Direct C–H bond sulfenylation of (Het)arenes using sulfonyl hydrazides as thiol surrogate: a review

Sulfonyl hydrazides are easily accessible, non-toxic, stable and extremely valuable compounds in organic synthesis that are extensively utilized as sulfonylating and arylating agents (through the cleavage of their sulfur–nitrogen and carbon–sulfur bonds, respectively) for the synthesis of diverse range of biologically active molecules such as biaryls, sulfones, and sulfonamides. These compounds have also been broadly used as environmentally friendly, stable, and odorless sulfenylation agents (through the cleavage of their sulfur–nitrogen and sulfur–oxygen bonds) in the synthesis of synthetically and biologically important thioether derivatives. In this review, we will highlight the most important advances and explorations in the direct C–H bond sulfenylation of (het)aromatic compounds with these compounds during the period 2013 to October 2018. Particular emphasis is placed on the mechanistic aspects of the reactions.     

Enhanced Tacit Secrets: System-assigned passwords you can’t write down,but don’t need to

International Journal of Information Security - We explore the feasibility of Tacit Secrets: system-assigned passwords that you can remember, but cannot write down or otherwise communicate. We...     

Exploration of Advanced Electrode Materials for Approaching High‐Performance Nickel‐Based Superbatteries

The surging interest in high performance, low‐cost, and safe energy storage devices has spurred tremendous research efforts in the development of advanced electrode active materials. Herein, the in situ growth of zinc–iron layered double hydroxide (Zn–Fe LDH) on graphene aerogel (GA) substrates through a facile, one‐pot hydrothermal method is reported. The strong interaction and efficient electronic coupling between LDH and graphene substantially improve interfacial charge transport properties of the resulting nanocomposite and provide more available redox active sites for faradaic reactions. An LDH–GA||Ni(OH)₂ device is also fabricated that results in greatly enhanced specific capacity (187 mAh g^?1 at 0.1 A g^?1), outstanding specific energy (147 Wh kg^?1), excellent specific power (16.7 kW kg^?1), along with 88% capacity retention after >10 000 cycles. This approach is further extended to Ni–MH and Ni–Cd batteries to demonstrate the feasibility of compositing with graphene for boosting the energy storage performance of other well‐known Ni‐based batteries. In contrast to conventional Ni‐based batteries, the nearly flat voltage plateau followed by a sloping potential profile of the integrated supercapacitor–battery enables it to be discharged down to 0 V without being damaged. These findings provide new prospects for the design of high‐performance and affordable superbatteries based on earth‐abundant elements.     

Stabilized finite elements for time-harmonic waves in incompressible and nearly incompressible elastic solids

The propagation of waves in elastic solids at or near the incompressible limit is of interest in many current and emerging applications. Standard low-order Galerkin finite element discretization struggles with both incompressibility and wave dispersion. Galerkin least squares stabilization is known to improve computational performance of each of these ingredients separately. A novel approach of combined pressure-curl stabilization is presented, facilitating the use of continuous, equal-order interpolation of displacements and pressure. The pressure stabilization parameter is determined by stability considerations, while the curl stabilization parameter is determined by dispersion considerations. The proposed pressure-curl–stabilized scheme provides stable and accurate results on a variety of numerical tests for incompressible and nearly incompressible elastic waves computed with linear elements.     

Copper effects in mechanical,thermal and electrical properties of rapidly solidified eutectic Sn–Ag alloy

The Sn–3.5 wt%Ag alloy considered as a good alternative to Pb–Sn alloys. This study aims to investigate the effects of Cu or Sb additions by 3 or 5 wt% to melt-spun Sn–3.5%Ag alloy. Ternary melt-spun Sn–Ag–Cu and Sn–Ag–Sb alloys investigated using X-ray diffractions (XRD), Scanning electron microscope (SEM), Dynamic resonance technique (DRT), Instron machine, Vickers hardness tester and Differential scanning calorimetry (DSC). The results revealed that the microstructures of the β-Sn phase, Ag₃Sn and Cu₃Sn intermetallic compounds (IMCs) in the solder matrices were refined due to the effect of Cu additions and melt-spun process. Moreover, increasing Cu content promotes Ag₃Sn intermetallic compound (IMC) formation. Consequently, the addition of “3 wt%” of Cu reduced the creep rate ? from (3.79?×?10^?3) to (1.65?×?10^?3) and delayed the fracture point. The tensile results showed an improvement in Young’s modulus by 47% (30.3 GPa), ultimate tensile strength (UST) by 11.6% (23.9 MPa), and in toughness by 20.5% (952.32 J/m³) compared to the eutectic Sn–Ag alloy. Vickers hardness has improved by 3.3% (136.71 MPa) and thermal activation energy by 54% (90.40 KJ/mol) when compared with that of eutectic Sn–Ag alloy. Those improvements are related to the lack of lattice strain from 7.56?×?10^?4 without “3 wt%” of Cu to 5.26?×?10^?4 with “3 wt%” of Cu. Its melting temperature (T_m) increased by 3 °C due to Ag₃Sn IMC increased and Cu₃Sn formation, but the pasty rang (mushy zone) decreased by 4 °C with “3 wt%” of Cu. The small lattice strains resulted with “3 wt%” of Cu made the electrical resistivity of this alloy more stable at elevated temperatures. The mechanical, thermal and electrical improvements of Sn_93.5–Ag_3.5–Cu₃ alloy provide good physical performance for soldering process and electronic assembly.     

Optical Imaging Approaches to Monitor Static and Dynamic Cell‐on‐Chip Platforms: A Tutorial Review

Miniaturized laboratories on chip platforms play an important role in handling life sciences studies. The platforms may contain static or dynamic biological cells. Examples are a fixed medium of an organ‐on‐a‐chip and individual cells moving in a microfluidic channel, respectively. Due to feasibility of control or investigation and ethical implications of live targets, both static and dynamic cell‐on‐chip platforms promise various applications in biology. To extract necessary information from the experiments, the demand for direct monitoring is rapidly increasing. Among different microscopy methods, optical imaging is a straightforward choice. Considering light interaction with biological agents, imaging signals may be generated as a result of scattering or emission effects from a sample. Thus, optical imaging techniques could be categorized into scattering‐based and emission‐based techniques. In this review, various optical imaging approaches used in monitoring static and dynamic platforms are introduced along with their optical systems, advantages, challenges, and applications. This review may help biologists to find a suitable imaging technique for different cell‐on‐chip studies and might also be useful for the people who are going to develop optical imaging systems in life sciences studies.     

Pattern synthesize of a cylindrical conformal array antenna by PSO algorithm

Pattern synthesize of conformal array antennas is often a challenging problem. Various optimization algorithms such as genetic, particle swarm optimization (PSO), and invasive weed optimization have already been used for pattern synthesizing of conformal arrays. In this paper, a focused beam is synthesized for a quarter cylindrical conformal array antenna using the PSO algorithm with small computations. The desired pattern is a focused beam at θ = 90° and ? = 45° with 10° beamwidth in elevation and 15° beamwidth in azimuth with ?20 dB side‐lobe level. This method can be used in general for synthesizing arbitrary desired patterns and array geometries.     

An efficient improvement remote user mutual authentication and session key agreement scheme for E-health care systems

The E-health care systems allow patients to gain the health monitoring facility and access medical services remotely. A secure mechanism for mutual authentication and session key agreement is the most important requirements for E-Health Care Systems. Recently, Amin et al.’s proposed a mutual authentication and session key agreement protocol and claimed that their scheme is secure against all possible attacks. In this paper, we show that not only their scheme is vulnerable to privileged-insider attack, replay attack, session key disclosure attack, but also does not provide patient untraceability and backward secrecy. In order to withstand the mentioned security weaknesses, we propose an efficient remote mutual authentication scheme for the systems which are using ECC and Fuzzy Extractor. The proposed scheme not only resists against different security attacks, but it also provides an efficient registration, login, mutual authentication, session key agreement, and password and biometric update phases. During the experimentation, it has been observed that the proposed scheme is secure against various known attacks. Beside, our scheme is robust against privileged-insider attack that it rarely checked in security analysis. The informal analysis will ensure that our scheme provides well security protection against the different security attacks. Furthermore, we analyzed the security of the scheme using AVISPA software and Random Oracle Model. The formal analysis results and performance evaluation vouch that our scheme is also secure and efficient in computation and communication cost.     

The Effects of Screw Geometry on the Pumping Efficiency of Micro‐Screw Pump

The design of a novel micro‐screw pump for viscous fluid is described. The device consists of a rotating screw in the centre of the channel, connected with a shaft and micro motor. The objective of this research is to investigate the effect of using various screw geometries on the pump performance. Theoretical analysis by finite volume simulations is carried out to study the influence of pitch, diameter of the screw and the thread (flight depth) to evaluate the optimal dimensions for the pump and to obtain the maximum flow rate. When the screw rotates, a net force is transferred to the fluid due to the differential pressure on the depth of the thread and pressure gradient along the screw axis, thus causing the fluid to displace. The three‐dimensional simulations indicate a gradual increase of the average velocity with increasing the screw diameter. The maximum average velocity can be obtained when the ratio between the pitch and screw diameter (pi/d) is 0.6. Effective pumping is achieved by increasing the thread and pitch at maximum screw diameter. The numerical simulation has been validated experimentally.