抗蚜威原药和制剂的气相色谱分析

本文报道了抗蚜威的气相色谱分析方法，其标准偏差为０．０１９，变异系数为０．２４４％，回收率为９９￣１０１％，适于抗蚜威原药和制剂的分析。     

Flow field analysis of the kneading disc region in a co-rotating twin screw extruder

Co-rotating, intermeshing twin screw extruders are widely used in polymer compounding and blending. Among the different modules of the co-rotating twin screw extruder, the kneading discs are the dominant ones in determining mixing efficiency. The major difficulty in solving the flow problem in the kneading disc region arises from the complex geometry and the time-dependent flow boundaries as the discs rotate. In this work, a fluid dynamics analysis package—FIDAP—using the finite element method was employed to simulate the flow patterns in the kneading disc region of a Werner & Pfleiderer ZSK-30 co-rotating twin screw extruder. The problem of time dependent flow boundaries was solved by selecting a number of sequential geometries to represent a complete mixing cycle. The flow field was characterized in terms of velocity profiles, pressure distributions, shear stresses generated and a parameter λ quantifying the elongational flow components. The last two parameters are the most important ones in analyzing mixing efficiency. The influence of design variables (stagger angle, right or left handed configuration) and processing conditions (rpm, axial pressure gradient) on the flow characteristics was analyzed.     

薄板坯连铸浸入式水口结构数值模拟

使用有限元计算方法开展薄板坯连铸浸入式水口流场的研究 ,分别对水口不同浸入深度的流场分布、水口出口不同角度的流场分布进行计算。结果发现 :水口的浸入深度在 30 0mm时较为合理 ;水口的出口角度以R1 5、60°、45°为宜     

低浓度的阴离子洗涤剂实验室内的质量控制

在环境监测中低浓度的阴离子洗涤剂实验室内质量控制应采取以下措施：空白试验值测定，检出限的确定，空白试验的质量控制图，校准曲线的检验，标准样品的测定。     

Effect of preparation conditions on the properties of a coal-derived activated carbon honeycomb monolith

Activated carbon honeycomb (ACH) monoliths were prepared by extruding of a mixture of bituminous coal and organic additives and subsequent carbonization and steam activation. Preparation parameters that were varied were carbonization temperature and activation time. The carbonization conditions were 500, 650 and 800 °C for 1 h and the steam activation conditions were 850 °C for 2, 4 and 6 h. The monoliths at various states were characterized by SEM, XRD, nitrogen adsorption and compression test. It was found that carbonization temperature has significant effects on pore size distribution and mechanical strength of ACH monoliths. The ACH monoliths prepared from high carbonization temperatures exhibited lower values of the BET surface area and total pore volume and higher value of the mechanical strength than those of the ACH monoliths prepared from low carbonization temperatures. This was attributed to the effect of high temperature carbonization that results in the formation of relatively less defective structures.     

磷钨钼杂多酸掺杂聚苯胺催化合成丁醛乙二醇缩醛

报道了以磷钨钼杂多酸掺杂聚苯胺为催化剂,通过丁醛和乙二醇反应合成了丁醛乙二醇缩醛。系统考察了醛醇物质的量比、催化剂用量以及反应时间诸因素对产品收率的影响。确定适宜的工艺条件为n(丁醛)∶n(乙二醇)=1∶1.5,催化剂的质量为反应物料总质量的0.8%,反应时间1.0 h。在此反应条件下,丁醛乙二醇缩醛的收率可达71.1%。     

CO还原液态铁氧化物的动力学研究

在1678K的温度下测定了用CO或CO与Ar的混合气体还原浮士体的反应速度浮士体放在纯铁坩埚中，还原速度是根据红外CO2气体分析仪所测出的CO2生成量来求出的．实验表明表现还原速度正比于气体中CO分压，并与气体流量的1．59次方有关，反应的前或其速度是由气相的传质速度所控制，化学反应的速度常数最小为60（g／atm·min·cm2）．     

干熄焦循环气体成分的分析和控制

分析了干熄焦循环气体成分，针对可燃气体成分爆炸的极限值，控制及制定循环气体成分的指标。     

HEAT TRANSFER IN PARTIALLY MISCIBLE TERNARY SYSTEMS

In the study of mass transfer between partially miscible liquids, temperature perturbations have been found to have an important effect in the generation of interfacial activity. Micro- and macro-generated interfacial convection usually occurs in combination with one another even in fairly simple heat or mass transfer events. These combinations are responsible for the enhancement of mass transfer rates. In an effort to acquire a better understanding of the heat transfer effects in ternary liquid-liquid systems, temperature difference profiles were measured when contacting two partially miscible phases. A vertical and a rotational transfer cell were designed to contact the partially miscible phases without inducing external disturbances. Five thermocouples were immersed in the bottom liquid phase at predetermined positions below the interface. In order to understand the influence of the convection generated, the vertical cell was designed to hinder convection in one phase, while the rotational cell permits convection in both phases. The experimental results showed larger temperature differences in the rotational cell after the contact of the phases. Also, systems which were initially unsaturated presented larger heat effects than those in which the partially miscible solvents were initially saturated. Several parameters indicating the importance of heat effects in the ternary systems studied are reported.