水乳型丙烯酸酯建筑防水胶的研制(Ⅱ)

摘 要 研究水乳型丙烯酸酯建筑防水胶与水泥的配比及共混性能、共混固化物胶膜的力学性能、耐冷热性能及老化性能。     

In—situ Composite Based on Poly （ethylene terephthalate）,Polyamide and Polyethylene with Microfibres Formed through Extrusion and Hot Stretching

In-situ composites based on dispersed poly (ethylene terephthalate) (PET) or polyamide (PA),and continuous Polyethylene (PE) were prepared through a single screw extruder of Haake rheometer system with a rod-die relatively small in diameter.The extrudate was drawn at a drawing ratio of 3.1,and then quickly cooled in cold water.The specimens were obtained by injection molding at processing temperatures less than 190℃，far below the melting temperature of PET (265℃) and PA (230℃),which can maintain the solid state of PET and PA microfiber phase in the composites.Morphological observation with scanning electron microscopy (SEM) indicated that PET and PA can more or less form in-situ microfibers at compositions studied (0-20 wt pct PET or PA),and especially,PET and PA were almost deformed into fibers at the concentration of 15wt pct.Eensile strength and especially.PET and PA were almost deformed into fibers at the concentration of 15wt pct.Tensile strength and modulus of the blends reinforced by PET or PA microfibers showed to be increased from the tensile test results.The most noticeable improvement of the tensile properties occurred at 15wt pct of PET in PET/PE system,corresponding to the highest microfiber content,where the tensile strength reached 32.5 MPa,whereas only 19.5 MPa for the pure PE.     

Electrorheological Fluids Based on Titania Particles Coated with Silica and Their Application in Smart Windows

The electrorheological (ER) fluids are colloidal suspension of highly polarizable particles in a non-conducting solvent.Chains of submicron-sized particles formed along an applied DC electric field by the so-called electrorheological effect.According to the obvious change of transmittance of the ER fluids in a DC electric field when the polarized particles arranged along the field,the model of smart window was proposed by sandwiching the ER fluids based on titania particles coated with silica between a pair of In-Sn oxide (ITO) coated glasses.The solar transmittance change as much as 48.0% was obtained with the wavelength of 500 nm at the maximum on applying and removing the electric field of 500V/mm.     

纳米氧化铝的制备及应用

介绍了高科技产品纳米氧化铝的 3大制备方法 :固相法、气相法、液相法的优缺点 ,以及纳米氧化铝的应用与发展前景     

液相色谱法测定萘普生中间体1-(6-甲氧基-2-萘基)乙醇

建立了萘普生中间体 1 (6 甲氧基 2 萘基 )乙醇的高效液相色谱分析方法。流动相 :甲醇 +水 =80 + 2 0 (v/v ) ,在C18柱上UV 2 38nm下测定其含量 ,方法精密度为 0 19,变异系数为 0 2 7% ,回收率在 98 5 %～ 10 0 4 %之间     

光学全交叉网络与SW榕树（F＝S＝2）网络拓扑等价的多样性

本文对有关互连网络拓扑等价的分析方法作了简单评述。并采用互连网络拓扑等价的图分析法分析了自由空间光学互连全交叉网络与ＳＷ榕树网络的拓扑等价及其多样性，拓展了全交叉网络在数字光计算、光子交换及多处理机系统的潜在应用。     

缓冲层对氮化镓二维生长的影响

报道了在射频等离子体（RF-Plasma)辅助的分子束外延（MBE）技术中，使用白宝石（0001）衬底，采用低温缓冲层工艺外延氮化镓（GaN)。通过原子力显微镜（AFM）的表面形貌比较及X射线双晶衍射（XRD）ω扫描摇摆曲线的分析，讨论了低温缓冲层成核机理及缓冲层生长温度与形成准二维生长的关系，确立了缓冲层的三维成核，准二维生长的生长机理，并在此基础上实现了氮化镓外延层更好地二维生长，进一步提高了氮化镓外延层的晶体质量。     

发射极δ掺杂的InGaAs/InPDHBT的特性分析

设计了一种新结构的InGaAs/InP双异质结晶体管(DHBT),其中发射结采用δ掺杂和阻挡层结构,集电极采用N+掺杂复合结结构.考虑隧穿作用和发射结空间电荷区复合电流的影响,计算了δ掺杂浓度和N+、n-层厚度等参数变化对InGaAs/InP DHBT电流、I-V输出特性、电流增益的影响,计算结果表明,随着这些参数值增大,InGaAs/InP DHBT输出特性逐渐改善.当δ掺杂浓度大于2×1012cm-3时,电流增益趋于饱和.     

Synthesis and aqueous solution behaviors of sodium sulfonate‐terminated dendritic poly(ester‐amine)

Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO₃) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, ¹H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008