Novel Hyperbranched predominantly Alternating Copolymers Made From A Charge Transfer Complex monomer pair of p-(chloromethyl)styrene and Acrylonitrile via Controlled Living Radical Copolymerization

Summary Novel hyperbranched copolymers were successfully synthesized by the controlled charge transfer complex inimer and living radical copolymerization of p-(chloromethyl)styrene (PCMS) and acrylonitrile (AN). The resulting copolymers were characterized by SEC, NMR, FTIR, DSC and elemental analysis etc.. The influences of reaction conditions, such as the polymerization temperature, the catalyst (CuBr) concentration and the monomer ratio, on the resulting copolymers were investigated in detail. The monomer reactivity ratios were evaluated to be r_PCMS=0.937 and r_AN=0.088 respectively by the Fineman-Ross method. The higher are the polymerization temperature and the ratio of catalyst to monomer, the higher is the branching degree of the resulting copolymer. When the amount of monomer AN was used in excess than that of the monomer PCMS in the raw feed, the hyperbranched predominantly alternating copolymers HP[PCMS-co-AN] could be obtained. These hyperbranched copolymers were successfully used as functional macroinitiators to synthesize the star-shaped poly(PCMS-co-AN)/poly(MMA) block copolymers.     

Tracking Control and Synchronization for Two-Dimension Discrete Chaotic Systems

1　ＩｎｔｒｏｄｕｃｔｉｏｎＳｉｎｃｅ 1 990 ,ｃｈａｏｔｉｃｓｙｎｃｈｒｏｎｉｚａｔｉｏｎ[1～ 4] ａｎｄｃｈａｏｔｉｃｃｏｎｔｒｏｌｌｉｎｇ[5～6] ｈａｖｅｒｅｃｅｉｖｅｄａｇｒｅａｔｄｅａｌｏｆａｔｔｅｎｔｉｏｎ[7～1 1 ] ,ａｎｄｃｈａｏｔｉｃｓｙｎｃｈｒｏｎｉｚａｔｉｏｎｉｓａｐｈｅｎｏｍｅｎｏｎｏｆｉｎｔｅｒｅｓｔｉｎｆｉｅｌｄｓｆｒｏｍｅｌｅｃｔｒｏｎｉｃｓｔｏｃｏｍｍｕｎｉｃａｔｉｏｎ[1 2 ] ,ａｎｄｆｒｏｍｂｉｏｐｈｙｓｉｃｓｔｏｎｅｕｒｏ ｓｃｉｅｎｃｅ[1 3] .Ｉｆｃｈａｏｔｉｃｓｙｎｃ…     

泥沙输移矢量式及其应用

本文基于Parker等人泥沙输移矢量式的分析和研究，增加了上举力的作用，并考虑了泥沙颗粒受力非平衡条件，采用牛顿力学的矢量分析法，推导了泥沙输移的通用矢量式。经对公式简化，且用Ikeda和笔者试验资料的验证，证明计算值与试验值吻合较好。     

一种新的机器人手臂控制方法

从机器人手臂的关节电机力学出发，本文提出了一种独立于现行机器人关节控制器的离线补偿方法，通过对－２自由度机器人的数值研究，证明该法不仅能有效地克服由于惯性负载，关节间耦合与重力效应给控制系统带来的动态精度问题，而且还可以消除由于控制系统本身的固有特性所决定的系统的跟踪误差。     

高发射率节能涂料及其应用

讨论了高发射率涂料节能的条件，了一种在1000℃仍保持高发射率的优质涂料，并解决了涂料与金属基体的粘结工艺，用此涂料制成增强辐射电阻带和复合炉衬，得到的新炉比旧炉节能20－40％。     

某型杀伤枪榴弹引信弹道炸原因分析及再设计思考

通过对某型杀伤枪榴弹引信所发生的三次弹道炸的原因进行分析，提出用延期索替代延期药盘，并对有关机构进行再设计的对策。     

蒸汽发生器二次侧清洁度的视频检查

立式平管板Ｕ形管束的压水堆核电站蒸汽发生器安装至瞬变工况期间，管板上表面的铁基金属残余物的堆积和外来物的存在，以及商业运行后管板、传热管、管子支撑板等的低流速区域里沉积物的堆积要求进行蒸汽发生器的清洁度检查。介绍了蒸汽发生器二次侧清洁度的视频检查技术。该技术适用于蒸汽发生器安装至瞬变工况和投入商业运行后可能发生污染的各阶段的清洁度检查。     

气体绝缘封闭电器的高速瞬变过程和现场试验

随着ＧＩＳ的工作电压不断提高和发展，一系列新的现象和问题也同时出现。从国外一些科研，设计，制造部门所研究发表的内容看，大致有隔离开关操作和高速瞬变过程，粒子影响和对干扰定位的技术，元件的监督，现场试验等课题，本文对以上问题加以综合介绍。