Influence of operating parameters on photocatalytic degradation of phenol in UV/TiO2 process

The use of hydrogen peroxide (H₂O₂) for improved photocatalytic degradation of phenol in aqueous suspension of commercial TiO₂ powders (Degussa P-25) was investigated. Photodegradation was compared using direct photolysis (UV alone), H₂O₂/UV, TiO₂/UV, and H₂O₂/TiO₂/UV processes in a batch reactor with high-pressure mercury lamp irradiation. The effects of operating parameters such as catalyst dosage, light intensity, pH of the solution, the initial phenol, and H₂O₂ concentrations on photodegradation process were examined. It was shown that photodegradation using H₂O₂/TiO₂/UV process was much more effective than using either H₂O₂/UV or TiO₂/UV process. The effect of the initial phenol concentration on TOC removal was also studied, demonstrating that more than 8 h was required to completely mineralize phenol into water and carbon dioxide. For all the four oxidation processes studied, photodegradation followed the first-order kinetics. The apparent rate constants with 400-W UV ranged from 5.0 × 10⁻⁴ min⁻¹ by direct photolysis to 1.4 × 10⁻² min⁻¹ using H₂O₂/TiO₂/UV process. The role of H₂O₂ on such enhanced photodegradation of phenol in aqueous solution was finally discussed.     

Thermally and mechanically enhanced epoxy resin‐silica hybrid materials containing primary amine‐modified silica nanoparticles

In this article, a series of hybrid materials consisted of epoxy resin matrix and well‐dispersed amino‐modified silica (denoted by AMS) nanoparticles were successfully prepared. First of all, the AMS nanoparticles were synthesized by performing the conventional acid‐catalyzed sol–gel reactions of tetraethyl orthosilicate (TEOS), which acts as acceded sol–gel precursor in the presence of 3‐aminopropyl trimethoxysilane (APTES), a silane coupling agent molecules. The as‐prepared AMS nanoparticles were then characterized by FTIR, ¹³C‐NMR, and ²⁹Si‐NMR spectroscopy. Subsequently, a series of hybrid materials were prepared by performing in situ thermal ring‐opening polymerization reactions of epoxy resin in the presence of as‐prepared AMS nanoparticles and raw silica (RS) particles (i.e., pristine silica). AMS nanoparticles were found to show better dispersion capability in the polymer matrices than that of RS particles based on the morphological observation of transmission electron microscopy (TEM) study. The better dispersion capability of AMS nanoparticles in hybrid materials was found to lead enhanced thermal, mechanical properties, reduced moisture absorption, and gas permeability based on the measurements of thermo gravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and gas permeability analysis (GPA), respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Induced Pluripotent Stem Cell-Derived Conditioned Medium Promotes Endogenous Leukemia Inhibitory Factor to Attenuate Endotoxin-Induced Acute Lung Injury

The conditioned medium of induced pluripotent stem cells (iPSC-CM) can attenuate neutrophil recruitment and endothelial leakage of lipopolysaccharide (LPS)-induced acute lung injury (ALI). Therefore, we investigated the mechanisms by which iPSC-CM regulate the interaction between neutrophils and the endothelium in ALI. Murine iPSCs (miPSCs) were delivered intravenously to male C57BL/6 mice (8–12 weeks old) 4 h after intratracheal LPS injection. A miPSC-derived conditioned medium (miPSC-CM) was delivered intravenously to mice after intratracheal LPS injection. DMSO-induced HL-60 cells (D-HL-60, neutrophil-like cells) and human umbilical vein endothelial cells (HUVECs) were used as in vitro models to assess the interaction of neutrophils and endothelial cells. miPSC-CM diminished the histopathological changes in the lungs and the neutrophil count in bronchoalveolar lavage fluids of ALI mice. miPSC-CM attenuated the expression of adhesion molecules in the lungs of ALI mice. Human iPSC conditioned medium (hiPSC-CM) reduced the expression of adhesion molecules in a HUVEC and D-HL-60 co-culture after LPS stimulation, which decreased the transendothelial migration (TEM) of D-HL-60. A human angiogenesis factors protein array revealed that leukemia inhibitory factor (LIF) was not detected in the absence of D-HL-60 and hiPSC-CM groups. hiPSC-CM significantly promoted the production of endogenous LIF in in vitro models. Administration of an anti-LIF antibody not only reversed the effect of iPSC-CM in ALI mice, but also blocked the effect of iPSC-CM on neutrophils TEM in in vitro models. However, a controlled IgG had no such effect. Our study demonstrated that iPSC-CM promoted endogenous LIF to inhibit neutrophils TEM and attenuate the severity of sepsis-induced ALI.     

Oil sensitivity and its asymmetric impact on the stock market

We develop a two-step methodology to facilitate an examination of the impact of oil shocks on stock returns. Oil price volatility is monitored in this study through the use of a regime-switching model, with the presence of jumps subsequently being taken into consideration to examine the asymmetric effects of oil prices on stock returns. Our analysis provides quite conclusive results based upon the use of a regime-switching model with consideration of jumps; that is, when there are significant fluctuations in oil prices (West Texas Intermediate; WTI), the resultant unexpected asymmetric price changes lead to negative impacts on S&P 500 returns. However, the same result does not hold in a regime of lower oil price fluctuations. We therefore suggest that the achievement of a well diversified portfolio should involve the consideration of oil price shocks, which, as a consequence, should also help to improve the accuracy of hedging against oil price risks.     

Comparison of potential water supply and demand in Taiwan

The authors estimated the potential water supply in Taiwan based on hydrologic and water resource data sets pertaining to 233 rainfall stations, 145 stage stations and 109 reservoirs. The comparison between potential water supply estimates and predicted water demand indicated a slight water shortage, even though Taiwan normally receives a large amount of rainfall. This predicted water shortage likely occurred due to the uneven distribution of rainfall in Taiwan. Taken together, the results of this study demonstrate the importance of conservation of forests and paddy fields for the maintenance of base flow and effective management of reservoirs in Taiwan.     

Electromigration in sputtered copper film on plasma-treated hydrogen silsesquioxane dielectric

Electromigration (EM) damage is one of the major causes for the failure of interconnects. Plasma treatment, such as dry etching, is frequently employed in the fabrication of multilevel interconnection patterns. This work investigates the hydrogen silsesquioxane (HSQ) and copper integrated systems and the effect of H₂ plasma treatment on the EM of Cu. Hydrogen plasma bombardment induces a rough HSQ surface and results in a coarse morphology of the Cu film deposited on HSQ. The crystallographic texture of Cu is also affected by the plasma treatment. A decrease in the Cu I(111)/I(200) peak ratio is observed for a specimen treated with H₂ plasma. The activation energy for EM in Cu and the EM lifetime of the Cu interconnect decreases with an increased degree of plasma treatment. The activation energies obtained, ranging from 0.76 eV to 0.94 eV, suggest that the electromigration in copper proceeds via an interfacial diffusion path. Possible mechanisms for the effects of plasma treatment are explored. The rough surface and the retarded Cu (111) orientation induced by H₂ plasma bombardment are the major causes for the decrease of activation energy and EM lifetime.     

Dual-band planar inverted F antenna for GSM/DCS mobile phones

A compact dual-band planar inverted F antenna suitable for the application as a global system for mobile communication/digital communication system (GSM/DCS) dual-band mobile phone internal antenna is proposed and implemented. The proposed antenna has three resonant elements, two meandered metallic strips of slightly different lengths and one nearly-rectangular patch, which are printed on a supporting FR4 substrate and arranged in a compact configuration. These three resonant elements share a common shorting pin, and for the GSM (890-960 MHz) operation, the proposed antenna is operated with the two meandered strips both resonated as a quarter-wavelength structure, leading to a wide bandwidth formed by two resonant modes. For the upper band of the proposed antenna, three resonant modes are generated, two from the second higher-order modes of the two meandered strips and one from the nearly-rectangular patch, leading to a wide bandwidth covering the DCS band (1710-1880 MHz). The antenna design and experimental results are presented.     

Simulations for thermal warpage and pressure nonlinearity of monolithic CMOS pressure sensors

The operation function of a piezoresistive pressure sensor utilizes a voltage output to detect the magnitude of pressure. The basic design concept for monolithic pressure sensors is to fabricate a standard submicron CMOS process with appropriate modifications to integrate on-chip signal conditioning circuits with anisotropic-etched piezoresistive sensing elements. In this study, thermal stress simulations with applied pressure loadings are used to estimate the electromechanical behavior of a new monolithic sensing element concept design. The major tasks are to predict the ripple deformation of a silicon diaphragm due to the thermal residual stresses from multiple passivation layers and estimate the pressure nonlinearities on the transducer. More detailed approaches with design and performance concerns are also discussed.     

Experimental study of forced convective boiling for non-azeotropic refrigerant mixtures R-22/R-124 in horizontal smooth tube

In this article, the experiment is carried out with four stages of test section and new experimental data of non-azeotropic refrigerant mixtures R-22/R-124 are presented. Existing correlations are analysed and new ones are proposed for pure refrigerants. The nucleate boiling correlation of the refrigerant mixtures is modified so as to obtain the evaporation heat transfer coefficient of the refrigerant mixtures in a smooth tube. The result shows that the majority of the predictions fall within ±30% of the experiments.