Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization

The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.     

色泽异常肉的检验和处理

本文通过对市场上五种常见色泽异常肉的检验与处理,为广大消费者提供了便利的鉴别手段,使“吃上放心肉”提供了可靠的依据,并在此基础上技术上有了新的改进。通过临床实践经验,采用对比法以及实验室快速检验法对五种常见色泽异常肉进行不同程度的处理。通过检验和处理常见色泽异常肉,反映了我国市场存在的严重问题,有待于我们进一步加强动检法。     

聚合物与水气交替联驱提高采收率试验研究

采用三种不同沉积韵律平面模型试验研究水驱后聚合物与水气交替联驱提高原油采收率的驱替特征。结果表明,聚合物与水气交替联驱对正韵律油藏提高采收率效果很好;对反韵律油藏和复合韵律油藏也有不同程度提高采收率效果。通过分析两种不同韵律砂岩油藏水气交替提高采收率矿场试验成功实例,认为聚合物与水气交替联驱法可综合发挥两种方法的优势,在类似油藏中比单一方法有更好的提高采收率效果。     

Effect of V doping concentration on the electronic structure,optical and photocatalytic properties of nano-sized V-doped anatase TiO2

V-doped TiO₂ with V/Ti ratio of 1–5% has been synthesized by hydrothermal method and then characterized by XRD, TEM, BET specific surface area, XPS and UV–vis. absorption spectra. The photocatalytic activity of the as-synthesized samples was investigated by the degradation of methylene blue in aqueous solution under visible light irradiation. Density functional theory (DFT) based calculations were performed to investigate the mechanism of band gap narrowing, the shift of light absorption edge, the location of V in the TiO₂ lattice and the variation in electronic and optical properties of TiO₂ with the increase of V doping concentration. Irrespective of the V doping concentration, TEM images indicate that all the doped samples were composed of equiaxed spherical anatase TiO₂ particles with good crystallinity and uniform particle size distribution. Both the experimental results from XPS survey and the theoretical calculation argue that the doped V replaces the lattice Ti and form substitutional impurity. The visible light absorption can be optimized by adjusting the V doping concentration. Among the doped samples with different V doping concentrations, the sample with V/Ti ratio of 2% depicts better visible light photocatalytic activity due to the enhanced visible light absorption and improved separation of electron–hole pairs.     

30.4 nm Si/C多层膜反射镜的制备与测量

采用离子束溅射镀膜装置制备了一种新的材料组合Si/C多层膜 ,用于 30 4nm波段的正入射多层膜反射镜。并用软X射线反射率计测得其反射比最大值为 0 14。有效地抑制了 15 0nm处的二级衍射峰。     

汽车挡风玻璃刮雨器的控制

本拟设计了一种用于汽车挡风玻璃上的自动雨点检测器及刮雨器控制装置,其原理利用了挡风玻璃中的光波导作用,并经模拟实验证实此方案可行。     

热挤压变形力计算的研究

本文考虑到变形区内切应力非线性分布的特点,采用球坐标系下的平衡微分方程和塑性条件联立求解,得出圆棒热挤压时变形区入口球面上的应力分布方程,然后应用功平衡法导出了圆棒热挤压力的计算公式。     

Preparation and thermophysical properties of nano-sized Ln2Zr2O7 (Ln?=?La, Nd, Sm, and Gd) ceramics with pyrochlore structure

Rare earth zirconates (Ln₂Zr₂O₇, Ln = La, Nd, Sm, and Gd) with pyrochlore structure were prepared by hydrothermal method with polyethylene glycol as surfactant. X-ray diffraction, thermogravimetric analysis/differential scanning calorimetry, Fourier transform infrared spectroscopy, Raman spectroscopy, and field emission scanning electron microscopy were utilized to characterize the phase structure, thermal decomposition, and morphology of the products. Qualitative analysis indicates that the as-prepared zirconates are pyrochlore-type structures. The specific surface area, lattice parameter, and average crystallite size of the as-prepared products are closely related to the ionic radius. The activation energy of crystal growth shows an increasing trend with the decrease in ionic radii. The sintering behavior of compacted body was also investigated, revealing that the sintering-resistance properties of Ln₂Zr₂O₇ are descending as the order of La₂Zr₂O₇, Nd₂Zr₂O₇, Sm₂Zr₂O₇, and Gd₂Zr₂O₇.     

Fabrication of Cu(In,Ga)Se2 thin films by ion beam sputtering deposition from a quaternary target at different substrate temperatures

Cu(In, Ga)Se₂ (CIGS) thin films were fabricated by ion beam sputtering deposition from a single quaternary target at different substrate temperatures (T _sub). The thin films were characterized with X-ray diffractometry, scanning electron microscopy, energy-dispersive X-ray spectroscopy and four-point probe technique to study the microstructures, surface morphology, composition and electrical properties, respectively. The results show that the films grown above 400?°C are of chalcopyrite structure. Cu(In_0.7Ga_0.3)Se₂ thin film was obtained when T _sub is 550?°C. The Cu and Se atomic percentage when T _sub is above 500?°C is higher than when T _sub is below 500?°C. With the increase in T _sub, the surfaces morphology of the films is denser and the resistivity of the films decreases.     

全层片状TiAl基合金断裂过程的原位观察

利用ＳＥＭ拉伸台，研究了Ｔｉ－３３Ａｌ－３Ｃｒ－０．５Ｍｏ合金的室温拉伸断裂动态过程。试验结果表明，具有全层片状显微组织的ＴｉＡｌ合金室温断裂韧性较高，归因于合金拉伸过程中裂纹尖端发生分叉致使应力松弛而使裂纹钝化；在变形过程中，主裂纹尖端附近的微裂纹之间形成剪切韧带，剪切韧带韧化是ＴｉＡｌ合金的一种韧化机理。