Comparison of the Ewald and Wolf methods for modeling electrostatic interactions in nanowires

Ionic compounds pose extra challenges with the appropriate modeling of long‐range coulombic interactions. Here, we study the mechanical properties of zinc oxide (ZnO) nanowires using molecular dynamic simulations with Buckingham potential and determine the suitability of the Ewald (Ann. Phys. 1921; 19) and Wolf (J. Chem. Phys. 1999; 110 (17):8254–8282) summation methods to account for the long‐range Coulombic forces. A comparative study shows that both the summation methods are suitable for modeling bulk structures with periodic boundary conditions imposed on all sides; however, significant differences are observed when nanowires with free surfaces are modeled. As opposed to Wolf's prediction of a linear stress–strain response in the elastic regime, Ewald's method predicts an erroneous behavior. This is attributed to the Ewald method's inability to account for surface effects properly. Additionally, Wolf's method offers highly improved computational performance as the model size is increased. This gain in computational time allows for modeling realistic nanowires, which can be directly compared with the existing experimental results. We conclude that the Wolf summation is a superior technique when modeling non‐periodic structures in terms of both accuracy of the results and computational performance. Copyright © 2010 John Wiley & Sons, Ltd.     

Selection of a pull production control policy under different demand situations for a manufacturing system by AHP-algorithm

A multistage serial production system is considered in the present paper. A generalized model has been developed with the use of probabilistic demand situations for the end product. The demand situations considered are binomial, exponential, lognormal and Poisson. These demand patterns are used as input parameter for various production control policies. The output values for performance parameters are obtained by simulation. The production policies analyzed are Kanban, CONWIP and Hybrid as alternatives for controlling the engineering manufacture. In the presence of several performance measures, it often becomes difficult for the management to select the most appropriate policy. Analytic hierarchy process (AHP) has been implemented for the purpose of selection. Computational results have been reported along with the sensitivity analysis after designing and conducting various experiments.     

Temperature measurements in steady axisymmetric partially premixed flames by use of rainbow schlieren deflectometry

We focus on the utility of rainbow schlieren as a tool for measuring the temperature of axisymmetric partially premixed flames (PPFs). Methane-air PPFs are established on a coannular burner. The flames involve two spatially distinct reaction zones, one in an inner premixed region that has a curved tip and a spatially planar wing portion and another that involves an outer nonpremixed zone in which intermediate species burn in air. Schlieren images are found to visualize clearly these PPF characteristics through light deflection by steep refractive-index gradients in the two reaction zone fronts. The temperature distributions of two flames established at fuel-rich mixture equivalence ratios of phi(r) = 1.5 and 2.0, with bulk-averaged velocities, Vreac = 60 cm s(-1) and Vair = 50 cm s(-1), are inferred from color schlieren images, and a measurement error analysis is performed. Errors arise from two sources. One lies in the process of inferring the temperature from the refractive-index measurement by making assumptions regarding the local composition of the flame. We have shown through simulations that the average temperature deviations due to these assumptions are 1.7% for the phi(r) = 1.5 flame and 2.3% for the phi(r) = 2.0 flame. Another source involves the local uncertainty in the measurement of the transverse ray displacement at the filter plane that is used to determine the refractive index and thereafter the flame temperature. We have ascertained that a maximum error of 4.3% in the temperature determination can be attributed to this local measurement uncertainty. This investigation demonstrates the capability of the schlieren technique for providing not only qualitative displays of the PPFs but also full-field-of-view temperature measurements that are accurate, spatially resolved, and nonintrusive.     

The VVERs at KudanKulam

A Nuclear Power Project is being set-up at KudanKulam in the state of Tamil Nadu, India in collaboration with the Russian Federation. The project comprises of two units each of 1000 MWe VVER type reactor. The design of the plant and supply of all the major equipment is in the scope of the Russian Federation while development of infrastructure and project construction is in Indian scope of works. The VVER (Version V-412) reactor that is under construction at KudanKulam site is an advanced PWR, which incorporates all the features of a modern PWR as per the current Russian, Western and IAEA standards. The KudanKulam site in the southern Indian state of Tamil Nadu was one among the several sites evaluated by the Site Selection Committee, which cleared KudanKulam site for setting up an installed capacity up to 6000 MWe. The design, construction and operation of the plant meets the regulatory and licensing requirements of Russian regulatory body “RTN” as also India's Atomic Energy Regulatory Board. The supply of the equipment from the Russian Federation is on schedule and the project construction work by various Indian agencies is also ahead of schedule. The two units of KudanKulam Nuclear Power Project (KKNPP) are scheduled to achieve first criticality in the year 2007–2008. The paper discusses various design features, project construction and management aspects.     

An integrated path-planning and control approach for nonholonomic unicycles using switched local potentials

In this paper, navigation and control of an autonomous mobile unicycle robot in an obstacle-ridden environment is considered. The unicycle dynamic model used has two differentially driven wheels, with the motor torques as the system input. Two novel potential-field-based controllers are derived, which stabilize the robot within a surrounding circular area (henceforth called a bubble) of arbitrary size. The first controller takes the unicycle to the center of its bubble, while the second corrects its orientation. The designed potentials also work with a kinematic model. Explicit bounds for permissible initial speeds are derived, such that maximum torque limits and/or maximum speed limits are not violated once the controller is activated. These controllers are then embedded in a navigation framework. An existing global planner is used to first create a string of variable-sized bubbles which connect the start point to the goal point, with each bubble's size indicative of the radial obstacle clearance available from its center. The robot then keeps itself within a fixed-sized bubble, which it then moves in discrete steps, according to the direction provided by the global plan, while repulsively avoiding unexpected obstacles. Hence, the gross movement is created by switching local potential-field-based controllers. This scheme is first verified in computer simulation of a single robot moving in a maze. It is then implemented on an experimental setup of robots equipped with proximity sensors. Results are presented to illustrate the effectiveness of the system.     

Lyapunov controller design for transverse vibration of a cable-linked transporter system

Modeling and Lyapunov controller design for transverse vibration of a flexible cable transporter system with arbitrarily varying lengths are presented using Hamilton's principle and Lyapunov theory. The axial velocity of the system is assumed to be unknown in the model. This is different from existing literature where the axial velocity is assumed either to be constant or prescribed. The governing equations include two coupled non-linear Partial Differential Equations (PDEs) and boundary conditions. The interactions between the cables and the slider, pulleys, and motors are included in the model. Numerical solution of the derived governing equations is obtained using Galerkin's method. Based on the Lyapunov theory, we propose two boundary controllers and one domain point-wise controller, which suppress the transverse vibration of the cables effectively while assuring the attainment of the slider goal. The proposed controllers dissipate the vibration energy and guarantee the stability of the closed-loop system in Lyapunov sense. Simulation results demonstrate the effectiveness of the proposed controllers.A short version of this paper was presented in 2004 ASME International Mechanical Engineering Conference and Exposition, Anaheim CA, November 14-19, 2004.     

Jini home networking: a step toward pervasive computing

Jini connection technology forms a network of devices on the fly, without manual connection or configuration. It can also complement other technologies that strive for "anytime, anywhere" connectivity. The article looks at lookup and discovery services; reliability and scalability; Jini architectural requirements; service for non-Jini devices; Jini mobile edition for wireless devices; Jini implementations; and competing and related technologies.     

Performance comparison of battery power consumption in wireless multiple access protocols

Energy efficiency is an important issue in mobile wireless networks since the battery life of mobile terminals is limited. Conservation of battery power has been addressed using many techniques such as variable speed CPUs, flash memory, disk spindowns, and so on. We believe that energy conservation should be an important factor in the design of networking protocols for mobile wireless networks. In particular, this paper addresses energy efficiency in medium access control (MAC) protocols for wireless networks. The paper develops a framework to study the energy consumption of a MAC protocol from the transceiver usage perspective. This framework is then applied to compare the performance of a set of protocols that includes IEEE 802.11, ECMAC, PRMA, MDRTDMA, and DQRUMA*. The performance metrics considered are transmitter and receiver usage times for packet transmission and reception. The time estimates are then combined with power ratings for a Proxim RangeLAN2 radio card to obtain an estimate of the energy consumed for MAC related activities. The analysis here shows that protocols that aim to reduce the number of contentions perform better from an energy consumption perspective. The receiver usage time, however, tends to be higher for protocols that require the mobile to sense the medium before attempting transmission. The paper also provides a set of principles that could be applied when designing access protocols for wireless networks.*ECMAC: energyconserving MAC. PRMA: packet reservation multiple access. MDRTDMA: multiservices dynamic reservation TDMA. DQRUMA: distributedqueuing request update multiple access.     

Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid

The work described here deals with the performance of ethylenediamine N,N^′-dibenzylidene, ethylenediamine N,N^′-di(p-methoxybenzylidene), ethylenediamine N,N^′-disalicylidene as corrosion inhibitors for zinc in sulphuric acid. The effect of various parameters on the efficiency of these inhibitors has been studied. Ethylenediamine N,N^′-di(p-methoxybenzylidene) and ethylenediamine N,N^′-disalicylidene give 99% protection under a variety of conditions. Activation energies in the presence and absence of inhibitors have been calculated. It appears that an efficient inhibitor is characterized by a relatively greater decrease in free energy of adsorption, relatively lower entropy of adsorption and relatively lower heat of adsorption. Galvanostatic polarisation studies indicate that these are basically cathodic inhibitors. Cathodic protection in the presence of these inhibitors has been studied. With an efficient inhibitor, cathodic protection is achieved at potentials much less negative than that required for plain acid. The difference between protective potential and corrosion potential appears to be less for an effective inhibitor. Mechanism of the action of inhibitors has been provided.