Phototransformation of metobromuron in the presence of TiO2

The photocatalytic degradation of the herbicide metobromuron was studied, using TiO₂ photocatalysts (Degussa P25 and Millennium PC50, PC100, PC105 and PC500). Intermediate products were identified by means of liquid chromatography–mass spectrometry (LC–MS–MS) using electrospray (ES) interfacing technique. In order of importance, the main reaction pathways were demethoxylation of the urea chain, ring oxidation leading to ortho hydroxylation with respect to the N atom, substitution of Br by OH, ring oxidation with formation of the meta hydroxylated compound. Demethylation of the demethoxylated product occurred as a secondary reaction. Formation of bromide ions was observed too. In the presence of 2-propanol used as a hydroxyl radical scavenger, demethoxylation was drastically inhibited while the other reactions were only partly inhibited. It suggests that demethoxylation was exclusively due to the oxidation by hydroxyl radicals, whereas the other reactions involved positive holes too. The degradation rate of metobromuron varied in the order: PC50 < PC100 < PC105 < PC500 < Degussa P25. TiO₂ Degussa P25 was therefore the most efficient photocatalyst although its surface area was lower than that of most of Millennium TiO₂.     

Fatty Acids Profile and Chemical Composition of Egyptian Moringa oleifera Seed Oils

Moringa oleifera is grown all over the world as a crop for its nutritious pods, leaves and seeds. The purpose of the present study was to evaluate the oil percentage, density, iodine value, saponification value, acid value and fatty acid profile of Egyptian moringa Seed oils. Moringa seeds were irradiated using ⁶⁰Co at dose levels of 0.0 (control), 5, 10 and 15 kGy and oil was extracted from unirradiated and irradiated samples. Results showed that the oil percentage and density were almost unaffected. Irradiation reduced the iodine value, whereas the acid and saponification values were increased in all irradiated samples. The oil was found to contain high levels of unsaturated fatty acids, especially an omega‐9‐fatty acid (oleic) (up to 76.29 %) at a dose level of 15 kGy. Also at the same dose level, the dominant saturated acids were palmitic, stearic acid and arachidic (the three up to 12.66 %). GC–MS revealed the presence of different compounds (more than 50) in the moringa oil extract, among them alkaloids, terpenoids steroids, saturated and unsaturated fatty acids, aromatic and aliphatic hydrocarbons and polyphenolic compounds. Phenolic and falvonoid were significantly increased by increasing irradiation dose levels. Also, the antioxidant activity of irradiated seed oil increased by increasing the phenolic and flavonoid contents. Moringa oleifera could be grown by wide scale production as a potentially valuable crop. However, isolation of individual compounds and their biological activities needs to be covered in future to enhance its pharmacological importance and to open new avenues of research.     

Exploring bioaugmentation strategies for azo dye CI Reactive Violet 5 decolourization using bacterial mixture: dye response surface methodology

The use of response surface methodology based on statistical design of experiments is becoming increasingly widespread in several sciences such as analytical and environmental chemistry. In the present study, the decolourization and the degradation efficiency of CI Reactive Violet 5 (CIRV5) was studied using a novel bacterial consortium. CIRV5 (1000 p.p.m.) biodegradation was investigated under shaking condition in mineral salt medium solution (MSM) at a 7.5 pH and a 25°C temperature. The degradation pathways were also predicted, using UV‐visible spectroscopy analysis. Under optimal conditions, the bacterial consortium was able to decolourize the dye completely (>99%) within 8 h. The colour and chemical oxygen demand (COD) removal were 99.29 and 94.93%, respectively. Polymerase chain reaction (PCR) technique was utilized to detect the adhesin genes ‘icaA’ and ‘icaD.’ Our results showed that Staphylococcus aureus had a high decolourization capacity. Phytotoxicity study using Triticum turgidum ssp durum showed the no toxicity of the produced products.     

Lobed grilles for high mixing ventilation – An experimental analysis in a full scale model room

In the present study it is shown that jet flows from innovative rectangular air diffusion grilles with lobed ailerons ensure higher mixing in a room than baseline jets from classical rectangular air diffusion grilles with straight ailerons. The experimental approach uses time resolved and classical large scale PIV measurements.     

Healthy and Adverse Effects of Plant-Derived Functional Metabolites: The Need of Revealing their Content and Bioactivity in a Complex Food Matrix

In recent years, both food quality and its effect on human health have become a fundamental issue all over the world. As a consequence of this new and increased awareness, American, European, and Asian policymakers have strongly encouraged the research programs on food quality and safety thematic. Attempts to improve human health and to satisfy people's desire for healthcare without intake of pharmaceuticals, has led the food industry to focus attention on functional or nutraceutical food. For a long time, compounds with nutraceutical activity have been produced chemically, but the new demands for a sustainable life have gradually led the food industry to move towards natural compounds, mainly those derived from plants. Many phytochemicals are known to promote good health, but, sometimes, undesirable effects are also reported. Furthermore, several products present on the market show few benefits and sometimes even the reverse - unhealthy effects; the evidence of efficacy is often unconvincing and epidemiological studies are necessary to prove the truth of their claims. Therefore, there is a need for reliable analytical control systems to measure the bioactivity, content, and quality of these additives in the complex food matrix. This review describes the most widespread nutraceutics and an analytical control of the same using recently developed biosensors which are promising candidates for routine control of functional foods.     

Experimental investigation of the mixing performance of a lobed jet flow

An experimental investigation of flow in a turbulent isothermal air lobed jet is presented. A lobed jet is compared, in the near field, with an isothermal axisymmetric jet with the same exit Reynolds number in terms of dynamics and mixing enhancement. It was found that the streamwise variation of the volumetric flow rate is characterized by a slope is more than twice larger than that for the reference circular jet. This high entrainment rate is governed, at the same time, by the turbulent structures generated by the asymmetric shape of the nozzle and by the high convection in these structures induced by the inner and outer penetration angles of their lobes. Published in Inzhenerno-Fizicheskii Zhurnal, Vol. 81, No. 1, pp. 102–107, February–March, 2008.     

Resonance effect of insulated negative current rail in a subway network

A modeling technique of a subway network is performed in order to quantify the effect of insulated negative current rail on resonance frequencies. A DC track circuit is modeled by means of transmission line modeling (TLM) approach to perform line current and voltage calculation. Impedance and admittance required by TLM equations are first derived. System impedance is expressed in terms of internal and external impedance. The former is calculated using exact expression of a cylindrical conductor whereas the external impedance is taken as the sum of conductor's reactance considering a perfect conducting plane and the ground impedance. The well-known Carson's formulas for ground impedance are compared to Sunde's one to investigate frequency range applicability of the former. Simulations reveal that Carson's expressions are valid for frequencies up to 50 kHz. It appears, however, that using Cason's formulas for higher frequencies lead to underrating ground impedance. To investigate the accuracy impact of internal impedance, ground impedance and inductance on resonance frequencies, a sensitivity analysis is performed. A noticeable resonance effect is observed at 8 kHz for a 10 km length rail. Simulation results show the network impedance effect on track current and voltage.     

Numerical study of the wake induced by a porous disk under deflected inflow

This study examines the wake of a porous disk that generates a velocity deficit equivalent to that of a wind turbine. Three-dimensional unsteady numerical simulations based on the finite volume method are performed. The URANS-SST (k–ω) model is applied for the turbulence closure. Two investigations are carried out in this study: (i) the influence of the disk porosity on the wake, for porosities values (p) ranging from 0 to 0.55 in the case of a perpendicular flow; and (ii) the influence of the yaw angle on the wake deviation, for yaw angles ranging from 5° to 30°. Good agreements with the available experimental data are obtained for the mean x-velocity component. The results confirm that wake length increases as porosity decreases. For nonporous disks, most part of the fluid is deflected toward the mast and above the disk. The y-velocity contours highlight two contra-rotating vortices in the vicinity of the disk. In both cases (nonporous and porous disks), a high turbulent kinetic energy is obtained near the disk area, with a higher maximum value for the nonporous disk.     

Analysis of phosphorylated peptides by ion mobility-mass spectrometry

An ion mobility-mass spectrometry technique for rapid screening of phosphopeptides in protein digests is described. A data set of 43 sequences (ranging in mass from 400 to 3000 m/z) of model and tryptic peptides, including serine, threonine, and tyrosine phosphorylation, was investigated, and the data support our previously reported observation (Ruotolo, B. T.; Verbeck, G. F., IV; Thomson, L. M.; Woods, A. S.; Gillig, K. J.; Russell, D. H. J. Proteome Res. 2002, 1, 303.) that the drift time-m/z relationship for singly charged phosphorylated peptide ions is different from that for nonphosphorylated peptides. The data further illustrate that a combined data-dependent IM-MS/MS approach for phosphopeptide screening would have enhanced throughput over conventional MS/MS-based methodologies.