MC(Mid-Century)催化氧化过程的研究进展

介绍了MC催化氧化过程规律；从催化荆体系的改进、新型溶剂体系的开发、反应器构型和配套设施的改进、富氧氧化技术的开发等方面综述了近年来MC技术的发展；探讨了MC液相催化氧化技术应用范围的拓展以及MC液相催化氧化过程的发展方向。     

基于社会和文化可持续性的城市设计价值观重塑

可持续发展是环境、社会、经济和文化可持续性四个支柱之间的平衡发展.其中,无论是理论研究还是政策分析,社会可持续性和文化可持续性作为可持续发展的重要支柱一直受到忽视,城市设计领域也不例外.我们从社会可持续性和文化可持续性两个维度探讨了城市设计价值观的重塑问题.从社会可持续性视角看,城市设计需要建构以公平的空间资源分配为核心的价值观,具体表现在两个方面,即和谐宜居观与环境正义观.基于文化可持续性的城市设计价值观,核心是尊重城市文化多样性,它是城市保持活力的命脉以及城市可持续发展的源泉.     

Optimization of uncertain acoustic metamaterial with Helmholtz resonators based on interval model

Uncertainties existing in the acoustic metamaterial may strongly affect its unusual properties. Aiming at this actuality, the interval model is introduced to treat with uncertainties existing in the acoustic metamaterial with Helmholtz resonators. Frequency intervals in which the sound intensity transmission coefficients are certainly less than the required value and the effective bulk moduli are certainly negative are defined as conservative approximations. Frequency intervals in which the sound intensity transmission coefficients may be less than the required value and the effective bulk moduli may be negative are defined as unsafe approximations. The proportion of the conservative approximation and the unsafe approximation is defined as an approximate precision. Based on the quantification of uncertainties of the sound intensity transmission coefficients and the negative effective bulk moduli, an optimization model for the interval acoustic metamaterial with Helmholtz resonators is constructed. Numerical results showed that even suffering from effects of interval parameters, unusual properties of the optimized acoustic metamaterial (such as the bandgap of the sound transmission and the negative effective bulk modulus) could be improved.     

频率响应法研究噻吩在CeY分子筛上的吸附行为

以NaY、液相Ce离子交换改性的Y型分子筛(L-CeY)为研究对象,运用N2吸附、XRD、NH3-TPD和Py-FTIR等实验方法表征两种Y型分子筛的物化性能。采用频率响应技术(FR)和智能重量分析仪(IGA)研究噻吩在两种分子筛上的吸附行为,并考察噻吩在稀土离子改性Y型分子筛上的不同吸附作用模式。结果表明,频率响应技术能够有效识别分子筛孔道内发生的不同传质过程。噻吩在NaY分子筛上的吸附行为较为简单,存在孔道吸附和π电子相互作用两种吸附过程;而在L-CeY分子筛上吸附行为较为复杂,同时存在孔道吸附和"S-M"吸附等多种吸附过程,另外,在高温条件下,还存在复杂的催化反应过程。     

Dynamic buffering performance of the honeycomb paperboard filled with polyurethane

A new kind of composite buffering material was made by filling the voids of honeycomb paperboard with polyurethane. Drop tests were performed to evaluate the dynamic energy absorption capacity of the material. Based on the tests results, we analyzed the mechanical behaviors of the material under different conditions and obtained the inherent influencing laws of some factors on the material＇s dynamic buffering performance. It was shown that the dynamic buffering performance varied directly with impact velocity, and inversely with the void diameter, thickness and buffeting area of the composite material.     

安徽中小企业发展现状及创新路径研究

近几年,在政府大力扶持之下,安徽中小企业快速发展,已成为推动经济持续、健康发展的重要力量,但在发展过程中也存在一些不容忽视的问题。本文从企业总量、地区分布、企业产值、所有制类型等方面对安徽中小企业进行调查,在此基础上分析安徽中小企业在发展过程中存在的问题,并提出相应的建议和对策,对丰富中小企业发展理论、制定安徽中小企业发展政策具有一定的意义。     

南通高职院校学生创业状况研究

探讨了当前普及的大学生创业教育的成功与不足之处.采取发放问卷、走访创业机构和校园随访等方式综合获得南通地区高职生创业状况的调研结果,根据结果提出了相应对策,以期真正提升高职学生创业素养,提高他们的创业成功率.     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

硝硫混酸与Ag、Cu反应的动力学

用失重法探讨了硝硫混酸此例、浸出温度和时间等因素对银的溶解和铜的钝化的影响。结果表明:在一定的[HNO_3]范周内,较高温度时,银的溶解符合一级反应规律;求得银的溶解量与时间、HNO_3起始浓度等的关系式和相应的反应活化能;铜在此条件时是钝化的。本实验再一次证实了银的溶解和铜的钝化机理的正确性,也为银、铜的分离提供了实验依据。     

多媒体网络技术环境下大学英语教学模式的思考

随着多媒体网络技术引入大学英语教学 ,传统的教学模式面临极大的冲击。本文在学生中心论和建构主义学习理论的基础上 ,总结了基于多媒体网络的人机结合的教学模式。通过对比分析传统教学与多媒体网络教学班级学生的学期能力综合测试成绩 ,阐述了实施这种教学模式的制约因素和对策