含磷氯和氮的化合物对软质PU泡沫塑料的阻燃作用

较全面地研究了含磷和氯(或氮)的化合物对软质聚氨酯泡沫塑料的阻燃作用,表明:(1)磷与氯或氨复配的协同阻燃效应能明显提高其阻燃效率,当其阻燃剂用量为11%—12%时,PU软泡的阻燃性达到GB10800—89阻燃一级;(2)使含磷氮阻燃基团结合在PU分子中,能降低阻燃剂的逃失性,从而提高材料阻燃耐久性,为阻燃技术的研究指出一条新途径。     

EFFECT OF PORE DIFFUSION ON DEACTIVATING RATES OF SECOND ORDER REACTION

The research and development of catalysts, the design and operation of catalytic reactors are complicated by the phenomenon of catalyst deactivation which is affected by various factors. In this paper, the effect of internal mass transfer resistance in the second order catalytic reaction system of uniform independent deactivation on both reaction and deactivation rates of straight cylindrical pore model has been discussed. In addition, the quantitative relations between effectiveness factor and Thiele modulus in second order reaction and first order deactivation system have been correlated     

注塑模微机CAD系统

本文介绍了一个微机上运行的注塑模ＣＡＤ系统，此系统主要解决了四个难点，浇注系统设计，冷却系统分析，型腔，型芯的曲面造型设计，装配图和零件工作图的设计绘制，经厂家实际运用证明，该系统使用方便，结果正确，能提高设计效率，降低生产成本。     

Acidic and catalytic properties of niobic acid crystallized at low temperature

Niobic acid was crystallized at 120 °C for 48 h, which showed the largest acid amounts at higher acid strengths. The crystallized niobic acid calcined at 300 °C was found to show higher activity than uncrystallized niobic acid and niobic acid washed with water or treated with sulfuric acid or phosphoric acid for the dehydration of isopropanol and the esterification of ethanol with acetic acid.     

Synthesis of carbon nanocapsules containing Fe, Ni or Co by arc discharge in aqueous solution

A simple, inexpensive and one-step synthesis method of metal-containing carbon nanocapsules using an arc discharge in aqueous solution is reported. It was found that Ni, Co and Fe nanoparticles could be in situ encapsulated in carbon shells when the arc was performed respectively in aqueous solutions of NiSO₄, CoSO₄ and FeSO₄. Transmission electron microscopy, energy dispersive X-ray spectroscopy and electron diffraction patterns of selected areas were used to determine the crystalline phase of the metal cores. To explain the formation mechanism of metal-containing carbon nanocapsules, a model of discharge in solution is proposed. This result presents a simply controllable way to synthesize metal-containing carbon nanocapsules.     

Echo state networks based predictive model of vinyl chloride monomer convention velocity optimized by artificial fish swarm algorithm

Conversion rate in the Polyvinylchloride (PVC) polymerizing process has a certain influence on the molecular weight of PVC, porosity, absorption rate of plasticizer, vinyl chloride monomer (VCM) residue and thermal stability. Therefore, a predictive model based on echo state networks (ESN) method optimized by the artificial fish swarm algorithm (AFSA) is proposed to predict the conversion velocity. Firstly, the hot balancing mechanisms of polymerizer and the influenced factors of convention rate of VCM are analyzed in details. Then the auxiliary variables of the predictive model kernel are selected by using the kernel principal component analysis method for reducing the model dimensionality. Thirdly, the structure parameters of the ESN are optimized by the AFSA to realize the nonlinear mapping between input and output variables of the discussed soft-sensor model. The artificial fish swarm behaviors, such as foraging, swarming, chasing, random, are introduced in details. Finally, simulation results show that the proposed model can significantly enhance the predictive accuracy and robustness of the technical index and satisfy the real-time control requirements of PVC polymerizing production process.     

Integrated size and topology optimization of skeletal structures with exact frequency constraints

The present paper studies the integrated size and topology optimization of skeletal structures under natural frequency constraints. It is found that, unlike the conventional compliance-oriented topology optimization problems, the considered problem may be strongly singular in the sense that the corresponding feasible domain may be disconnected and the global optimal solutions are often located at the tips of some separated low dimensional sub-domains when the cross-sectional areas of the structural components are used as design variables. As in the case of stress-constrained topology optimization, this unpleasant behavior may prevent the gradient-based numerical optimization algorithms from finding the true optimal topologies. To overcome the difficulties posed by the strongly singular optima, some particular forms of area/moment of inertia-density interpolation schemes, which can restore the connectedness of the feasible domain, are proposed. Based on the proposed optimization model, the probability of finding the strongly singular optimum with gradient-based algorithms can be increased. Numerical examples demonstrate the effectiveness of the proposed approach.     

扎赉诺尔褐煤制取高炉喷吹料和中热值煤气研究 (Ⅰ)煤气、焦油产率及性质

本文是在10kg／h固体热载体干馏实验装置上用扎赉诺尔褐煤制取高炉喷吹料和中热值煤气的研究结果。在干馏温度450℃～650℃范围制得煤气110Nm3/t～400Nm3/t，煤气热值为14．7MJ／Nm3～17．5MJ／Nm3，属中热值煤气。可供民用，也可用于补充钢铁企业燃气不足，平衡能源。得低温焦油2％～9％，可加工成化工产品和燃料油。半焦可用于高炉喷吹。     

Direct synthesis of electrorheological suspension containing salt of poly(methacrylic acid) and its electrorheological effect

Colloidal suspensions containing salts of poly(methacrylic acid) which exhibit high electrorheological (ER) activity were synthesized by inverse emulsion polymerization. Factors influencing the ER effect were studied. The results showed that maximum yield stress occurred at optimum amounts of both polymeric stabilizer and crosslinking agent used in the inverse emulsion polymerization as well as a certain water content of the particles, while yield stress increased with electric field strength, average diameter of the particles below 0.9 μm, or the molar ratio of the salt to the acid. The ER activity for the suspensions containing different monovalent counter ions decreased in the following order: Li⁺ > Na⁺ > K⁺ > NH₄⁺. The phenomena were discussed with the ionic polarization mechanism. © 1995 John Wiley & Sons, Inc.