A force modulation study on crystallization process in ferroelectric vinylidene fluoride and trifluoroethylene copolymer films

This paper introduces the Force Modulation technique to the study of crystallization process in ferroelectric vinylidene fluoride and trifluoroethylene copolymer films. Using this technique we have successfully visualized ferroelectric crystalline domains and observed that these ferroelectric domains grow out from amorphous phase, unite into strip-like structures, and finally congregate into a union. Force Modulation can weaken the influence of topography on imaging of ferroelectric domains, and reveal more details, which are difficult to be observed in topographical image.     

曹店灌区渠道防渗衬砌技术研究

详细介绍了引黄灌区干渠衬砌试验段的设计原则、方案以及冻胀观测技术 ,根据试验结果对不同防渗材料、不同结构形式的渠道衬砌方案的使用效果及经济指标进行了分析。     

FBOLES—outline of a frequency-based on-line expert system approach for fault diagnoses in nuclear power plants

The basic concept of a novel frequency-based on-line expert system (FBOLES) approach for on-line fault diagnoses in nuclear power plants has been presented previously. This paper reports further progress, and includes how to express the uncertainties of expert opinion in knowledge-bases and propagate then in inferences, and how to deal with imperfect knowledge-bases. It also describes the main elements of FBOLES and outlines how the system works under complex conditions including the dynamic behavior of signals during accidents, multiple failures, and on-line changes of plant operation mode. Its ability to diagnose root causes of accidents has been tested using the main steam and feedwater condensate systems of a full-scale, three-loop, 950 MW nuclear power plant simulated by the Tsinghua simulator. So far the results seem good.     

杀菌剂苯菌灵的结构鉴定及其核磁共振研究

用红外、质谱、核磁共振等手段确证了江阴农药厂合成的苯菌灵的化学结构,并进行了该化合物核磁共振谱线的归属。     

机载扫描成象系统的技术发展

叙述了机载扫描成象系统的发展,基本结构,特点及其应用.     

薄管板换热器的设计及薄管板计算的探讨

结合化肥厂丁辛醇装置薄管板换热器的设计 ,着重分析薄管板的特点 ,应用合理的计算方法对薄管板进行强度校核 ,验证这一新型换热器的安全性和经济实用性     

Synthesis of p‐aminophenol from the hydrogenation of nitrobenzene over metal–solid acid bifunctional catalyst

BACKGROUND: A single‐step conversion of nitrobenzene (NB) to p‐aminophenol (PAP) through catalytic hydrogenation is a widely used synthesis route for PAP. The main shortcoming of this route is the use of sulfuric acid for rearrangement of the phenylhydroxylamine (PHA) intermediate. In this paper, S₂O₈^2?/ZrO₂ (PSZ) solid acid and Pt‐S₂O₈^2?/ZrO₂ (Pt‐PSZ) bifunctional catalysts were prepared for the synthesis of PAP in non‐acid medium. RESULTS: Calcination temperature has a substantial effect on the acidity, structure and activity for PHA rearrangement of PSZ. The highest PAP yield was 33.8% over PSZ calcined at 823 K when the reaction was carried out in water at 423 K. A high PAP yield of 23.9% was achieved by a single‐step reaction of nitrobenzene over Pt‐PSZ bifunctional catalysts. CONCLUSION: PSZ solid acid exhibits high activity for PHA rearrangement. Perfect tetragonal ZrO₂ and much stronger acid sites play important roles in catalytic activity. Inhibiting the hydrogenation activity by reducing the amount of Pt loading on Pt‐PSZ can improve the competition of PHA rearrangement on acid sites with hydrogenation of PHA on metal active sites, resulting in better selectivity to PAP. Copyright © 2008 Society of Chemical Industry     

谈如何建设高素质施工管理人员队伍

阐述了以“三个代表”要求建设高素质施工管理人员队伍的必要性 ,指出只要尊重知识、尊重人才 ,建立和完善激励机制 ,就能激发广大管理人员的积极性、主动性和创造性     

电子工业用高纯氮的生产

生产电子工业用高纯氮的制氮装置 ,其要点和难点是一氧化碳和氢的清除。采用一氧化碳转换炉和特殊的冷箱内流程组织 ,可以生产纯度为 99 9999%以上的高纯氮。对制取电子工业用高纯氮制氮装置与常规制氮装置加氮终端净化器两种流程进行了比较。     

CO毒化AB5型合金分形特征研究

研究了三种贮氢合金 L a Ni5、L a Ni4 .7Al0 .3、Ml Ni4 .5Al0 .5被 10 0× 10 - 6 CO毒化后的分形特征 ,求出这三种合金在含 10 0× 10 - 6 CO的氢中循环 ,分维分别为 0 .2 5 4 7、0 .170 9、0 .0 72 5。可以较好的解释合金被毒化的宏观现象。