Structure evolution of conductive polymer composites revealed by solvent vapor induced time-dependent percolation

The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test.     

Biomimetic synthesis of spherical nano-hydroxyapatite in the presence of polyethylene glycol

Spherical nano-hydroxyapatite (nano-HA) was synthesized successfully by a biomimetic method using Ca(NO₃)₂·4H₂O and (NH₄)₃PO₄·3H₂O as reagents in the presence of polyethylene glycol (PEG). The crystalline phase, microstructure, chemical composition, and morphology of the obtained samples were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). The results show that spherical nano-HA with diameter of 30–50 nm can be synthesized in the presence of a certain concentration (2–6%) of PEG. The crystallinity of HA powder synthesized in the presence of PEG was higher than that synthesized in the absence of PEG, but the crystallinity of HA reduced with increasing the concentration of PEG. The electrical conductivity (EC) of the solution revealed that PEG reduced the transfer rate of Ca²⁺ in the process of HA crystallization, indicating the interaction between PEG and HA. The possible mechanism of formation spherical nano-HA was discussed.     

A new efficient numerical method and the dynamic analysis of composite laminates with piezoelectric layers

Firstly, a numerical method for the inversion of Laplace transform is developed and its accuracy is shown through examples. Then, a state-vector equation for the dynamic problems of piezoelectric plates is deduced directly from a modified mixed variational principle for piezoelectric bodies and its exact solution for the dynamic problems of simply supported rectangle piezoelectric plate is simply given. For multilayered hybrid plates, we derive the solution in terms of the propagator matrices. The techniques accounts for the compatibility of generalized displacements and generalized stresses on the interface both the elastic layers and piezoelectric layers, and the transverse shear deformation and the rotary inertia of laminate are also considered in the global algebraic equation of structure. Meanwhile, there is no restriction on the thickness and the number of layers. As an application of the numerical inversion of Laplace transform presented in this paper, typical numerical examples of the harmonic vibration and transient response are proposed and discussed. Since the highly accurate numerical results, they can serve as benchmarks to test various thick plate theories and various numerical methods, such as the finite and boundary element methods for transient response problems.     

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研究燃料汽车及其氢源系统是当今国内外能源工业与汽车工业的共同课题，而优选制氢能源则是这一课题的关键。章介绍了利用能源、经济、环境(EEE)——生命周期评估(LCA)这一综合评估方法，针对以天然气、煤或石油作为制氢能源的多种燃料电池氢源供应方式以及配套的燃料电池汽车系统，从经济性、能源利用效率和环境影响三个方面进行了生命周期清单分析和EEE综合评价。结果显示：天然气作为发展燃料电池汽车氢源的一次能源，具有氢制取技术路线多样化、经济上竞争力强、能源利用效率高和环境效益好等诸多优势，应为燃料电池汽车的首选制氢能源。对这一评估模型的敏感性分析显示，即使在天然气价格波动较大时，天然气制甲醇--甲醇车载重整车和天然气制氢--纯氢车这两个方案仍然最具优势。     

钢包炉(LF)预熔精炼渣的研究

预熔精炼渣具有成分均匀，性能稳定，储存时不吸水等特点，钢包炉中使用预熔精炼渣时成渣均匀且速度快，具有较强的吸附钢中非金属夹杂的能力。综合脱硫率高等冶金效果。有显著净化钢液作用。     

硫含量对钴钼型耐硫脱氧剂的脱氧活性影响

研究了工艺气中硫含量对钴钼型耐硫脱氧剂脱氧活性的影响。通过常压微反 -色谱装置测定脱氧剂的本征脱氧活性 ,加压原粒度反应器测定脱氧剂的表观脱氧活性 ,结合实际经验确定了耐硫脱氧剂所需的最低硫含量。还讨论了温度、压力、空速对耐硫脱氧剂脱氧活性的影响。结果表明 ,耐硫脱氧剂完全能满足耐硫变换工艺的要求 ,而且有耐硫变换的作用 ,并对耐硫变换催化剂起到保护作用     

铸铝激光熔融处理后的组织与性能

应用光学和电子显微镜及显微硬度计研究了铸造Al-Si合金经激光表面熔融处理后的组织和性能。指出,组织分熔化区、过度区和基体三层。在熔化区中树枝状先共晶α相的平均宽度由原始组织的20～40μm细化到2～3μm,同时共晶组织也被大大细化。这些变化使显微硬度值由67.4提高至109～115.     

尺寸驱动的变参设计系统研究

本研究在简介国际上先进的变参设计几种方法及优点后,叙述了一个国家863/CIMS项目:CAD/CAPP/NCP集成系统中二维尺寸驱动的变参设计子系统的构成与功能;然后着重阐述了本系统采用的尺寸驱动的变参设计思想和几何约束建立的原则,并提供了系统数据结构,最后以几个实例证明了此方法的正确性与工程实用性。     

中高频小功率电子元器件用非晶材料的开发与应用

随着电力和电子技术的飞速发展，相应的元器件向高频化，小型化，高效率和节能的方向发展，从而对元器件用材料也提出了更高要求。为此，本文概述了冶金部钢铁研究总院近年来所研究的用于开关电源，脉冲变压器，传感器，电流互感器和电感器等方面的非晶软磁合金的性能及其应用概况。     

Soliton position jitter caused by periodic amplification andself-frequency shift

The formula for soliton timing jitter due to self-frequency shift and pulse width fluctuations caused by spontaneous-emission noise has been deduced. Such timing jitter is compared with that caused by the carrier frequency shift due to spontaneous-emission noise. It is shown that the timing jitter due to the self-frequency shift can be as large as the timing jitter due to carrier frequency shift when the total transmission distance is 100 times longer than the soliton period