Gas barrier properties and periodically fractured surface of thin DLC films coated on flexible polymer substrates

Thin DLC films coated on polymer surfaces are attracting considerable attention due to their wide applications and their interesting surface properties. When DLC films were coated on polymers, the resulting DLC-polymer composites are highly functionalized materials, some of which presenting dramatically improved gas barrier properties.In this paper, we will introduce several commonly used polymers including polyethylene terephthalate (PET), polyethylene (PE) and polypropylene (PP) for semi-crystalline polymers, and polymethyl methacyrlate (PMMA) for an amorphous polymer. The polymers were coated with thin DLC films and the gas barrier properties of the resulting DLC-polymer composites were investigated. Some of the DLC-polymer composites dramatically improved their gas barrier properties while they presented horizontal crack lines and vertical micro-buckling lines on the DLC surface when stretched to a certain strain. The gas barrier properties of the DLC-polymer composites with fractured DLC surface were also studied. It was found that the gas barrier property of the polymer substrates with lower residual strains was less damaged, when the substrates were mechanically deformed, than that of the polymer substrates with higher residual strains. When the number of the cracks increases, the strain imposed on each crack decreases, since the overall deformation is almost equally distributed to each crack while the crack spacing of each crack becomes shorter. Thus, it was found that the degradation of the gas barrier property after mechanical deformation is dependent on the residual strain of the polymers and the number of cracks on DLC films.     

Microstructure development of steel during severe plastic deformation

The microstructure development during plastic deformation was reviewed for iron and steel which were subjected to cold rolling or mechanical milling (MM) treatment, and the change in strengthening mechanism caused by the severe plastic deformation (SPD) was also discussed in terms of ultra grain refinement behavior. The microstructure of cold-rolled iron is characterized by a typical dislocation cell structure, where the strength can be explained by dislocation strengthening. It was confirmed that the increase in dislocation density by cold working is limited at 10¹⁶m⁻², which means the maximum hardness obtained by dislocation strengthening is HV3.7 GPa. However, the iron is abnormally work-hardened over the maximum dislocation strengthening by SPD of MM because of the ultra grain refinement caused by the SPD. In addition, impurity of carbon plays an important role in such grain refinement: the carbon addition leads to the formation of nano-crystallized structure in iron.     

Development of the remote-controlled platform truck for handling heavy object and the remote control human interface for the disaster response

General interest for robotic technology has been increased by the public and the media after Fukushima Daiichi Nuclear Power Plant (hereafter referred to as 1F) disaster. Especially, robots which can work under the very severe condition where personnel cannot access have demands for development. As to respond to such high demands, NEDO established ‘Disaster response unmanned systems development project’ in 2012.[1] This project is specialized in the development of various remote-controlled equipment, such as remote-controlled platform truck and remote control human interface under ‘Mobile Robot Development’. Remote-controlled platform truck is designed to safely and surely deliver robots and supplies, instead of using stairs and elevator, etc. in and out of building where it is too critical for personnel to work under. Remote control human interface for robots is designed to standardize the command and operation screen for operator, based on opinions from project members, and manned facility construction.[2] In this article, mechanical structure and development tasks for remote-controlled platform truck, and commonalization approach for operation and camera display of various remote-controlled equipment and robot for remote control human interface are stated. Background: due to hydrogen explosion triggered by The Great East Japan Earthquake on 11 March 2011, a reactor building at Fukushima Daiichi Nuclear Power Plant was severely damaged. It is required to reduce high radiation dose in the atmosphere of the reactor building to perform restoration. To pursue decontamination of the reactor building, equipment to lift and carry decontamination devices to upper floor are required.     

Topology optimization for fluid–thermal interaction problems under constant input power

This paper deals with density-based topology optimization considering fluid and thermal interactions, in which the Navier–Stokes and heat transport equations are coupled. We particularly focus on designing heat exchangers. In the engineering context, heat exchangers are designed while considering a certain amount of input power. Therefore it is important to maximize the performance of a heat exchanger under a constant input power. In this paper we propose a way to control the input power by introducing an extra integral equation. To be more precise, in the fluid analysis, the inlet pressure is determined by solving the extra integral equation together with the Navier–Stokes equation. By doing this we can keep the inlet power constant even when the flow channels are changed in the optimization process. Consequently, the system of equations of the fluid field takes an integrodifferential form. On the other hand, in the heat transport analysis, a single governing equation is defined for simultaneously modeling both the solid and fluid parts. The design variable is a fluid fraction whose distribution represents the topology of the solid and fluid domains. When designing heat exchangers, two different heat conditions are considered in the formulation of the optimization problems, namely temperature-dependent and temperature-independent heat sources. Through the numerical examples for designing flow channels in a heat exchanger, it is shown that distinct topologies can be obtained according to the input power and the heat source conditions.     

Impedancemetric gas sensor based on Pt and WO3 co-loaded TiO2 and ZrO2 as total NOx sensing materials

Pt-loaded metal oxides [WO₃/ZrO₂, MO_x/TiO₂ (MO_x = WO₃, MoO₃, V₂O₅), WO₃ and TiO₂] equipped with interdigital Au electrodes have been tested as a NO_x (NO and NO₂) gas sensor at 500 °C. The impedance value at 4 Hz was used as a sensing signal. Among the samples tested, Pt-WO₃/TiO₂ showed the highest sensor response magnitude to NO. The sensor was found to respond consistently and rapidly to change in concentration of NO and NO₂ in the oxygen rich and moist gas mixture at 500 °C. The 90% response and 90% recovery times were as short as less than 5–10 s. The impedance at 4 Hz of the present device was found to vary almost linearly with the logarithm of NO_x (NO or NO₂) concentration from 10 to 570 ppm. Pt-WO₃/TiO₂ showed responses to NO and NO₂ of the same algebraic sign and nearly the same magnitude, while Pt/WO₃ and WO₃/TiO₂ showed higher response to NO than NO₂. The impedance at 4 Hz in the presence of NO for Pt-WO₃/TiO₂ was almost equal at any O₂ concentration examined (1–99%), while in the case of Pt/WO₃ and WO₃/TiO₂ the impedance increased with the oxygen concentration. The features of Pt-WO₃/TiO₂ are favorable as a NO_x sensor that can monitor and control the NO_x concentration in automotive exhaust. The effect of WO₃ loading of Pt-WO₃/ZrO₂-based sensor is studied to discuss the role of surface W-OH sites on the NO_x sensing.     

Fabrication of large area diffraction grating using LIGA process

X-ray imaging is a very important technology in the fields of medical, biological, inspection, material science, etc. However, it is not enough to get the clear X-ray imaging with low absorbance. We have produced a diffraction gratings for obtaining high resolution X-ray phase imaging, such as X-ray Talbot interferometer. In this X-ray Talbot interferometer, diffraction gratings were required to have a fine, high accuracy, high aspect ratio structure. Then, we succeeded to fabricate a high aspect ratio diffraction grating with a pitch of 8 μm and small area using a deep X-ray lithography technique. We discuss that the diffraction gratings having a narrow pitch and an large effective area to obtain imaging size of practical use in medical application. If the pitch of diffraction gratings were narrow, it is expected high resolution imaging for X-ray Talbot interferometer. We succeeded and fabricated the diffraction grating with pitch of 5.3 μm, Au height of 28 μm and an effective area of 60 × 60 mm².     

Nonequilibrium dynamics of a reacting network system

The nonlinear nonequilibrium properties of reacting network systems are studied by computer simulations. It is shown that the fluctuation in the population of each chemical species obeys a log-normal distribution, not the normal Gaussian distribution. The reaction rate shows power-law decay with activation cost (energy), not the Arrhenius-type exponential decay observed in a linear nonequilibrium regime. These two characteristic features will explain the diversity, plasticity, and adaptivity observed in complex biological reaction networks. This work was presented in part at the 13th International Symposium on Artifical Life and Robotics, Oita, Japan, January 31–February 2, 2008     

Closed-form forward kinematics solutions of a 4-DOF parallel robot

It is well known that the forward kinematics of parallel robots is a very difficult problem. Closed-form forward kinematics solutions have been reported only to a few special classes of parallel robots. This paper presents closed-form forward kinematics solutions of a 4-DOF parallel robot H4. A 16th order polynomial in a single variable is derived to solve the forward kinematics of the H4. The 16 roots of the polynomial lead to at most 16 different forward kinematics solutions. A numerical verification is also presented.     

Stabilization of geometrically nonlinear topology optimization by the Levenberg–Marquardt method

This paper deals with the design of compliant mechanisms in a continuum-based finite-element representation. Because the displacements of mechanisms are intrinsically large, the geometric nonlinearity is essential for designing such mechanisms. However, the consideration of the geometric nonlinearity may cause some instability in topology optimization. The problem is in the analysis part but not in the optimization part. To alleviate the analysis problem and eventually stabilize the optimization process, this paper proposes to apply the Levenberg–Marquardt method to the nonlinear analysis of compliant mechanisms.