb content of the process stream periodically. Tailings from this process have up to 3 wt% Sb, dispersed through As-rich iron oxyhydroxides that are formed in the autoclave. The Sb-rich tailings are strongly diluted (approximately 100:1) by the Macraes tailings, and adsorption of Sb to iron oxyhydroxides in the tailings piles ensures that there has been no increase in the Sb content of the tailings water since the Reefton concentrate has been added at Macraes.     

Disintegration and separation of granite into mineral components by powerful superhigh-frequency fields

Conclusions 1. Based on the above discussion it can be concluded that disintegration of mineral raw materials by powerful impact of SHF is promising because disintegration of these materials ensures retention of the original size of the structural units of the mineral as well as fairly good separation into the mineral components. 2. Further studies of rocks, which are useful fossil mineral raw materials, will allow us to optimize specific conditions of their disintegration. State University of Mining, St. Petersburg, and Institute of Geology of the Kola Scientific Center, Russian Academy of Sciences, Apatity. Translated from Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, Vol. 33, No. 4, pp. 95–99, July–August 1997.     

Kaiser Effect in Rock Salt

Using the results of experiments with rock salt samples under various loading regimes as an example, the regularities of the Kaiser effect formation and manifestation in rocks with plastic properties are investigated.