吡咯对电沉积磷酸钙类复合涂层的生长方式的影响

利用电化学沉积的方法,在电解液中加入吡咯,制备了磷酸钙-聚吡咯复合涂层.结果表明:吡咯使涂层的生长方式发生了改变.未加入吡咯获得的单一的磷酸钙沉积陶瓷膜呈现无序排列,叶片状.电解液中加入吡咯后,陶瓷膜层有序排列,呈针状且整个膜层的晶粒增大.红外光谱分析表明,出现了C=C和N-H基团的伸缩振动吸收峰,说明吡咯已经由电解液中转移到涂层中.相分析表明:吡咯的加入并没有改变涂层的相组成,说明整个过程中仅有少量的吡咯进入涂层.     

如何有效提高PLC控制系统的可靠性

本文简述了影响PLC控制系统可靠性的主要因素,并就PLC的工作环境、电源的要求、接地和连接线的方式、冗余设计和降级操作设计、控制系统的输入电路和输出电路与PLC的软件程序编制等多个方面,提出了一些可行的方法和措施。     

氮化铝陶瓷研究和发展

从氮化铝陶瓷的制备工艺，即粉末的合成、成形、烧结3个方面详细介绍了氮化铝陶瓷的研究状况，指出低成本的粉末制备工艺和氮化铝陶瓷的复合形状成形技术是目前很有价值的氮化铝陶瓷的研究方向。     

电磁动态金属粉末注射成型型坯结构性能的研究

利用自行设计的电磁动态注射机DPII-90，对不锈钢金属粉末316L和粘结剂的混合喂料进行稳态和动态注塑成型实验，研究振动参数对金属粉末和粘结剂混合喂料的均匀化和密实机理的影响。实验结果表明，各动态成型条件下的型坯密度明显大于稳态成型条件下的密度。当振动频率（或振幅）不变时，随着振幅（频率）的增大，型坯密度呈非线性增大，达到最大值后缓慢下降，存在一个最佳值。在频率7Hz-10Hz，振幅50μm～150μm的范围内，注射出的型坯密度较高，密实性好。电镜扫描（SEM）发现，金属粉末与粘结剂的分散均匀和完善程度的变化规律和型坯密度随着振幅（频率）的变化规律基本一致。     

静高压作用下纯铝凝固过程温度场的数值模拟

采用数值模拟的方法,研究了纯铝在静高压作用下凝固过程温度场的变化情况。首先建立了温度场的数学模型,根据压力与金属熔点的关系,将压力作用到凝固过程的温度场上。模拟结果表明:压力越大,纯Al开始凝固的时间越早;在凝固过程中,压力越大,对应的温度变化速度越快。     

中铝河南分公司矿山公司可持续发展三步走战略

中铝河南分公司是个资源性企业．矿山公司的可持续发展有赖于铝土矿的基础性支撑．关键是解决好铝土矿资源的可持续开发利用问题。本文提出了资源调研、勘查、开发三步走的战略．并制定了每一步的实施方案和具体目标。     

层流等离子体射流铝合金表面熔覆SiCp/Al-Si涂层的磨损过程

采用层流等离子体炬作为加热热源，在ZL104铝硅合金表面制备镍包SiCp／Al-Si复合熔覆层。磨损过程中，该熔覆层中的SiCp颗粒微凸体对磨轮的切削产生的切屑，在熔覆层表面形成机械混合层(MML)，此机械混合层硬度较高，耐磨性好，使熔覆层在磨损过程中经历了较长距离的磨损孕育阶段，从而改变了铝合金的磨损过程，延缓了中等磨损向严重磨损的转变。     

两相区热处理对TC21钛合金显微结构的影响

采用金相显微镜和扫描电镜等手段，研究了固溶、固溶时效等热处理工艺对TC21钛合金显微组织的影响，确定了两相区热处理得到的显微组织，采用透射电镜、X射线衍射方法研究了TC21钛合金在两相区热处理的相组成。同时探讨了固溶温度、固溶时间、冷却方式以及时效处理对这种合金显微组织和相结构的作用。结果表明：在两相区进行热处理，均得到双态组织；相组成主要是α相、β相，并在TC21合金中发现含有少量金属化合物，如α2-Ti3Al相、B2相、Zr3Al、Si2Mo等；固溶温度影响了初生α相的体积分数和晶粒尺寸：固溶时间达到一定程度后，延长保温时间对显微组织没有明显影响；冷却速度影响声转变基体组织；时效也对β转变基体组织和次生α相有影响。     

Characterization of in situ synthesized TiC particle reinforced Fe-based composite coatings produced by multi-pass overlapping GTAW melting process

In this paper, in situ synthesized TiC particles reinforced Fe-based surface composite coatings by multi-pass overlapping gas tungsten arc welding (GTAW) melting process employing a proper amount of graphite and ferrotitanium (FeTi) on AISI 1020 steel substrate was produced. The microstructure and wear properties of the composite coatings were investigated by means of an electron microprobe microanalysis (EPMA), X-ray diffractometer and wear tester. The results showed that the multi-pass overlapping GTAW melting surface composite coatings can be obtained under suitable welding parameters, and no crack and porosity are found in the tracks. The X-ray and EPMA results confirm that TiC particles can be formed via reaction of FeTi and graphite during multi-pass overlapping GTAW melting process. TiC particles present cubic and dendrite shape in the non-overlapping zone. It is found that there occurred TiC particles coarsening at the overlap regions, which can lead to detrimental effects on the hardness and wear performance. Composite coatings give a high hardness and excellent wear resistance; and the wear friction coefficient of the coating is less than that of the 1020 steel. As a result, multi-pass overlapping GTAW melting process can be used effectively for producing surface composite coatings with a pre-placed powder to improve wear resistance of the AISI 1020 steel.     

Behavior of residual carbon in Sm(Co, Fe, Cu, Zr)z permanent magnets

When sintered Sm(Co, Fe, Cu, Zr)_z permanent magnets are prepared by metal injection molding, some organic binders are added in alloy powder, which leads to much residual carbon in the magnets. The residual carbon decreases magnetic properties and destroys the microstructure of the magnets. In this paper, the behavior of carbon in Sm(Co, Fe, Cu, Zr)_z permanent magnets has been studied. The results indicate that Sm(Co, Fe, Cu, Zr)_z magnets can keep excellent magnetic properties when the carbon content is below 0.1 wt.%: Br ≥ 10 kGs, H_cj ≥ 22 kOe, BH_max ≥ 25 MGOe. When the carbon content is above 0.1 wt.%, Br, H_cj and BH_max decrease with increasing carbon content evidently. Carbon consumes Zr content and forms ZrC, which reduces the volume fraction of the lamella and Sm(Co, Cu)₅ phases. Thus, the cell size increases and the cellular microstructure deteriorates. When the carbon content reaches 0.43 wt.%, there is not enough Sm(Co, Cu)₅ phase to form a uniform cellular microstructure. Br, H_cj and BH_max are approximate to zero. Since carbon has little influence on the content of Sm₂(Co, Fe)₁₇ phase, Ms can keep a high value (≥100 emu/g). ZrC has high melting point (3420 °C) and acts as dispersion particle in the magnets, which prevents the grains of SEM structure growing and reduces the liquid content of green compacts during sintering. Therefore, the density of the magnets decreases.