Aggregate stability of ZrO2 aqueous sols in electrolyte solutions

The aggregate stability of submicron and nanosized ZrO₂ aqueous sols of different origins and different dispersities at pH 3–10 in the KCl concentration range 10^?3–10^?1 M is investigated by flow ultramicroscopy and photometry. The results obtained are analyzed in the framework of the extended Derjaguin-Landau-Verwey-Overbeek theory and the Muller-Martynov theory of reversible aggregation. The extension of boundary layers of water near the surface of the ZrO₂ particles is estimated.     

Advantage of heat insulation made of materials with natural porosity

Various heat insulation materials produced at home and abroad are compared. The advantage of using natural nano-structured materials is substantiated. Translated from Novye Ogneupory, No. 7, pp. 41–44, July 2008.     

A fragmentary model of vitreous As<Subscript>2</Subscript>S<Subscript>3</Subscript>

The X-ray scattering intensity curves for vitreous As₂S₃ are experimentally measured using soft (copper) and hard (molybdenum) X rays. The inclusion of all the specific features revealed in the experimental scattering intensity curves makes it possible to obtain the experimental atomic radial distribution function (ARDF) in the ordering range up to ～1 nm. The experimental ARDF is interpreted in the framework of the fragmentary model. A comparison of the experimental ARDF with the model ARDF calculated from the crystal structure data obtained for orpiment demonstrates that the corrugated layers inherent in crystalline As₂S₃ are retained in the glass structure but the characteristic interlayer interatomic distances are absent. The layers are joined together through the As₄S₅ molecular clusters. Microcrystals consisting of several unit cells are absent in the glass structure, which involves only the structural fragments of both crystalline analogs. One of the possible variants of their joining is proposed.     

γ-Absorption express analysis of the moisture content of coal concentrate in coke production

Coal concentrate with minimum moisture content is used for coke production in metallurgy. At various enterprises, the moisture content is determined by weighing [1]. However, this method is slow and is undertaken in the laboratory. To reduce the loss of production, accelerated monitoring of the moisture content in industrial conditions is required.     

Study of medium-cement concrete based on mixed Chamotte-periclase chromite filler

The possibility is demonstrated of using an addition of periclase-chromite filler (PCF) prepared from PCF grade broken material articles in medium-cement concrete with chamotte filler. The effect of this addition on cement hardening duration, strength and heat resistance is considered. Translated from Novye Ogneupory, No. 8, pp. 42–46, August 2008.     

Reproducibility of plastic measurements: The need to modify State Standard GOST 1186-87

A very important characteristic of coking coal is its clinkering ability, i.e., its ability to form a nonvolatile solid residue, consisting of disparate grains, on heating in specific conditions. The clinkering ability of the coal is determined by the properties of its plastic mass. Various methods may be used to evaluate the plastic-ductile properties of the coal. However, since the 1930s, the main method used to evaluate the clinkering properties of coal, within the nations of the former Soviet Union, has been the Sapozhnikov-Bazilevich plastometric method, because it provides more information than competing approaches. For the same reason, the thickness of the plastic layer, which is one of the parameters determined by this method, is used for coal classification in State Standard GOST 25543-88 (Lignite, Coal, and Anthracite: Genetic and TEchnological Classification) and its Ukrainian counterpart DSTU 3472-96 (Lignite, Coal, and Anthracite: Classification). This explains the strict requirements on the accuracy and reliability of the plastometric characteristics.