采用电子束检测技术辅助晶体管开发

涉足尖端技术研究工作的芯片制造商正在把无数新材料和奇特的器件结构结合起来,用于65nm及更低节点的量产。同时他们发现,在这些研究上的努力生产的结果还包括目前必须着手解决各器件各个层上出现的     

Influence of the molecular weight of ionenes on the cobaltphthalocyanine-catalysed autoxidation of mercaptoethanol

In order to study the promoting effect of polycations on the cobalt(II)phthalocyanine-tetrasodiumsulphonate (CoPc(NaSO₃)₄)-catalysed autoxidation of thiols, it is imperative to know the molecular weight dependence of the polymer. Monodisperse oligomers can often supply a lot of information. To elecidate the mechanism of the promoting effect of 2,4-ionene, a poly(quaternary ammonium)salt, on the CoPc(NaSO₃)₄-catalysed autoxidation of 2-mercaptoethanol, a series of monodisperse 2,4-ionene oligomers were prepared. Trimeric 2,4-ionenes, containing two quaternary ammonium groups separated by four methylene groups, showed a high co-catalytic activity, and active Co-aggregates were detected with visible light spectroscopy. The spectroscopic behaviour was in close agreement with that of high molecular 2,4-ionene/CoPc(NaSO₃)₄ complexes. In order to achieve this aggregation several oligomeric ionenes have to act concertedly. If the distance between the ionic sites is short the trimer acts as a simple salt in stablizing the aggregates. With respect to the catalytic activity the optimum polycation/catalyst ratio, expressed as the N⁺/Co ratio, decreased with increasing chain lenght and reached a constant level of 50 at a 2,4-ionene nonamer. For the trimers and pentamers this ratio is affected by the type of end-group. All synthesized 2,4-ionene oligomers exhibited excellent co-catalytic properties at the optimum N⁺/Co ratio, with maximum turnover frequencies of 4600 mol thiol/(mol Co s), i.e. 50 times higher than those obtained for the polymer-free system. In the case of monodisperse 2,4-ionene pentamer with bromo end-groups, double Michaelis–Menten kinetics were observed, as also was exhibited by high molecular weight ionene.     

COLLOIDS IN GLASS1

A discussion of the various elements and compounds found in a colloidal state in glass. Attention is called to the similarity of colloidal behavior in vitreous and aqueous media. Theories and experimental evidence are furnished to account for the formation and destruction of the colloidal state.     

Propagation properties of foreshock cavitons: Cluster observations

Foreshock cavitons are transient phenomena observed in the terrestrial foreshock region. They are characterized by a simultaneous depression of magnetic field magnitude and plasma density, which are bounded with enhancements of these two parameters and surrounded by ultralow frequency(ULF) waves. Previous studies focused on the interplanetary magnetic field(IMF) conditions, solar wind(SW) conditions, and the growth of the foreshock waves related to the generation of foreshock cavitons. Previously, a multipoint spacecraft analysis method using Cluster data was applied to analyze only two foreshock cavitons, and this method did not consider uncertainties. In this study, multipoint spacecraft analysis methods, including the timing method, the minimum directional derivative(MDD) method, and the spatiotemporal difference(STD) method are applied to determine the velocity in both spacecraft and solar wind frames. The propagation properties show good agreement with previous results from simulations and observations that most cavitons move sunward in the solar wind frame, with the velocities larger than the Alfvén speed. The propagation properties of foreshock cavitons support the formation mechanism of cavitons in previous simulations, which suggested that cavitons are formed due to the nonlinear evolution of compressive ULF waves. We find that there is clear decreasing trend between the size of cavitons and their velocity in the solar wind frame. In addition, the timing method considering errors has been applied to study the evolution properties by comparing the velocities with errors of the leading and trailing edges, and we identify three stable cavitons and one contracting caviton, which has not been studied before.Most cavitons should remain stable when they travel toward the Earth's bow shock. The relationship between the size of foreshock cavitons and their distance from the bow shock is also discussed.     

Ru-Containing Polymeric Catalysts for Cellulose Conversion to Polyols

In this paper Ru-containing catalysts based on hypercrosslinked polystyrene (MN-270) and its functional analogues (MN-100 and MN-500) were studied for the first time in cellulose hydrolytic hydrogenation. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0 % Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50 % on the average at 85 % cellulose conversion.