Mixed convection from an isolated spherical particle

A numerical study on mixed convection around a hot spherical particle moving vertically downwards in a still fluid medium has been made. The flow field is considered to be axisymmetric for the range of Reynolds number (based on the diameter and the settling velocity of the particle) considered. A third-order accurate upwind scheme is employed to compute the flow field and the temperature distribution. The form of the wake and the thermal field is analyzed for several values of Grashof number and the Reynolds number. The influence of buoyancy on drag and the rate of heat transfer are studied. At moderate Reynolds number, recirculating eddy develops in the downstream of the sphere. With the rise of surface temperature this eddy collapses and the fluid adjacent to the heated surface develops into a buoyant plume above the sphere. The increase in surface temperature of the sphere delays the flow separation. Our results show that the drag force and the rate of heat transfer strongly depend on Grashof number for the moderate values of Reynolds number. The conjugate heat transfer from the moving sphere is also addressed in the present paper. We have compared our computed solution with several empirical and asymptotic expressions available in the literature and found them in good agreement.     

Metabolism of monoterpene alcohol, linalool, by a soil pseudomonad

A microorganism of the genus Pseudomonas has been isolated from the soil by enrichment culture techniques with linalool(I) as the sole source of carbon and energy. The organism is also capable of utilizing limonene, citronellol, and geraniol as substrates but fails to grow on citral, critranellal, and 1,8-cineole. Fermentation of linalool by this bacterium in a mineral salt medium results in the formation of 10-hydroxylinalool(II), oleuropeic acid (IX), 2-vinyl-2-methyl-5-hydroxyisopropyl-tetraphydrofuran)linalool oxide, V), 2-vinyl-2-methyl-tetrahydrofuran-5-one(unsaturated lactone, VI), and few unidentified minor metabolities. Probable pathways for the biodegradation of linalool are presented.     

Ion flotation of dichromate and of complexed cyanide: Surfactants for qualitative analysis

Ion flotation studies have shown that a surface-active agent is useful for qualitative analysis of complex ions in dilute aqueous solution, with the surfactant forming a particulate complex with the complex ion of concern. Experiments with a monovalent, cationic surfactant have established the prevalence of Cr₂O₇ ²⁻ (HCrO₄ ⁻) and not CrO₄ ²⁻; of [Fe(CN)₆]⁴⁻ and [Fe(CN)₅H₂O]³⁻; and of [FeFe(CN)₆]²⁻ and not [FeFe(CN)₆]⁻ or [Fe(CN)₆]³⁻. The results can be contrasted to those with ions that do not form particulate complexes with the surfactant, such as HPO₄ ²⁻ and phenolate; with the latter, no qualitative analytical information can be gained. Ion flotation appears to be a promising technique in general for the determination of ionic species present in aqueous solution; the surfactant must react with the ion of significance to form a particulate complex and the initial surfactant concentration must be controlled carefully.     

Colorimetric Estimation of Allyl Isothiocyanate Content in Mustard and Rapeseed Oils

A colorimetric method based on the colour reaction between allyl thiourea and potassium ferricyanide solution in dilute acetic acid has been developed for the determination of allyl isothiocyanate content in mustard and rapeseed oils. The method measures the optical density of the colour complex at 600 nm and it works in the range 2.5 to 7.5 μg of allyl isothiocyanate per ml of the colour solution. Mustard and rape oil samples analysed contain 0.40 to 0.6% of allyl isothiocyanate, with standard deviation of 0.002 to 0.016. The method takes around 3 hours and permits a number of sample analysis at a time.     

The gas-cooled fast breeder reactor critical experiments program

This paper presents results of measurements and calculations of physics parameters in the first gas-cooled fast breeder reactor (GCFR) critical assemblies in the US, a program of experiments conducted on the ZPR-9 facility at Argonne National Laboratory. Through a progressive three-phase series of assemblies, the major features unique to GCFR physics due to the gaseous coolant, and the resulting hard neutron spectrum and greater leakage, were investigated. Phases I and II were simple-geometry, uniform-core assemblies providing tests of nuclear data and GCFR design methods for fast reactors with large void fractions. The Phase III core simulates a GCFR design with three enrichment zones. This report primarily concerns the results obtained in Phase II.In addition to the usual central indices, reaction rate mappings, etc. these initial studies have provided the first experimental data on reactivity coefficients relevant to GCFR safety, such as worths of fuel, control, and cladding materials, Doppler effect, and coolant (helium) depressurization worth. Effects of steam ingress into coolant channels (due to a hypothesized steam generator leak) were simulated using polyethylene. The physics information obtained is providing a valuable base for verification of GCFR design and safety analyses.     

Glyceride Composition in Interesterified Fats

The positional distribution of acyl groups in interesterified fats obtained from a number of vegetable oil-mixtures was studied by the selective deacylation reaction of Pancreatic Lipase. In the case of randomised fats, there was almost equal distribution of fatty acids in the three positions, which indicated completeness of randomisation and destruction of the selective orientation of acyl groups present in natural fats. On the other hand, there was little or no change in positional distribution during directed interesterification. It was found that for natural and randomised fats, the glyceride compositions calculated from the Lipase hydrolysis data agreed quite well with those obtained by argentation thin-layer chromatography (TLC) followed by gas-liquid chromatography (GLC) with an internal standard. The glyceride compositions of directed interesterified fats, found by argentation TLC followed by GLC, indicated that the proportions of GS₃ and GU₃ increase to a considerable extent with simultaneous decrease in GSU₂, while that of GS₂U increases to a comparatively small extent, or remains unchanged.