Using chemical reactivity to provide insights into environmental transformations of priority organic substances: the Fe⁰-mediated reduction of Acid Blue 129

Sulfonated anthracenedione dyes are medium priority organic compounds targeted for environmental assessment under the Government of Canada's Chemical Management Plan (CMP). Since organic compounds undergo transformations in environmental matrices, understanding these transformations is critical for a proper assessment of their environmental fate. In the current study, we used zero-valent iron (ZVI) to provide insight into reductive transformation processes available to the anthracenedione dye, Acid Blue 129 (AB 129), a dye which is used in the textile industry. At high temperatures, we found that AB 129 was rapidly reduced (within 3 h) after being adsorbed onto the ZVI-surface, whereupon decomposition took place via multiple competitive and consecutive reaction pathways. Reaction products were identified using state-of-the-art accurate mass Liquid Chromatography-Quadrupole Time of Flight-Mass Spectroscopy (LC-QToF-MS). Five transformation products were identified, including a genotoxic (and thus, potentially carcinogenic) end-product, 2,4,6-trimethylaniline. The same products were found at room temperature, demonstrating that the transformation pathways revealed here could plausibly arise from biological and/or environmental reductions of AB 129. Our results demonstrate the importance of identifying reaction product arising from priority substances as part of the environmental risk assessment process.     

Reliability modeling of degradation of products with multiple performance characteristics based on gamma processes

Many highly reliable products usually have complex structure, with their reliability being evaluated by two or more performance characteristics. In certain physical situations, the degradation of these performance characteristics would be always positive and strictly increasing. In such a case, the gamma process is usually considered as a degradation process due to its independent and non-negative increments properties. In this paper, we suppose that a product has two dependent performance characteristics and that their degradation can be modeled by gamma processes. For such a bivariate degradation involving two performance characteristics, we propose to use a bivariate Birnbaum-Saunders distribution and its marginal distributions to approximate the reliability function. Inferential method for the corresponding model parameters is then developed. Finally, for an illustration of the proposed model and method, a numerical example about fatigue cracks is discussed and some computational results are presented.     

Switched predictor adaptation of DPCM-AQB speech coder using an imbedded vector quantisation

An adaptive differential pulse-code-modulation speech coder with a switched predictor adaptation scheme is described. The predictor adaptation is done by switching one of the several predetermined predictors stored both at the encoder and the decoder. The selection of the predictor is controlled by a vector quantiser. The tradeoff between the performance and the extra side information that needs to be transmitted is evaluated for bit rates of 16, 24 and 32 Kbit/s.     

Analyzing unidentified locked-joint failures in kinematically redundant manipulators

Robots are frequently used for operations in hostile environments. The very nature of these environments, however, increases the likelihood of robot failures. Common failure-tolerance techniques rely on effective failure detection and identification. Since a failure may not always be successfully identified, or, even if identified, may not be identified soon enough, it becomes important to consider the behavior of manipulators with unidentified failures. This work investigates the behavior of robots experiencing unidentified locked-joint failures in a general class of tasks characterized by point-to-point motion. Based on the analysis, a procedure for workspace evaluation is developed that allows for the identification of regions in the manipulator's workspace in which tasks may be completed even with such failures. © 2005 Wiley Periodicals, Inc.     

Optimal price and quantity determination for retail electric power contracts

Considering the viewpoint of a retailer, this paper analyzes the problem of setting up contracts on both the supplier and end-user sides to maximize profits while maintaining an acceptable level of settlement risk. The proposed stochastic optimization model can assist retailers with these efforts and guide them in their contractual arrangements. A realistic example illustrates the capabilities of the methodology proposed.     

Implications of Autonomy for the Expressiveness of Policy Routing

Thousands of competing autonomous systems must cooperate with each other to provide global Internet connectivity. Each autonomous system (AS) encodes various economic, business, and performance decisions in its routing policy. The current interdomain routing system enables each AS to express policy using rankings that determine how each router in the AS chooses among different routes to a destination, and filters that determine which routes are hidden from each neighboring AS. Because the Internet is composed of many independent, competing networks, the interdomain routing system should provide autonomy, allowing network operators to set their rankings independently, and to have no constraints on allowed filters. This paper studies routing protocol stability under these conditions. We first demonstrate that ldquonext-hop rankings,rdquo commonly used in practice, may not ensure routing stability. We then prove that, when providers can set rankings and filters autonomously, guaranteeing that the routing system will converge to a stable path assignment imposes strong restrictions on the rankings ASes are allowed to choose. We discuss the implications of these results for the future of interdomain routing.     

Characterization of fluctuation statistics of radar clutter forIndian terrain

Characterization of the fluctuation statistics of radar clutter using Weibull and lognormal distribution models, is presented. Both farmland and sea clutter data measured using a noncoherent, airborne S-band radar are used in the analysis. The clutter data represent the first measurements from an airborne platform over Indian terrain. The values of the distribution parameters estimated using two different techniques have also been presented along with the different criteria used to classify the clutter