Effect of acid gases on the solubility of n-propylmercaptan in 50 wt% methyl-diethanolamine aqueous solution

In this communication, we have measured the solubility and partition coefficient of n-propylmercaptan in 50 wt% MDEA aqueous solution at 366 K in the presence of single and mixed acid gases (CO₂ and H₂S). A static analytic method was used for performing all the measurements. Methane was used to maintain the total pressure of the system in equilibrium cell. The concentration of n-propylmercaptan in aqueous phase was in the 50–1000 ppm (mole) range. The effect of acid gas loadings on the physical and chemical solubility of n-propylmercaptan is discussed.     

立达:新型工业用纱捻线机

描述了立达公司生产的新型通用捻线机UT 50的特性,它可以提高适应性和降低加捻成本.每个锭位都是独立驱动的,可以生产不同的纱线.基于最新驱动技术的设计理念,由于免去了机头箱,可以节省占地面积、降低生产和投资成本.通用捻线机UT 50迎合市场需要,追求环锭捻线机的适应性和倍捻机的性能.     

An initial comparison of a fuzzy neural classifier and a decision tree based classifier

At the present time a large number of AI methods have been developed in the field of pattern classification. In this paper, we will compare the performance of a well-known algorithm in machine learning (C4.5) with a recently proposed algorithm in the fuzzy set community (NEFCLASS). We will compare the algorithms both on the accuracy attained and on the size of the induced rule base. Additionally, we will investigate how the selected algorithms perform after they have been pre-processed by discretization and feature selection.     

Ratioquadrics: an alternative model for superquadrics

This paper presents a new family of 2D curves and its extension to 3D surfaces, respectively, calledrationconics andratioquadrics that have been designed as alternatives to the well-known superconics and superquadrics. This new model is intended as an improvement to the original one on three main points: first, it involves lower computation cost and provides better numerical robustness; second, it offers higher order continuities (C ¹/G ² orC ²/G ² instead ofC ⁰/G ⁰); and third, it provides a greater variety of shapes for the resulting curves and surfaces. All these improvements are obtained by replacing the signed power function involved in the formulation of superconics and superquadrics by linear or quadratic rational polynomials.     

Analysis of shipboard aerosol optical thickness measurements from multiple sunphotometers aboard the R/V Ronald H. Brown during the Aerosol Characterization Experiment--Asia

Marine sunphotometer measurements collected aboard the R/V Ronald H. Brown during the Aerosol Characterization Experiment-Asia (ACE-Asia) are used to evaluate the ability of complementary instrumentation to obtain the best possible estimates of aerosol optical thickness and Angstrom exponent from ships at sea. A wide range of aerosol conditions, including clean maritime conditions and highly polluted coastal environments, were encountered during the ACE-Asia cruise. The results of this study suggest that shipboard hand-held sunphotometers and fast-rotating shadow-band radiometers (FRSRs) yield similar measurements and uncertainties if proper measurement protocols are used and if the instruments are properly calibrated. The automated FRSR has significantly better temporal resolution (2 min) than the hand-held sunphotometers when standard measurement protocols are used, so it more faithfully represents the variability of the local aerosol structure in polluted regions. Conversely, results suggest that the hand-held sunphotometers may perform better in clean, maritime air masses for unknown reasons. Results also show that the statistical distribution of the Angstrom exponent measurements is different when the distributions from hand-held sunphotometers are compared with those from the FRSR and that the differences may arise from a combination of factors.     

Cytostatic activity of 1,10-phenanthroline derivatives generated by the clip-phen strategy

The cytostatic activities of a series of twelve 1,10-phenanthroline (Phen) derivatives and of their copper complexes were studied on L1210 murine leukemia cells. Large increases in the biological activity were observed for compounds of the 3-Clip-Phen series, in which two Phen moieties were bridged at their C3 positions by an alkoxy linker, the 3-pentyl-Clip-Phen derivative showing an IC(50) value of 130 nM while Phen shows an IC(50) value of 2500 nM under the same conditions. IC(50) values seemed to be modulated not only by the position, the nature, and the length of the linker of Clip-Phen but also by hydrophobicity. Since copper complexes of Phen are chemical nucleases and nucleic acids are thus a potential target for these compounds, the corresponding copper complexes were also studied. Copper complexation of the 3-Clip-Phen ligands did not increase their biological activities. Attempts to vectorize 3-Clip-Phen derivatives with a DNA binder such as spermine or with a cell-penetration peptide failed to increase their biological activity relative to the original 3-Clip-Phen series.     

Atmospheric particle evolution during a nighttime atmospheric mercury depletion event in sub-Arctic at Kuujjuarapik/Whapmagoostui, Québec, Canada

During a field experiment at Kuujjuarapik/Whapmagoostui (55.31 degrees N, 77.75 degrees W), Quebec, we observed increases of concentrations of particles with diameters larger than 0.3 microm in the ambient air during a nighttime atmospheric mercury depletion event (AMDE). These increases were strongly correlated with decreases of ozone and atmospheric mercury, and we also observed a change in the particle size distribution during this AMDE. Assuming that these phenomena imply either a chemical link or an association through transport, we also studied the nature of this AMDE. We hypothesize that the observed AMDE was a result of an influx of already depleted air masses and that it was not a product of local chemical reactions.     

Properties of amorphous carbon films produced by magnetron sputtering

Amorphous carbon films were prepared by magnetron sputtering of a graphite target. Their electrical and optical properties obey the relationship governing the conduction mechanisms in amorphous semiconductors. Their microscopic and structural properties are characteristic of physically vapour-deposited films. A scattering of single crystals of carbon in an amorphous carbon matrix was obtained by triode sputtering of a graphite target.