Fundamentals of the incremental tube forming process

The manufacture of bent tubes made of high-strength materials requires high bending loads, which lead to large springback and eventually distortion of the cross-section. The incremental tube forming process allows significant reduction of the bending moment. This is achieved by combining the continuous bending process with an incremental tube spinning process. The paper describes an analytical model to predict the bending moment reduction as a function of the superposed spinning process parameters. Experimental results are provided to validate the theoretical results. This model allows the design and optimization of the incremental tube forming process with low springback.     

Pathogen-induced Release of Plant Allomone Manipulates Vector Insect Behavior

Infochemicals mediate communication within and between different trophic levels. In this study, we identified a new type of plant allomone induced by a plant pathogen and perceived by its vector insect Cacopsylla picta. This phloem-feeding psyllid is the main vector of Candidatus Phytoplasma mali, a cell wall-lacking bacterium that causes the so-called apple proliferation disease. In a previous study, we showed that newly emerged females of C. picta were attracted by the odor of phytoplasma-infected apple plants (Malus domestica), which release ß-caryophyllene in contrast to uninfected plants. Here, the attractiveness of this sesquiterpene for C. picta was confirmed in both olfactometer bioassays and field studies. Synthetic ß-caryophyllene was highly attractive to newly emerged adults of C. picta both when offered simultaneously with healthy apple odor and without. The psyllid’s response was independent of its odor experience and infection status. These results confirm our previously established hypothesis that this phytoplasma manipulates the behavior of its vector insect by changing the odor blend of its host plant. Deployed in apple orchards, sticky traps baited with ß-caryophyllene dispensers caught both males and females of C. picta. Consequently, this new type of infochemical, i.e., a phytopathogen-induced plant allomone, represents a promising compound to develop innovative techniques for monitoring or maybe even mass trapping of C. picta.     

Dense silicon carbonitride ceramics by pyrolysis of cross-linked and warm pressed polysilazane powders

This study reports on the pyrolysis and densifaction behavior of cross-linked poly(hydridomethylsilazane) powders. The influence of the cross-linking procedure such as temperature and annealing time of the polymer powders on the compaction behavior under cold and warm pressing conditions is discussed. The degree of cross-linking is determined by thermal mechanical analysis (TMA). In addition to particle sliding which is assumed to be the compaction mechanism obtained by cold-pressing, the polymer powder consolidates by plastic deformation applying warm-pressing. A continuous 3-dimensional polysilazane network is formed after a dwelling time under these conditions. Pyrolysis of the cross-linked and compacted polysilazane powder in argon at 1100°C gives crack-free amorphous silicon carbonitride Si_3+xC_x+yN₄ with compositions ranging from x=1·47 and y=0·88 for cold pressed samples to x=1·47 and y=1·86 for warm pressed materials. The residual open porosity is significantly reduced from 10–15 vol% in the cold pressed specimens to 1·3–5 vol% by the warm pressing procedure. The weight loss during pyrolysis between room temperature and 1300°C is about 5 wt% lower than that for cold pressed specimens. This result is explained by a reduced methane evolution during the polymer-to-ceramic conversion and is in accordance with the enhanced carbon content of the warm pressed material.     

Reversible and irreversible degradation of organic solar cell performance by oxygen

The effect of oxygen on the degradation of inverted bulk heterojunction solar cells based on poly(3-hexylthiophene):[6,6]-phenyl-C₆₁-butyric acid methyl ester (P3HT:PCBM) blends has been investigated by monitoring current-voltage (jV)-curves, impedance spectra and charge extraction by linearly increasing voltage (CELIV) traces during the degradation process. The use of gas permeable top electrodes allows monitoring the kinetics of degradation without being limited by the diffusion through a compact metal electrode. A computational model is used to provide a phenomenological explanation of the experimental results. The charge distribution inside the device is modeled by solving the fully coupled set of nonlinear differential equations for the quasi-one-dimensional transport of electrons and holes.Degradation of the cells in the presence of oxygen results mainly in the reduction of short circuit current (j_sc), while the concomitant loss in light absorption is negligible. The rate of degradation is enhanced significantly by illumination. A significant part of the loss in j_sc is reversible upon annealing under nitrogen or in vacuum.The irreversible part of the degradation is assigned to the photochemical formation of carbonyl and carboxylic groups, which act as traps for electrons. The reversible component of degradation is due to p-doping of the photoactive layer by oxygen, which results in the formation of mobile holes and immobile superoxide anions. This leads to the formation of a space charge region in front of the electron extracting electrode whose width depends on the doping level as well as on the applied bias. The space charge region shields the electric field inside the photoactive layer and hence hampers charge carrier extraction, which leads to the observed loss in short circuit current.     

Second generation CIS solar modules

Multinary Cu(In,Ga)(Se,S)₂ absorbers (abrev. CIGSSe) are promising candidates for reducing the cost of photovoltaics well below the cost of crystalline silicon. Shell Solar has pioneered production of this new thin film technology and is now with the first generation at a volume of well over 1 MW/year. In a separate pilot line for second generation products we have further improved the performance of CIGSSE based solar modules. We developed a novel CIGSSE formation technique called stacked elemental layer rapid thermal processing (SEL-RTP). This process has recently been scaled up from initial laboratory sized mini-modules (10 × 10 cm²) to full sized power modules of 60 × 90 cm². The present paper concentrates on in situ and ex situ characterization techniques that were developed to control and further improve large area CIGSSE processing. The crystalline thin film formation process has been analyzed with in situ thin film calorimetry and in situ X-ray diffraction (XRD). That work has added fundamental insights and accelerates the optimization process. The depth distribution of gallium and sulfur has been determined by secondary ion mass spectroscopy (SIMS) for different selenization and sulfurization processes. Appropriate profiles of these elements allow for a deliberate bandgap profiling within the Cu(In,Ga)(S,Se)₂ absorber. In addition further quality control tools like X-ray fluorescence analysis and Raman spectroscopy for stoichiometry monitoring, photoluminescence lifetime mapping and thermographic imaging have been developed in order to improve large area uniformity and reproducibility.

Some first full sized modules from the new pilot line look very promising: Aperture area efficiencies of up to 13.1% for monolithic thin film circuits on 0.54 m² and a module power of 65 W represent an international champion value for large are thin film solar modules.     

Assignment of raw material and authentication of spirits by gas chromatography, hydrogen- and carbon-isotope ratio measurements I. Analytical methods and results of a study of commercial products

Gas chromatography and the determination of natural isotope ratios are powerful analytical methods which can be used to check the authenticity of alcoholic beverages and to detect any adulteration. To check the origin and the authenticity of commercial fruit spirits, whiskies, etc., 197 samples were analysed by gas chromatography, ²H-NMR and ¹³C isotope mass spectrometry. The discrimination between different varieties was demonstrated by bivariate and multivariate discriminant analysis using different concentrations of volatile compounds such as methanol, butan-1-ol, 2- and 3-methyl-butanol, benzaldehyde and hexanol as well as isotopic data like (D/H)_I, (D/H)_II and ¹³C/¹²C isotopomers of ethanol. The results show that by using multivariate discriminant analysis it is possible to distinguish not only between different groups of spirits, e.g. those made of stone-fruit, malaceous fruit, grain and corn, but also between individual varieties, such as cherry, plum, mirabelle and apple. If the detection of highly rectified ethyl alcohol of agricultural origin and the identification of its raw materials are required, then natural isotope ratios are the only discriminant analytical parameters available.     

Flexible organic P3HT:PCBM bulk-heterojunction modules with more than 1 year outdoor lifetime

Flexible organic solar cells and modules based on P3ht:PCBM bulk-heterojunctions were fabricated and their lifetime was investigated under laboratory and outdoor conditions. In the laboratory cells were exposed to 1 sun illumination at 65 °C in order to accelerate the degradation. The outdoor behavior of modules was investigated at the Konarka rooftop testing setup in Lowell, MA (USA). We show that these flexible polymer solar cells have a good light stability, passing 1000 h under accelerated light soaking conditions in the laboratory, and that flexible modules survived over 1 year of outdoor exposure without performance losses.     

Germany's solar cell promotion: Dark clouds on the horizon

This article demonstrates that the large feed-in tariffs currently guaranteed for solar electricity in Germany constitute a subsidization regime that threatens to reach a level comparable to that of German hard coal production, a notoriously outstanding example of misguided political intervention. Yet, as a consequence of the coexistence of the German Renewable Energy Sources Act (EEG) and the EU Emissions Trading Scheme (ETS), the increased use of renewable energy technologies does not imply any additional emission reductions beyond those already achieved by ETS alone. Similarly disappointing is the net employment balance, which is likely to be negative if one takes into account the opportunity cost of this form of solar photovoltaic (PV) support. Along the lines of the international energy agency [IEA, 2007. Energy policies of IEA countries: Germany, 2007 review. International Energy Agency, OECD, Paris, p. 77], we recommend the immediate and drastic reduction of the magnitude of the feed-in tariffs granted for solar-based electricity. Ultimately, producing electricity on this basis is among the most expensive greenhouse gas abatement options.