Synthesized K2O·11Al2O3 as sagger matrix for the preparation of Li-ion battery cathode materials at high temperatures

Refractory materials such as mullite, andalusite, forsterite, and cordierite are generally used to prepare saggers for the calcination of Li-ion battery Li(Ni_xCo_yMn_z)O₂ (LNCM) cathode material. However, these compounds are prone to be attacked by the LNCM materials, thereby leading to short life spans and contamination of the Li-ion battery cathode materials. To improve the corrosion resistance of refractory sagger materials, the most clear cut-way is enhancing the corrosion resistance of matrix using a new refractory component. Potassium aluminate (K₂O·11Al₂O₃, KA₁₁) with an excellent corrosion resistance against alkaline oxide was synthesized via solid-state method using potassium carbonate (K₂CO₃) and industrial alumina powder (Al₂O₃). Interactions between KA₁₁ and LNCM cathode materials at 800°C–1100°C were characterized by refractory-LNCM precursor laboratory-scale tests to understand the corrosion behavior of KA₁₁. The microstructure and phase composition of synthesized KA₁₁ and the calcined KA₁₁-LNCM mixture cylinders were analyzed with SEM and XRD. The observations reveal that KA₁₁ shows a better corrosion resistance to LNCM materials compared with mullite, cordierite, and forsterite. The addition of synthesized KA₁₁ also favors the thermal shock resistances of mullite-based sagger materials.     

无机盐对新疆油田三元复合驱界面性能影响研究

界面性能对复合驱提高采收率有重大的影响,界面张力越低,洗油效率越高;Zeta电位越高,油水乳状液越稳定。研究了各类无机盐对新疆油田复合驱界面性能的影响。结果显示,Zeta电位的绝对值随着无机盐浓度的增高而增大;无机碱中,碳酸根离子降低界面张力效果最好,氢氧根次之,碳酸氢根最差;阳离子中,钾离子降低界面张力效果最好,其次是钠离子,镁离子会略微提高界面张力,钙离子则会大幅度提高界面张力;阴离子中,与硫酸根相比,氯离子能更好地降低界面张力。通过以上研究,确定了Q站污水处理站外排水更适合三元复合驱配液。     

含砷氰化尾矿回填利用污染控制技术试验研究

针对某黄金生产企业含砷氰化尾矿污染特征,开展了搅拌洗涤法、臭氧氧化法、酸化溶砷法、铁盐固砷法等多种无害化方法联合处理试验研究,旨在将该含砷氰化尾矿处理至满足氰渣规范回填利用污染控制要求。结果表明：该含砷氰化尾矿回填利用污染控制技术工艺为压滤调浆搅拌洗涤+臭氧氧化+酸化溶砷+铁盐固砷,最佳参数为原矿浆压滤后加水调浆,矿浆浓度40%,臭氧投加量0.66 g/L,酸化溶砷pH值3、曝气量0.1 m³/h、反应时间2 h,铁盐固砷七水合硫酸亚铁投加量20.0 g/L、反应时间1 h。研究结果为该黄金生产企业含砷氰化尾矿回填利用提供了技术支撑。     

缩进式管子-管板焊接工艺

管子-管板焊接是换热器生产的关键工序,通过对缩进式管子-管板焊接技术进行的试验和分析,确定了最佳的焊接参数,供换热器制造厂有关技术人员参考.     

铸件缺陷修补方法

简述了铸件缺陷的谷种修补方法及工艺，指出液膜溶解扩散焊是一种比较先进的焊补方法。     

PZT／Terfenol-D／PVDF层状复合磁电材料谐振特性

采用热压法制备出二层锆钛酸铅(PZT)／聚偏氟乙烯(PVDF)与1层Tb0.28Dy0.72Fe2(Terfenol-D)／PVDF叠层结构的三元复合磁电材料，研究了不同PVDF含量，以及不同层厚比tp／L对样品的介电常数、介电损耗、电阻率、谐振频率以及磁电转换系数αE33，αE31的影响规律，结果显示PVDF的含量和层厚比都存在最佳值(最佳值出现在产0．5，tp／L=2／7)，并且在这个最佳值处，磁电转换系数达到最大。     

The kinetics of desorption in the presence of a gas phase of the desorbing molecule: CO/Re(001)

TPD/Exchange from CO/Re(001) in a gas ambience showed that the absolute rate of desorption depends on the gas pressure and has a first plus second order rate law. It is proposed that desorption is a two step process from the adsorbed state to a stable intermediate which is itself weakly adsorbed.     

硼酚醛树脂在涂料中的应用

通过将硼酚醛树脂和环氧树脂进行混用,利用硼酚醛树脂优异的耐酸、碱腐蚀性能以及耐高温性能和环氧树脂可以常温固化成膜的特点,制备常温固化的耐高温防腐蚀涂料。     

异丁烯两段催化氧化制甲基丙烯酸催化剂研究 Ⅰ．异丁烯气相氧化制甲基丙烯醛多元复合氧化物催化剂的研究

本文报导用于异丁烯（叔丁醇）选择氧化制ＭＡＬ（甲基丙烯醛）的多元复合氧化物催化剂的研究结果。同共沉淀法制备的催化剂的活性主要决定于其化学组成，同时受到制备条件的影响。最佳催化剂的主要物相组成为ＰｂＯ３，Ｂｉ２ＭｏＯ３．３、ＮｉＭｏＯ４、Ｓｂ２Ｏ３及ａ－Ｆｅ２Ｏ３小颗粒。在３５５℃，１０００～２５００ｈ－１空速范围，叔丁醇：水：空气＝１：３．３：７（摩尔比）的条件下可获得异丁烯转化率达９６％，ＭＡＬ选择性达８９％的结果。     

Synthesis, characterization of bimetallic Sn-Zn-MCM41 and its catalytic performance in the hydroxylation of phenol

A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA, FT-IR, HRTEM and N_2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H₂O₂. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to 56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover, the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41.