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排序方式: 共有196条查询结果,搜索用时 11 毫秒
51.
Reaction and nucleation mechanisms of copper electrodeposition from ammoniacal solutions on vitreous carbon 总被引:2,自引:0,他引:2
Darko Grujicic 《Electrochimica acta》2005,50(22):4426-4443
The reaction and nucleation mechanisms of the electrodeposition of copper from ammoniacal solutions were investigated by cyclic voltammetric (cv) and chronoamperometric (ca) techniques, respectively. Each experiment with both electrochemical techniques was followed by morphological studies by atomic force microscopy (AFM). With respect to pH, the studies were performed on ammoniacal solutions at pH 4, pH 6, and pH 8, each representing a characteristic predominance region in E-pH diagrams. The experimental parameters were copper concentration, scanning rate, deposition potential, and electrode conditioning. It was found that at pH 4 copper electrodeposition occurs via reduction of cupric species to cuprous, which in turn can be either reduced, or disproportionated to metallic copper. At pH 6, deposition occurs from free and complexed cupric species, while at pH 8, only cupric amine complexes are involved. Copper nucleates according to instantaneous mechanisms at pH 4, and progressive nucleation mechanisms at pH 6 and pH 8. The diffusion coefficients of the copper species involved were also determined and are reported in this study. 相似文献
52.
Darko Lovrec Mitja Kastrevc Samo Ulaga 《The International Journal of Advanced Manufacturing Technology》2009,41(11-12):1066-1075
High-power transmission capacity at low-energy losses, low noise emissions, high reliability, and ease of maintenance, as well as convenient cost-effectiveness, are required for industrial applications regarding variable electro-hydraulic supply systems. Only up-to-date principles regarding volumetrically controlled hydraulic energy using variable supply systems and appropriate control strategy have proven satisfactory for these requirements. The aim of the present work was to study the applicability of a low-priced drive concept using a speed-controlled induction motor in combination with a constant-displacement pump applied in a load-sensing control strategy. The suggested approach of the drive concept has been experimentally verified on a prototype of the drive. A hydraulic press-brake used for the machining of casting products in the automotive industry was taken into consideration. 相似文献
53.
A new, simple, low-temperature method for the synthesis of superparamagnetic, photocatalytic, nanocomposite particles for applications in the decomposition of pollutants in water is presented. The method is based on the coating of clusters of superparamagnetic maghemite (γ-Fe2O3) nanoparticles with a photocatalytic anatase layer using the hydrolysis of aqueous TiOSO4. The clusters of an appropriate size between 100 and 200 nm form by the simultaneous agglomeration of the aminopropyl-triethoxy-silane-grafted maghemite nanoparticles with a size of approximately 15 nm in a suspension of diluted TiOSO4. During a sudden increase of pH with the addition of NaOH the titania is heterogeneously nucleated at the cluster surfaces. If the hydrolysis was conducted at an elevated temperature of 90 °C, the titania layer was nanocrystalline anatase. The composition of the nanocomposite particles, i.e., the thickness of the anatase layer, can be controlled simply by changing the starting TiOSO4/Fe2O3 ratio for low titania contents, and by multiple coatings to get high titania contents. The photocatalytic activity of the nanocomposites was evaluated in the photocatalytic decomposition of formic acid. The activity seems to increase with an increase in the thickness and the crystallinity of the anatase coating, whereas it decreased after the calcination of the as-synthesized nanocomposite. The coating of the maghemite nanoparticles with a thin layer of insulating silica also slightly improves the photocatalytic activity. 相似文献
54.
David Vuilleumier Darko Kozarac Marco Mehl Samveg Saxena William J. Pitz Robert W. Dibble Jyh-Yuan Chen S. Mani Sarathy 《Combustion and Flame》2014
This study examines intermediate temperature heat release (ITHR) in homogeneous charge compression ignition (HCCI) engines using blends of ethanol and n-heptane. Experiments were performed over the range of 0–50% n-heptane liquid volume fractions, at equivalence ratios 0.4 and 0.5, and intake pressures from 1.4 bar to 2.2 bar. ITHR was induced in the mixtures containing predominantly ethanol through the addition of small amounts of n-heptane. After a critical threshold, additional n-heptane content yielded low temperature heat release (LTHR). A method for quantifying the amount of heat released during ITHR was developed by examining the second derivative of heat release, and this method was then used to identify trends in the engine data. The combustion process inside the engine was modeled using a single-zone HCCI model, and good qualitative agreement of pre-ignition pressure rise and heat release rate was found between experimental and modeling results using a detailed n-heptane/ethanol chemical kinetic model. The simulation results were used to identify the dominant reaction pathways contributing to ITHR, as well as to verify the chemical basis behind the quantification of the amount of ITHR in the experimental analysis. The dominant reaction pathways contributing to ITHR were found to be H-atom abstraction from n-heptane by OH and the addition of fuel radicals to O2. 相似文献
55.
Importance-performance analysis (IPA) is a decision-support tool used in prioritizing quality improvements of products/services. Recently, back-propagation neural network (BPNN)-based approaches have been proposed to deal with the problem of asymmetric effects in customer satisfaction formation. Though reliability of IPA is increased by the integration of BPNN, shortcomings of the analytical framework remain that (a) it does not provide insight into forms and degrees of these asymmetric effects, (b) it does not account for differences between the relevance and determinance of quality attributes, and (c) it neglects the competitor dimension in attribute-prioritization. Since all these issues have important managerial implications, the authors of this study propose an extended BPNN-based IPA that uses a multidimensional operationalization of attribute-importance, and that considers competitive performance levels. Using data from an airline satisfaction survey, an empirical test reveals that the proposed approach significantly outperforms conventional BPNN-based IPA. In particular, conventional BPNN-IPA would mislead managerial action with regard to 3 out of 8 quality components (37.5%). 相似文献
56.
A Unified Sensor Architecture for Isothermal Detection of Double‐Stranded DNA,Oligonucleotides, and Small Molecules 下载免费PDF全文
57.
58.
Miha Drofenik Irena Ban Darko Makovec Andrej Žnidaršič Zvonko Jagličić Darko Hanžel Darja Lisjak 《Materials Chemistry and Physics》2011
Superparamagnetic Ba-hexaferrite nanoparticles were prepared using modified hydrothermal synthesis. The precursor and hydroxide [OH−] concentrations were optimized and the synthesis temperature and time were drastically reduced. The size and the morphology of synthesized nanoparticles was confirmed by transmission electron microscopy (TEM) images. The crystal structure of the nanoparticles was characterized by X-ray diffraction data. Powders synthesized at 160 °C exhibit a bimodal particle size distribution while those synthesized at TS = 150 °C show a monomodal particle size distribution. Zero-field-cooling (ZFC) and field-cooling (FC) magnetization measurements were performed using a superconducting quantum interference device magnetometer from 2 to 300 K to investigate the magnetic properties of nanoparticles. The FC/ZFC magnetization measurements showed a typical superparamagnetic behavior. The synthesized superparamagnetic particles exhibit a disc-like shape, in average 11 nm wide and 3 nm thick with a room temperature magnetization of approximately 10 Am2/kg at 5 T. 相似文献
59.
Candy Ann Dwamena Darkwa Anthony Andrews Stephen Akosah Darko George Asare 《International Journal of Applied Ceramic Technology》2023,20(3):1730-1739
A large quantity of water treatment sludge (WTS) is generated yearly from Ghana's Weija water treatment plant. The sludge contains some heavy metals and other toxic chemicals, which must be managed to minimize environmental impact. In the current work, WTS was mixed with varying quantities of kaolinitic-based clays (kaolin and lithomargic clays) to produce porous mullite-based bricks. The bricks were fired at 1200°C for 1 h, and their properties were determined. Lithomargic clay-based mixtures had less dimensional variation and were suitable to produce near-net shape bricks compared to WTS-based bricks. The addition of WTS increased the linear firing shrinkage and apparent porosity whilst decreasing bulk density and compressive strength. Porous mullite-based bricks fabricated from lithomargic clay exhibited high compressive strength (6.3 MPa) at 10 wt.% WTS addition. The highest apparent porosity of 27% was attained at 40 wt.% WTS addition with compressive strength of 5.1 MPa and thermal conductivity of .5 W/m K. 相似文献
60.
Improvement of ammonia removal in activated sludge process with feedforward-feedback aeration controllers. 总被引:1,自引:0,他引:1
Darko Vrecko Nadja Hvala Aljaz Stare Olga Burica Marjeta Strazar Meta Levstek Peter Cerar Sebastjan Podbevsek 《Water science and technology》2006,53(4-5):125-132
In the paper three linear aeration controllers that can be easily implemented are presented and evaluated on the activated sludge process pilot plant. Controllers differ according to the information that is used about the process, which can be oxygen in the last aerobic reactor, ammonia in the last aerobic reactor and ammonia in the influent. The aeration controllers that are addressed are: oxygen cascade PI controller, ammonia cascade PI controller and ammonia feedforward-cascade PI controller. Experiments show that, in comparison with the oxygen cascade PI controller, the ammonia cascade PI controller allows better control of effluent ammonia and airflow savings of around 23%, while the ammonia feedforward-cascade PI controller gives the best reduction of ammonia peaks and can save up to 45% of the airflow. 相似文献