Catalyst and its diameter dependent growth kinetics of CVD grown GaN nanowires

GaN nanowires were grown using chemical vapor deposition with controlled aspect ratio. The catalyst and catalyst-diameter dependent growth kinetics is investigated in detail. We first discuss gold catalyst diameter dependent growth kinetics and subsequently compare with nickel and palladium catalyst. For different diameters of gold catalyst there was hardly any variation in the length of the nanowires but for other catalysts with different diameter a strong length variation of the nanowires was observed. We calculated the critical diameter dependence on adatoms pressure inside the reactor and inside the catalytic particle. This gives an increasing trend in critical diameter as per the order gold, nickel and palladium for the current set of experimental conditions. Based on the critical diameter, with gold and nickel catalyst the nanowire growth was understood to be governed by limited surface diffusion of adatoms and by Gibbs–Thomson effect for the palladium catalyst.     

Analysis of the reference accidental sequence for safety assessment of LLCB TBM system

Safety analysis of the reference accidental sequence has been carried out for Lead Lithium cooled Ceramic Breeder (LLCB) Test Blanket Module (TBM) system; India's prototype of DEMO blanket concept for testing in International Thermonuclear Experimental Reactor (ITER). The accidental event analyzed starts with a Postulated Initiating Event (PIE) of ex-vessel loss of first wall helium coolant due to guillotine rupture of coolant pipe with simultaneous assumed failure of plasma shutdown system. Three different variants of the sequences analyzed include simultaneous additional failures of TBM and ITER first wall, failure of TBM box resulting in to spilling of lead lithium liquid metal in to vacuum vessel and reactor trip on Loss of Coolant Accident (LOCA) signal from TBM system. The analysis address specific reactor safety concerns, such as pressurization of confinement buildings, vacuum vessel pressurization, release of activated products and tritium during these accidental events and hydrogen production from chemical reactions between lead–lithium liquid metal and beryllium with water. An in-house customized computer code is developed and through these deterministic safety analyses the prescribed safety limits are shown to be well within limits for Indian LLCB-TBM design and it also meets overall safety goal for ITER. This paper reports transient analysis results of the safety assessment.     

Uncertainty in estimating renewable energy utilisation potential: a case of solar thermal power generation in India

Estimation of renewable energy utilisation potential is important for identification of niche areas and prioritisation amongst different options. However, large variation in the potential estimates has been observed in different studies for the same renewable energy technology. This study is an attempt to analyse such a variation in the estimated potential for solar thermal power generation in India. From the analysis of three studies, it is found that the values of input parameters and the assumptions made substantially affect the estimated potential. The estimates of the utilisation potential depend upon the categories of wastelands selected, the chosen values of threshold DNI and wind speed as well as the criteria used for allocating suitable wastelands between solar photo-voltaic (PV) and thermal power generation. It is therefore critically important that reported values of renewable energy utilisation potential be interpreted and used with full cognisance of assumptions made and input parameters used in estimation.     

Application of Imaging Techniques to Geometry Analysis of Aggregate Particles

This paper presents image analysis techniques by which to characterize the texture, angularity, and form of aggregate particles used in highway construction and geotechnical applications. For texture analysis, wavelet decomposition in gray scale images of particles is performed. The results demonstrate that multiscale wavelet representation is a powerful tool by which to capture the texture and to differentiate “true” texture from “false” texture caused by variations of natural color on a particle surface. Angularity and form analyses of particles are done using binary images. A gradient-based method is employed to describe angularity. This method is shown to differentiate between particles with different angularity characteristics. Form analysis of the particles includes computing the shape factor and sphericity index, which are based on measurements of the shortest, intermediate, and longest axis of the particle. Particle thickness is measured using the feature of an autofocus microscope. The width and length are calculated by an eigenvalue decomposition method of two-dimensional particle projections. Details of an interactive software developed to compute the different aggregate shape factors are discussed. The results indicate that these calculated values of the particle dimensions match very closely the values measured manually using a digital caliper.     

Impact of Halo Doping on the Subthreshold Performance of Deep-Submicrometer CMOS Devices and Circuits for Ultralow Power Analog/Mixed-Signal Applications

In addition to its attractiveness for ultralow power applications, analog CMOS circuits based on the subthreshold operation of the devices are known to have significantly higher gain as compared to their superthreshold counterpart. The effects of halo [both double-halo (DH) and single-halo or lateral asymmetric channel (LAC)] doping on the subthreshold analog performance of 100-nm CMOS devices are systematically investigated for the first time with extensive process and device simulations. In the subthreshold region, although the halo doping is found to improve the device performance parameters for analog applications (such as g_m/I_d, output resistance and intrinsic gain) in general, the improvement is significant in the LAC devices. Low angle of tilt of the halo implant is found to give the best improvement in both the LAC and DH devices. Our results show that the CMOS amplifiers made with the halo implanted devices have higher voltage gain over their conventional counterpart, and a more than 100% improvement in the voltage gain is observed when LAC doping is made on both the p- and n-channel devices of the amplifier     

Extrusion Processing of High-Strength Al Alloy 7055

The effects of a combination of extrusion processing parameters and aging schedules on the microstructure and mechanical properties of the 7055 Al alloy were investigated. A safe extrusion processing zone is determined through a limit diagram constructed over the experimental initial billet temperature ranging from 380° to 420°C, extrusion ratio from 10:1 to 40:1, and the ram speed ranging from 1 to 15 mm s^-1. Microstructural characterization of as-extruded, solution-treated, and artificially-aged materials was carried out using polarized light microscopy (for grain structure) and transmission electron microscopy (for precipitate morphology). A combination of hardness and tensile tests was used to evaluate mechanical properties. It is shown that in 7055 Al alloy, the optimization of alloy composition, extrusion processing parameters, and peak aging treatment results in reproducible tensile properties of 0.2% P.S. = 725 MPa, UTS = 750 MPa, and % elongation = 12.9. In order to improve the stress-corrosion resistance of peak aged material, retrogression and reaging (RRA) temper was established. A strength-electrical conductivity relationship has been established for the RRA temper between 36% and 37% International Annealed Copper Standard (IACS) electrical conductivity to enable selection of suitable combination of properties.     

Structure and dynamics of confined water inside narrow carbon nanotubes

We have performed atomistic molecular dynamics (MD) simulations of water molecules inside narrow, open-ended carbon nanotubes placed in a bath of water molecules. The radius of the tube is such that only a single file of water molecules is allowed inside the tube. The confined water molecules are shown to be positionally ordered even at a temperature of 300 K. The calculated mean-square displacement (MSD) of the confined water molecules reveals that initially the water molecules undergo ballistic motion that crosses over to normal (Fickian) diffusion at longer times. We also develop a random-walk model in 1D for the motion of a cluster of water molecules inside the nanotube. The agreement of the MSD calculated from the MD simulation and from the 1 D random-walk model establishes the occurrence of normal diffusion of water molecules even in a tube where single-file diffusion is expected.     

Complete delay modeling of sub‐threshold CMOS logic gates for low‐power application

In this paper, the propagation delay of a complementary metal‐oxide semiconductor (CMOS) inverter circuit in sub‐threshold regime has been analyzed thoroughly with respect to variable loads, rise and fall time of input, device dimensions and temperature, without neglecting the significant drain induced barrier lowering (DIBL) and body bias effects. In particular, sub‐threshold slope factor and current strength have been modeled with respect to temperature, which would be efficacious for the analysis of sub‐threshold circuit as temperature plays an important role in propagation delay. Transistor stacking has also been modeled considering variation in threshold voltage, sub‐threshold slope factor and DIBL coefficient owing mainly to fluctuation in doping levels. The CMOS inverter delay model together with transistor stacking model has been incorporated in the analysis of propagation delays of NAND and NOR gates. Extensive simulations have been performed under 45 and 22 nm CMOS technology using simulation program with integrated circuit emphasis (SPICE) to ensure the correctness of the analysis. Simulation shows that this model is applicable for the analysis of digital sub‐threshold circuit in sub‐90 nm technology. Copyright © 2015 John Wiley & Sons, Ltd.     

Modified Hydraulic Models for Thin Smoke and Crowd Crawling Phenomena

Fire Technology - The hydraulic model is a set of closed-form, deterministic equations used to predict average crowd speeds and movement times of evacuees exiting a building. The standard SFPE...