锤式破碎机在石灰石破碎中的改进

为解决双转子锤式破碎机在破碎石灰石时出现磨损等问题，采用了改进锤头、锤盘的结构和材质的方法，镶嵌合金棒的锤头、锤盘可以显著提高锤头、锤盘的使用寿命；改进的锤盘衬套结构型式能改善由于变形卡死锤轴的情况，减少了更换锤头的工作量，降低了企业生产维护成本。     

基于运动相关皮层电位握力运动模式识别研究

面向基于脑-机接口（Brain-computer interface,BCI）的脑-机交互控制（Brain-machine interaction control,BMIC）——直接脑控机器人,提出一种新的左、右手握力运动参数范式,在该范式下探索左、右手握力运动相关皮层电位/运动相关电位（Movement-related potentials,MRPs）的时域特征表示并识别握力运动模式.在涉及左、右手4个不同任务的实验中采集了11个健康被试的脑电信号,任务期间要求被试以2种握力变化模式之一完成自愿握力运动,每种任务随机重复30次.不同握力任务之间具有显著差异的运动相关电位特征用于识别握力运动模式.分别用基于核的Fisher线性判别分析和支持向量机识别4个不同的握力运动任务.研究结果进一步证实运动相关电位可以表征握力运动规划、运动执行和运动监控的脑神经机制过程.基于核的Fisher线性判别分析和支持向量机分别获得24±4%和21±5%的平均错误分类率.最小误分类率是12%,所有被试平均最小误分类率为20.9±5%.与传统的仅仅识别参与运动的肢体类型以及识别单侧肢体运动参数的研究相比,本研究可望为脑-机交互控制/脑控机器人接口提供更多的力控制意图指令,奠定了后续的对比研究基础.     

预测控制约束边界效应与解决方法研究

约束预测控制（Constrained model predictive control,CMPC）中,因约束的存在,优化过程中最优控制作用可能会在可行域的边界取值,也就是说会 有一个或多个变量饱和,即约束边界效应. 而过程控制中操纵变量饱和是我们不希望出现的. 对此,首先基于稳态模型,对期望值位于可行域内时最优解必在期望值处达到给出证明;同时证明了期望值在可行域外时最优解可转化为期望值到可行域的投影. 其次,针对变量在动态及稳态过程中饱和的情况提出了改善控制性能的措施——调整目标函数;终端约束的加入,为预测控制系统稳定性提供了保障. 通过对包含约束的连续搅拌釜式反应器（Continuous stirred tank reactor,CSTR）系统进行仿真实验,验证了所提方法的正确性,并说明了对目标函数进行适当调整,可有效改善系统的控制性能.     

基于线性时序逻辑的最优巡回路径规划

基于线性时序逻辑(Linear temporal logic, LTL)的路径规划方法中, 多点巡回路径规划问题尚无有效解决方案. 为了在道路网络中实现最优巡回监测, 提出了基于LTL的最优巡回路径规划方法. 首先, 将环境建模成一个切换系统, 用LTL语言描述包含多个巡回点和障碍物的任务需求; 接着, 利用循环移位法构建能够融合任务需求和环境模型的扩展乘机自动机, 以建立路径信息完整的网络拓扑; 最后, 采用基于迪科斯彻法的最优综合算法搜索扩展乘机自动机网络上的最优路径, 从而获得能够满足复杂任务需求的最优巡回路径. 仿真结果表明, 该方法能够有效实现最优巡回路径规划.     

无线传感网络中拥塞控制与路由的跨层设计:分布式牛顿法

无线传感网络应用广泛, 其性能与路由选择和拥塞控制密切相关. 致力于拥塞控制与多径路由的跨层优化, 以实现在链路容量受限和节点能量受限情况下的无线传感网络效用最大化. 针对对偶次梯度算法具有收敛速度慢与信息交互量大等缺陷, 设计了具有二阶收敛性能的分布式牛顿算法来实现网络效用最大化. 通过矩阵分裂技术, 实现了只需单跳信息交互的牛顿对偶方向的分布式求解方法. 仿真结果表明, 分布式牛顿算法的收敛性能显著优于对偶次梯度算法.     

Electrodeposition of Ni-transition alloys for the oxygen evolution reaction

The oxygen evolution reaction (OER) is the anodic reaction in several industrial electrolytic processes. The objective of this work was to develop a new electrocatalytic material for long-lasting and economical high performance electrodes. New electrodes were prepared by electrodeposition of nickel, nickel-ruthenium and nickel-iridium alloys. They were then activated by anodic polarization at 100 mA cm^–2 to form an oxide layer. The electrocatalytic activity was characterized for the OER in 5M KOH solution. The results show that nickel-iridium alloys provide greater electrocatalytic activity for the OER and better corrosion resistance than nickel-ruthenium in alkaline solution. The effects of transition elements on improving the performance of the nickel electrode are then discussed.Notation b Tafel slope - i _ex exchange current density - i _dp electrodeposition current density - i _OER oxygen evolution reaction current density - C _dl double-layer capacity - o₂ oxygen overpotential     

Solubility of Si3N4 in Liquid SiO2

The nitrogen solubility in the SiO₂-rich liquid in the metastable binary SiO₂-Si₃N₄ system has been determined by analytical TEM to be 1%–4% of N/(O + N) at 1973–2223 K. Analysis of the near edge structure of the electron energy loss peak indicates that nitrogen is incorporated into the silicate network rather than being present as molecular N₂. A regular solution model with a positive enthalpy of mixing for the liquid was used to match the data for the metastable solubility of N in the presence of crystalline Si₃N₄ and to adjust the computed phase diagram. The solubility of Si₃N₄ in fused SiO₂ is far less than reported in liquid silicates also containing Al, Mg, and/or Y. Apparently, these cations act as modifiers that break anion bridges in the silicate network and, thereby, allow further incorporation of Si₃N₄ without prohibitive amounts of network cross-linking. Finally, indications emerged regarding the diffuse nature of the Si₃N₄-SiO₂ interface that leads to amorphous regions of higher N content.     

高效节能水力旋流器研究进展

综合介绍了国内外高效节能水力旋流器的研究进展,分析了影响旋流器分离性能和能耗的主要因素,介绍了针对不同问题提出的相应解决办法.对其迄今的研究成果进行了简要评述,并对其发展进行了展望。     

从假性紫罗兰酮合成β-紫罗兰酮中主要副产物(I)的分离鉴定

假性紫罗兰酮在浓硫酸及 - 2 0°C低温条件下反应 ,主要生成 β-紫罗兰酮 ,少量的 α-及 γ-紫罗兰酮 ,同时生成副产物 ( I)及 ( II)。用 IR、1H NMR及 MS光谱分析方法 ,对副产物 ( I)进行了结构鉴定 ,结构为 3,4,4a,5 ,8,8a-六氢 - 2 ,5 ,5 ,8a-四甲基 - 2 H - 1 -苯并吡喃     

电化学界面处离子分布、静电势和ξ势的研究

Density functional theory is applied to predicting the structures and electrostatic potentials of planar electrochemical surfaces within the framework of the restricted primitive model where small ions are represented by charged hard spheres of equal diameter and the solvent is assumed to be a continuous dielectric medium. The hard-sphere contribution to the excess Helmholtz energy functional is evaluated using the modified fundamentalmeasure theory and the electrostatic contribution is obtained from the quadratic functional Taylor expansion using the second-order direct correlation function from the mean-spherical approximation. Numerical results for the ionic density profiles and the mean electrostatic potentials near a planar surface of various charge densities are in excellent agreement with molecular simulations. In contrast to the modified Gouy-Chapman theory, the present density functional theory correctly predicts the second layer formation and charge inversion of charged surfaces as observed in simulations and in experiments. The theory has also been tested with the zeta potentials of positively charged polystyrene particles in aqueous solutions of KBr. Good agreement is achieved between the calculated and experimental results.