Mixed oxide supported hydrodesulfurization catalysts—a review

Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al₂O₃ containing mixed oxide supports, TiO₂ containing mixed oxide supports, ZrO₂ containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO₂ containing mixed oxides received maximum attention, especially TiO₂–Al₂O₃ supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication.     

光学材料的激光微加工研究进展与应用前景

综述了国内外在光学材料激光微加工方面的研究成果和应用状况，并展望了其发展前景。     

Explosive chemistry: Simulating the chemistry of energetic materials at extreme conditions

In this article, we review recent atomistic computational techniques to study the electronic structure aspects and chemistry of energetic materials at high-pressure and/or high temperature. While several mechanisms have been proposed for the initial events of energetic materials at high-pressure, we explore the validity of a proposed shear-induced local metallization via molecular bond bending in the insensitive explosive TATB. We study the effect of high-stress (both uniform and uniaxial) on the electronic energy band-gap and the first chemical event of a prototypical energetic material, that of nitromethane. We also determine chemical reactions rate laws and decomposition mechanisms from a quantum-based molecular dynamics simulation of HMX, a widely used explosive material, at conditions of high density and temperature similar to that encounter under detonation. Finally, we review a new multi-scale computational tool recently developed to model the shock-induced chemistry of energetic materials at the atomistic level, and report its applicability to shocked solid nitromethane. This revised version was published online in June 2006 with corrections to the Cover Date.     

三峡工程三期截流三维施工仿真研究

三峡工程三期截流提前到 2 0 0 2年 11月上旬进行 ,截流难度显著增大。为了使截流工程顺利进行 ,以先进的计算机可视化技术为基础 ,采用IMAGIS软件生成三维地形图 ,用Creator建模形成导流明渠、纵向围堰及三期围堰等三维实体模型 ,最后通过运用虚拟现实技术 ,开发出三峡工程三期截流施工实时动态演示、查询系统。该系统能根据需要实现漫游 ,可以随意定位到感兴趣的区域作细部观察 ,且具有良好的交互性。通过施工仿真研究 ,将三期截流施工过程生动地显示在屏幕上 ,用以指导施工组织管理 ,为三期截流的决策和控制提供了有效的工具     

正确选择气顶油藏高效开发模式

通过对不同类型气顶油藏的油气水分布特征及气顶和边水能量的研究分析，计算水侵量与边水体积及合理的弹性产率。提出适合气顶油藏特点的开发模式是先开采油区后开采气顶，并以唐家河油田港深18—2断块为例，证明采用该模式可以高效开发气顶油藏。图3表1参6     

东濮凹陷三春集下第三系隐蔽油气藏研究

东濮凹陷三春集地区下第三系隆起带各高点勘探效果较东翼斜坡带差，但具备形成隐蔽油气藏的地质条件，该地区沙四上亚段－沙三下亚段烃源岩晚第三纪早中期产烃规模有限，生成的油气沿着断层向固阳洼陷西侧运移，在春东断层下降盘中的反向屋脊岩性圈闭中富集。通过石油地质综合研究，预测固阳洼陷西侧为三春集构造带陷蔽油气藏滚动勘探的有利地区。图3参2（张建军摘）。     

MIM隧道发光结的负阻现象

本文介绍了薄膜隧道发光结的基本结构、发光机理，阐述了其Ｉ－Ｖ特性中的负阻现象。简单介绍了ＭＩＭ结构负阻的几种解释，根据热像仪照片和低温测试结果分析，再结合Ｄｅａｒｍａｌｅｙ导电模型，我们提出了ＭＩＭ负阻的物理模型，理论与实验符合较好，最后分析了负阻现象的应用前景。     

油气圈闭地质评价方法及应用

本从含油气系统理论出发，对圈闭成藏的油源，储层，圈闭，保存，配套史制定分级评价标准，并赋予相应的评价系数，在此基础上应用地质风险概率理论与模糊数学的方法，在微机上定量评价圈闭含油气性。     

防垢剂BZF－2的研制与应用

桩西油田产出原油综合含水已达６０％－７０％，原用防垢剂ＨＥＤＰ已失去有效抑制集输站结垢的性能。本工作针对结垢最严重的桩５２站的应用，研制了以有机膦化合物和聚氧乙烯醚为主成份的防垢剂ＢＺＦ－２，在室内考察了不同条件下的防垢率、腐蚀性、配伍性等性能，在桩５２站进行了为期４个月的现场试验，加量为１０．３ｍｌ／ｌ、防垢率≥９８．０％，加药设备管线的腐蚀率大大降低。