Zirconia Nanoparticles Made in Spray Flames at High Production Rates

Synthesis of zirconia nanoparticles by flame spray pyrolysis (FSP) at high production rates is investigated. Product powder is collected continuously in a baghouse filter unit that is cleaned periodically by air-pressure shocks. Nitrogen adsorption (BET), X-ray diffractometry (XRD), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA) are used to characterize the product powder. The effect of powder production rate (up to 600 g/h), dispersion gas flow rate, and precursor concentration on product particle size, crystallinity, morphology, and purity is investigated. The primary particle size of zirconia is controlled from 6 to 35 nm, while the crystal structure consists of mostly tetragonal phase (80–95 wt%), with the balance monoclinic phase at all process conditions. The tetragonal crystal size is close to the primary particle size, which indicates weak agglomeration of single crystals.     

A Comprehensive GRNN Model for the Prediction of Cutting Force,Surface Roughness and Tool Wear During Turning of CP-Ti Grade 2

Silicon - Titanium alloys are most widely used in aerospace, military, marine, medical and bio-medical industries because of their unique properties such as high corrosion resistance,...     

A comprehensive survey of network coding in vehicular ad-hoc networks

Network coding is a data processing technique in which the flow of digital data is optimized in a network by transmitting a composite of two or more messages to make the network more robust. Network coding has been used in traditional and emerging wireless networks to overcome the communications issues of these networks. It also plays an important role in the area of vehicular ad-hoc networks (VANETs) to meet the challenges like high mobility, rapidly changing topology, and intermittent connectivity. VANETs consist of network of vehicles in which they communicate with each other to ensure road safety, free flow of traffic, and ease of journey for the passengers. It is now considered to be the most valuable concept for improving efficiency and safety of future transportation. However, this field has a lot of challenges to deal with. This paper presents a comprehensive survey of network coding schemes in VANETs. We have classified different applications like content distribution, multimedia streaming, cooperative downloading, data dissemination, and summarized other key areas of VANETs in which network coding schemes are implemented. This research work will provide a clear understanding to the readers about how network coding is implemented in these schemes in VANETs to improve performance, reduce delay, and make the network more efficient.     

Search me if you can: Multiple mix zones with location privacy protection for mapping services

The mobile vehicle is gaining popularity nowadays using map services like Google Maps and other mapping services. However, map services users have to expose sensitive information like geographic locations (GPS coordinates) or address to personal privacy concerns as users share their locations and queries to obtain desired services. Existing mix zones location privacy protection methods are most general purposed and theoretical value while not applicable when applied to provide location privacy for map service users. In this paper, we present new (multiple mix zones location privacy protection) MMLPP method specially designed for map services on mobile vehicles over the road network. This method enables mobile vehicle users to query a route between 2 endpoints on the map, without revealing any confidential location and queries information. The basic idea is to strategically endpoints to nearby ones, such that (1) the semantic meanings encoded in these endpoints (eg, their GPS coordinates) change much, ie, location privacy is protected; (2) the routes returned by map services little change, ie, services usability are maintained. Specifically, a mobile client first privately retrieves point of interest close to the original endpoints, and then selects 2 points of interest as the shifted endpoints satisfying the property of geoindistinguishability. We evaluate our MMLPP approach road network application for GTMobiSim on different scales of map services and conduct experiments with real traces. Results show that MMLPP strikes a good balance between location privacy and service usability.     

Removal and recovery of zirconium from its aqueous solution by Candida tropicalis

Removal and recovery of zirconium from dilute aqueous solutions by Candida tropicalis used as biosorbent, was studied by performing biosorption-desorption tests. This biosorbent was selected after screening a range of microbial species. The process was found to be highly dependent on initial pH and concentration of metal solution. At optimized experimental parameters, the maximum zirconium biosorption capacity of C. tropicalis was 179 mg Zr g(-1) dry weight of biosorbent. The adsorption distribution coefficient value of 3968 ml g(-1) was obtained for zirconium biosorption by C. tropicalis. Different theoretical thermodynamic models governing the adsorption behavior of zirconium were also tested. Zirconium biosorption was found to closely follow the Langmuir model. At low biomass concentrations it was found to follow pseudo-first-order kinetics. However when higher biomass concentrations were used kinetics was changed to pseudo-second-order. The zirconium bound to the biomass was stripped out (60.2% at S/L of 1.0 g of zirconium loaded biomass/l of eluent) using sodium bicarbonate and the biomass could be used for multiple sorption-desorption cycles.     

Passivation of pigment-grade TiO(2) particles by nanothick atomic layer deposited SiO(2) films

Pigment-grade TiO(2) particles were passivated using nanothick insulating films fabricated by atomic layer deposition (ALD). Conformal SiO(2) and Al(2)O(3) layers were coated onto anatase and rutile powders in a fluidized bed reactor. SiO(2) films were deposited using tris-dimethylaminosilane (TDMAS) and H(2)O(2) at 500?°C. Trimethylaluminum and water were used as precursors for Al(2)O(3) ALD at 177?°C. The photocatalytic activity of anatase pigment-grade TiO(2) was decreased by 98% after the deposition of 2?nm SiO(2) films. H(2)SO(4) digest tests were performed to exhibit the pinhole-free nature of the coatings and the TiO(2) digest rate was 40 times faster for uncoated TiO(2) than SiO(2) coated over a 24?h period. Mass spectrometry was used to monitor reaction progress and allowed for dosing time optimization. These results demonstrate that the TDMAS-H(2)O(2) chemistry can deposit high quality, fully dense SiO(2) films on high radius of curvature substrates. Particle ALD is a viable passivation method for pigment-grade TiO(2) particles.     

Malnutrition in South Asia—A Critical Reappraisal

Malnutrition continues to be a major public health challenge especially in South Asian developing countries. The aim of the present review is to spotlight the magnitude of the prevalence of malnutrition and its dynamics in South Asian region and to suggest potential approaches for the prevention and control of this issue of public health significance. An extensive review of literature, covering malnutrition and its determinants, health and economic consequences and pragmatic preventive strategies was performed on computer based bibliographic databases (PubMed, Google Scholar, Scopus, Medline and Sciencedirect.com) to retrieve abstracts and full texts for India, Pakistan, Bangladesh, Sri Lanka and Nepal. All relevant titles and abstracts were examined and evaluated for malnutrition and its prevalence in South Asia. The results revealed malnutrition to be a major public health problem and a potential cause of high disease burden and mortality in South Asia. Compelling evidence suggests malnutrition to be the leading cause of stunting, wasting and underweight with drastic economic consequences among vulnerable populations. Reduced cognitive performance and low productivity have also been associated with micronutrients malnutrition. Suboptimal breastfeeding, inadequate food supply, micronutrient deficiencies, low household income, poor health care system, increased healthcare costs, illiteracy, unhygienic and substandard living, inappropriate child's care and the caregiver, food insecurity and on top of that vicious cycle of poverty, have been recognized as principal indicators for growing malnutrition prevalence in South Asia. Global organizations, local governments, program managers, NGOs, academia, industry in particular and the society at large need to take up the challenge to completely confiscate malnutrition from the region for economic prosperity and a healthier future.     

Structural,rheological, and mechanical properties of ternary blends of PEN,PET, and liquid crystalline polymer

Structural, rheological, and mechanical properties of ternary blends of a liquid crystalline copolyester (LCP) composed of p-hydroxybenzoic acid and 2,6-hydroxynaphthoic acid, poly(ehtylene naphthalate)(PEN), and poly(ethylene terephtalate) (PET) were investigated using capillary rheometry, tensile testing, scanning electron microscopy, and X-ray diffraction. Viscosity-shear rate behavior of the ternary blends is very similar to that of pure polymers and their binary blends. The activation energy of flows of the ternary blends was smaller than those of PEN and PET. Tensile modulus and strength of extruded strands of the blends increased with increasing LCP content. The extruded strands of the blends consist of a crystalline and oriented LCP phase and an amorphous and unoriented PEN/PET blended phase. Tensile mechanical properties and structures of the ternary blends were discussed.