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41.
In the present work, a continuous photo-fermentative hydrogen (H2) production from lactate was attempted at various hydraulic retention times (HRTs) (48–120 h). Electron balance was made at each operating conditions to elucidate different performances. At 120 h HRT, H2 production was negligible, while 42% and 52% of substrate electrons diverted towards cell growth and soluble microbial products (SMPs), respectively. After changing HRT to 96 h, H2 yield jumped to 2.3 mol-H2/mol-lactateadded with less SMPs production and minimal cell growth. The highest H2 production rate of 260 mL-H2/L-fermenter/d was also achieved at 96 h HRT. When HRT was further shortened to 72 and 48 h, H2 yield dropped to 1.4 and 0.2 mol-H2/mol-lactateadded, respectively. While almost all of the lactate was degraded at <72 h HRT, only 65% of the lactate was consumed at 48 h HRT. From 200th day, the feedstock was changed to lactate-rich acidified food waste, which was obtained via one-day fermentation of food waste and subsequent centrifugation. At 2 g chemical oxygen demand/L, substrate conversion efficiency reached 35%, which was slightly lower than that of feeding pure lactate. SMPs were found to be mainly consisted of low molecular weight compounds (<500 Da), and the majority of organic matters were aromatic proteins at 120 h HRT and it was shifted to humic-like region in 96 h HRT.  相似文献   
42.
In this paper, a three-phase current-fed dc/dc converter with an active clamp is introduced, and a new three-phase three-leg high frequency transformer is proposed for the converter. The three-phase dc/dc converter transfers power through transformer leakage inductances in the discontinuous current mode; a single common active clamp branch is employed for zero-voltage switching (ZVS) in all active switches. Further, the converter's three-phase power configuration increases power transfer, and it reduces the rms current per phase, thus reduces conduction losses. Moreover, a delta–delta connection on the three-phase transformer provides parallel current paths and reduces conduction losses in the transformer windings. A three-phase transformer can be constructed by connecting three discrete single-phase transformers, but this process results in a higher volume and higher material costs. Therefore, a new three-phase three-leg high frequency transformer is designed with three discrete cores integrated into a single transformer core. The proposed transformer is analyzed according to the several operating modes of the converter, and its design rules are determined. Experimental results are obtained on a 500-W prototype unit; the design is fully verified and analyzed.  相似文献   
43.
    
We discuss models of preventive maintenance (PM) under different assumptions on the failure/repair processes. The main emphasis is on the PM modeling under the Brown‐Proschan model for minimal/perfect repairs. We also present the generalization of this model for the failure/repair process governed by the generalized Polya process. Some comparisons with conventional PM models are discussed (Nonhomogeneous Poisson process, renewal process, and geometric process of failure/repairs). Several practical examples are considered.  相似文献   
44.
    
Understanding and possibly recovering from the failure mechanisms of phase change memories (PCMs) are critical to improving their cycle life. Extensive electrical testing and postfailure electron microscopy analysis have shown that stuck–set failure can be recovered. Here, self‐healing of novel confined PCM devices is directly shown by controlling the electromigration of the phase change material at the nanoscale. In contrast to the current mushroom PCM, the confined PCM has a metallic surfactant layer, which enables effective Joule heating to control the phase change material even in the presence of a large void. In situ transmission electron microscope movies show that the voltage polarity controls the direction of electromigration of the phase change material, which can be used to fill nanoscale voids that form during programing. Surprisingly, a single voltage pulse can induce dramatic migration of antimony (Sb) due to high current density in the PCM device. Based on the finding, self‐healing of a large void inside a confined PCM device with a metallic liner is demonstrated for the first time.  相似文献   
45.
    
Edges of 2D transition metal dichalcogenides (TMDs) are well known as highly reactive sites, thus researchers have attempted to maximize the edge site density of 2D TMDs. In this work, metal‐organic framework (MOF) templates are introduced to synthesize few‐layered WS2 nanoplates (a lateral dimension of ≈10 nm) confined in Co, N‐doped hollow carbon nanocages (WS2_Co‐N‐HCNCs), for highly sensitive NO2 gas sensors. WS2 precursors are assembled in the surface cavity of Co‐based zeolite imidazole framework (ZIF‐67) and subsequent pyrolysis produced WS2_Co‐N‐HCNCs. During the pyrolysis, the carbonized ZIF‐67 are doped by Co and N elements, and the growth of WS2 is effectively suppressed, creating few‐layered WS2 nanoplates functionalized Co‐N‐HCNCs. The WS2_Co‐N‐HCNCs exhibit outstanding NO2 sensing characteristics at room temperature, in terms of response (48.2% to 5 ppm), selectivity, response and recovery speed, and detection limit (100 ppb). These results are attributed to the enhanced adsorption and desorption kinetics of NO2 on abundant WS2 edges, confined in the gas permeable HCNCs. This work opens up an efficient way for the facile synthesis of edge abundant few‐layered TMDs combined with porous carbon matrix via MOF templating route, for applications relying on highly active sites.  相似文献   
46.
    
Transition metal dichalcogenides (TMDs) have emerged as promising materials to complement graphene for advanced optoelectronics. However, irreversible degradation of chemical vapor deposition‐grown monolayer TMDs via oxidation under ambient conditions limits applications of TMD‐based devices. Here, the growth of oxidation‐resistant tungsten disulfide (WS2) monolayers on graphene is demonstrated, and the mechanism of oxidation of WS2 on SiO2, graphene/SiO2, and on graphene suspended in air is elucidated. While WS2 on a SiO2 substrate begins oxidation within weeks, epitaxially grown WS2 on suspended graphene does not show any sign of oxidation, attributed to the screening effect of surface electric field caused by the substrate. The control of a local oxidation of WS2 on a SiO2 substrate by a local electric field created using an atomic force microscope tip is also demonstrated.  相似文献   
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49.
    
Although BKNO3 ignited by ZPP is commonly used as an explosive charge for many pyrotechnics, only a limited number of modeling studies can be found in the literature. Thus, recently proposed governing equations for combustion modeling of ZPP are supplemented to simulate the combustion of the BKNO3 with ZPP. The combustion model was independently validated using CBT results with fixed volume chambers of various sizes. In this process, the concept of the unburning ratio was introduced to correlate the combustion modeling with actual phenomena. The term “unburned” means that some fraction of explosive charge turns into non-reactive solid rather than into combustion products. The model was then coupled with the equations of motion for the internal moving parts of a pyroshock-reduced separation nut. Tests with prototype were performed to validate the coupled model. For accurate verification, the pressure of the expansion chamber and annular chamber and the displacement of the bolt were measured and compared. All measurements are in good agreement with the analysis results obtained from the coupled model. The results validated the generality of the modeling approach for the simulation of the pyroshock-reduced separation nut.  相似文献   
50.
    
The esophagus is a tubular-shaped muscular organ where swallowed fluids and muscular contractions constitute a highly dynamic environment. The turbulent, coordinated processes that occur through the oropharyngeal conduit can often compromise targeted administration of therapeutic drugs to a lesion, significantly reducing therapeutic efficacy. Here, magnetically guidable drug vehicles capable of strongly adhering to target sites using a bioengineered mussel adhesive protein (MAP) to achieve localized delivery of therapeutic drugs against the hydrodynamic physiological conditions are proposed. A suite of highly uniform microparticles embedded with iron oxide (IO) nanoparticles (MAP@IO MPs) is microfluidically fabricated using the genipin-mediated covalent cross-linking of bioengineered MAP. The MAP@IO MPs are successfully targeted to a specific region and prolongedly retained in the tubular-structured passageway. In particular, orally administered MAP@IO MPs are effectively captured in the esophagus in vivo in a magnetically guidable manner. Moreover, doxorubicin (DOX)-loaded MAP@IO MPs exhibit a sustainable DOX release profile, effective anticancer therapeutic activity, and excellent biocompatibility. Thus, the magnetically guidable locomotion and robust underwater adhesive properties of the proteinaceous soft microbots can provide an intelligent modular approach for targeted locoregional therapeutics delivery to a specific lesion site in dynamic fluid-associated tubular organs such as the esophagus.  相似文献   
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