Study on the long‐term thermal‐oxidative aging behavior of polyamide 6

The long‐term thermal‐oxidative aging behavior of polyamide 6 (PA6) was studied by comparison with the stabilized sample in this work. The variation of mechanical properties of the pure and the stabilized samples of PA6 with aging time at 110°C, 130°C, and 150°C were investigated, respectively. The aging mechanism of PA6 under heat and oxygen was studied in terms of the reduced viscosity, crystallization behavior, dynamic mechanical behavior, and chemical composition through the methods of polarized light microscopy (PLM), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), X‐ray photoelectron energy spectrum (XPS), and so on. The results indicated that at the initial stage of aging, the molecular crosslinking reaction of PA6 dominated resulting in the increase of the mechanical strength, reduced viscosity, and the glass transition temperature of the sample. And the molecular degradation dominated in the subsequent aging process resulting in the decrease of the melting temperature, the increase of the crystallinity, and the formation of the oxides and peroxides products. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Thermal stabilization effect of biphenol monoacrylate on polyamide 6

Biphenol monoacrylate (AL) was combined with a traditional hindered phenolic‐based binary antioxidant system to form a ternary stabilization system for the purpose of further improving the thermal–oxidative stability of polyamide 6 (PA6). The thermal stabilization effect of the antioxidant AL on PA6 was studied in terms of the reduced viscosity, the chemical structure, the yellow index, and the mechanical properties. The results showed that the antioxidant AL, with the proper chemical structure, could improve the thermal stability of PA6 effectively through a unique bifunctional stabilizing mechanism. The interaction of the molecules of PA6 with the antioxidant AL was investigated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

DH-2催化剂在尿素装置脱氢反应器的应用

简要介绍了塔西南化肥厂尿素原料气脱氢系统工艺,改用国产DH-2催化剂对系统进行的改进及实际应用情况.对国产催化剂应用前后的工艺情况--脱氢效果、反应器压差及床温进行了分析、评价,认为:用该催化剂取代进口催化剂是成功的,完全能满足工艺要求.     

智能数显仪在生产中的应用

利用智能数显仪的万能输入、变送输出和控制输出功能,不仅可以实现加热站采暖温度根据大气温度自动调节的方案,而且通过改进可以实现硝酸透平压缩机轴位移联锁控制和应用于制作栲胶溶液槽上的液面计.     

首钢2号高炉的技术进步

介绍首钢2号高炉大修采用的新技术、开炉操作和投产以来的生产情况。     

种分Δα_k与精液Al_2O_3浓度的关系

对烧结法和拜尔法种分槽的Δαk 变化进行了概述 ,阐述了精液Al2 O3 浓度关系到晶种分解的产出率、分解率、氢氧化铝粒度及系统的液量平衡、能耗等 ,生产中要把握这些影响因素 ,确保氢氧化铝晶体的长大速度为正值。     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

90平米开启住宅新时代

大力发展90平米以下中小套型住宅，不仅具有重大的现实意义，而且将对我国住宅建设的发展产生深远的影响。[编者按]