Transition metal-isolant dans l'oxyde V6O11: Etude structurale,magnetique et calorimetrique

Structural, magnetic and thermal properties have been carried out on V₆O₁₁ mixed valence oxide. It has been shown that the metal-insulator transition which occurs at 163 K is associated to a crystallographic modification. On the basis of the already known low temperature structure of V₄O₇ a scheme is proposed in order to describe the M-I transition. It involves both electron localization and pair formation, and agrees well with the magnetic susceptibility data in the paramagnetic region.     

Nutritional quality of uncultivated cereal grains utilised as famine foods in western sudan as measured by chemical analysis

The chemical composition of the grain of a number of wild grasses used as food in times of famine in western Sudan are reported and compared with those of the local staple cereals. Species investigated were Cenchrus hiflorus (haskaneet). Dactyloctenium aegyptium (korecb). Echinochloa colona (difra) and Oryza punctata (ruz el wadi). The grain of all species except C biflorus had protein contents in the range 110-140 g kg^?1, broadly similar to those of the local staple cereals. The grain of C biflours possessed a particularly high protein content of 210 g kg^?1. The nutritional quality of the proteins as measured by their chemical scores ranged from 20 for C biflorus to 65 for O punctata compared with scores of 36 and 58 for the local sorghum var Kurgi and millet respectively. Lysine was the limiting amino acid in all cases. Whilst the composition of the protein of sorghum var Kurgi was typical of sorghum generally, that of var Karamaka was unusual in possessing lysine levels of 3.4 g (16 g N)¹, double that normally present in sorghum and raising the chemical score of the protein to 62. The ash content of the famine food cereals was high, attaining 113 g kg¹ in C biflorus. All grains were good sources of zinc and D aegyptium. O punctata and E colonum additionally contained comparatively high levels of iron. Remarkably for a cereal D aegyptium was also very rich in calcium, containing over 10 g kg¹, and possessed high concentrations of manganese. Carbohydrate content of the famine food grains varied from 617 g kg¹ for C biflorus to 748 g kg¹ for O punctata, values comparable to the local staple cereals. The proportion of starch in this fraction ranged from 650 g kg¹ in D aegyptium to 940 g kg¹ in O punctata. Seed oils of all species were predominantly unsaturated containing mainly oleic and linoleic acids.     

Electromagnetic unbalance in power systems with untransposed transmission lines

Transposition of power transmission lines represents high costs due to the required transposition towers and also results in low mechanical and electrical strengths. These disadvantages make it desirable not to transpose lines if the resulting unbalances are not adverse. This paper proposes a method to predict the electromagnetic (combination of inductive and capacitive) unbalance of untransposed lines. The method is validated by its application to typical lines under various load conditions and various geometric mean radii.     

Benchmarking of lightweight cryptographic algorithms for wireless IoT networks

Wireless Networks - Cryptographic algorithms that can provide both encryption and authentication are increasingly required in modern security architectures and protocols (e.g. TLS v1.3). Many...     

A Novel Speech Enhancement Method Using Fourier Series Decomposition and Spectral Subtraction for Robust Speaker Identification

Wireless Personal Communications - This paper presents a novel speech enhancement approach by combining Fourier series expansion and spectral subtraction. This approach is implemented in speaker...     

Synthesis of Novel Tetra(µ3-Methoxo) Bridged with [Cu(II)-O-Cd(II)] Double-Open-Cubane Cluster: XRD/HSA-Interactions,Spectral and Oxidizing Properties

A new double-open-cubane core Cd(II)-O-Cu(II) bimetallic ligand mixed cluster of type [Cl₂Cu₄Cd₂(NNO)₆(NN)₂(NO₃)₂].CH₃CN was made available in EtOH/CH₃CN solution. The 1-hydroxymethyl-3,5-dimethylpyrazole (NNOH) and 3,5-dimethylpyrazole (NNH) act as N,O-polydentate anion ligands in coordinating the Cu(II) and Cd(II) centers. The structure of the cluster in the solid state was proved by XRD study and confirmed in the liquid state by UV-vis analysis. The XRD result supported the construction of two octahedral and one square pyramid geometries types around the four Cu(II) centers and only octahedral geometry around Cd(II) two centers. Interestingly, NNOH ligand acts as a tetra-µ³-oxo and tri-µ²-oxo ligand; meanwhile, the N-N in NNH acts as classical bidentate anion/neutral ligands. The interactions in the lattice were detected experimentally by the XRD-packing result and computed via Hirschfeld surface analysis (HSA). The UV-vis., FT-IR and Energy Dispersive X-ray (EDX), supported the desired double-open cubane cluster composition. The oxidation potential of the desired cluster was evaluated using a 3,5-DTB-catechol 3,5-DTB-quinone as a catecholase model reaction.     

Support vector machine based decision for mechanical fault condition monitoring in induction motor using an advanced Hilbert-Park transform

In this work we suggest an original fault signature based on an improved combination of Hilbert and Park transforms. Starting from this combination we can create two fault signatures: Hilbert modulus current space vector (HMCSV) and Hilbert phase current space vector (HPCSV). These two fault signatures are subsequently analysed using the classical fast Fourier transform (FFT). The effects of mechanical faults on the HMCSV and HPCSV spectrums are described, and the related frequencies are determined. The magnitudes of spectral components, relative to the studied faults (air-gap eccentricity and outer raceway ball bearing defect), are extracted in order to develop the input vector necessary for learning and testing the support vector machine with an aim of classifying automatically the various states of the induction motor.