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1.
2.
以Si-MCM-41、Al-MCM-41(1) (n(Si)/n(Al)=15)、Al-MCM-41(2) (n(Si)/n(Al)=10)以及用NH4NO3或HAc的醇溶液分别与Si-MCM-41离子交换所得的H-MCM-41(N)和H-MCM-41(H)为载体制备了系列Ru/MCM-41催化剂。采用N2吸附、XRD和H2-TPR表征了负载Ru前后催化剂的结构及Ru在各种载体表面上的分散状态。以0.5%(质量分数)苯的环己烷溶液为模型化合物,在298K、3.0MPa反应条件下,考察了上述催化剂的苯液相加氢反应性能,并与Ru/HY、Ru/H61538;和Pt/MCM-41催化剂进行了比较。结果表明,载体MCM-41的n(Si)/n(Al)和表面化学组成等性质对Ru在其表面上的分散状态、还原性及催化性能均有影响。对苯的转化率与反应时间的关系曲线进行拟合,发现其遵循一级动力学方程,加氢反应速率常数按照Ru/Al-MCM-41(2)相似文献
3.
Up until today extreme rainfall properties are frequently applied in sewer design guidelines. Uncertainty in the estimation of such properties will hence directly influence the dimensions of sewers, structures and pumps. In this paper the issue of potential trend and noise in the estimation is investigated for 6 rain series ranging from 19 to 55 years in duration. Different to recent research that predicts a climate induced-increase in heavy precipitation no clear indication for such trend was found in the investigated historical rain series. Another important aspect is the length of the rain series that is required for the estimation of extreme rainfall properties and the associated uncertainty. The analysis indicates that at least a period of 10 years should be used for the estimation. But even so the possible deviation expressed in terms of the 90 percentile is in the order of 5 to 10% of the 'true value', defined as the value derived when the whole given series is used for the estimation. 相似文献
4.
On the effect of spatial variances in historical rainfall time series to CSO performance evaluation.
Historical, high-resolution rain series are the backbone of modern combined sewer overflow (CSO) structure design. These rain series are the input to the computational estimation of the performance of the measures with respect to CSO pollution abatement. However, those historical precipitation measurements are available at only a few locations. Frequently rain series have to be used from gauging stations at a significant distance. In order to judge and to compensate for this influence an estimate between rain characteristics and combined sewer outflow (CSO) performance indicators would be useful. In this paper such correlations have been sought for a collection of 37 rain series covering large areas of Europe. It was found that the mean annual rain volume can explain most of the variances for the performance indicators Number of overflows and CSO volume. For explaining the spatial differences in the efficiency of the CSO structure another rain characteristic, i.e. the maximum event with a return period of one year, is to be used. 相似文献
5.
G Garrote J
M Cruz H Domínguez J
C Paraj 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(4):392-398
Non‐isothermal processing of lignocellulosic materials in aqueous media (autohydrolysis reaction) under mild conditions leads to solutions containing valuable chemicals (oligosaccharides, sugars and acetic acid) and other, undesired, compounds (belonging to the extractive and acid‐soluble lignin fractions) which have to be removed in further purification treatments. Liquors obtained by non‐isothermal autohydrolysis of Eucalyptus globulus wood and corncobs under a variety of operational conditions were extracted with ethyl acetate in order to remove non‐saccharide components, and the suitability of the fraction dissolved in the organic phase was assayed for possible utilisation as an antioxidant. The yield and antioxidant activity of ethyl acetate extracts (measured by the α,α‐diphenyl‐β‐picrylhydrazyl (DPPH) radical scavenging capacity) showed a strong dependence on the autohydrolysis conditions. The antioxidant activity of extracts obtained under selected operational conditions compared well with synthetic antioxidants. © 2003 Society of Chemical Industry 相似文献
6.
Kilchytska V. Neve A. Vancaillie L. Levacq D. Adriaensen S. van Meer H. De Meyer K. Raynaud C. Dehan M. Raskin J.-P. Flandre D. 《Electron Devices, IEEE Transactions on》2003,50(3):577-588
This work presents a systematic comparative study of the influence of various process options on the analog and RF properties of fully depleted (FD) silicon-on-insulator (SOI), partially depleted (PD) SOI, and bulk MOSFET's with gate lengths down to 0.08 /spl mu/m. We introduce the transconductance-over-drain current ratio and Early voltage as key figures of merits for the analog MOS performance and the gain and the transition and maximum frequencies for RF performances and link them to device engineering. Specifically, we investigate the effects of HALO implantation in FD, PD, and bulk devices, of film thickness in FD, of substrate doping in SOI, and of nonstandard channel engineering (i.e., asymmetric Graded-channel MOSFETs and gate-body contacted DTMOS). 相似文献
7.
The Two-Dimensional Clifford-Fourier Transform 总被引:1,自引:0,他引:1
Fred Brackx Nele De Schepper Frank Sommen 《Journal of Mathematical Imaging and Vision》2006,26(1-2):5-18
Recently several generalizations to higher dimension of the Fourier transform using Clifford algebra have been introduced,
including the Clifford-Fourier transform by the authors, defined as an operator exponential with a Clifford algebra-valued
kernel.
In this paper an overview is given of all these generalizations and an in depth study of the two-dimensional Clifford-Fourier
transform of the authors is presented. In this special two-dimensional case a closed form for the integral kernel may be obtained,
leading to further properties, both in the L
1 and in the L
2 context. Furthermore, based on this Clifford-Fourier transform Clifford-Gabor filters are introduced.
AMS subject classification numbers: 42B10, 30G35
Fred Brackx received a diploma degree in mathematics from Ghent University, Belgium, in 1970 and a Ph.D. degree in mathematics from the
same university in 1973. Since 1984 he is professor for mathematical analysis at Ghent University and currently he is leading
the Clifford Research Group. His main interests are function theory and functional analysis for functions with values in quaternion
and Clifford algebras. The research covers Clifford distributions, generalized Fourier, Radon and Hilbert transforms, orthogonal
polynomials and multi-dimensional wavelets.
Nele De Schepper received a diploma degree in mathematics from Ghent University, Belgium, in 2001. Since then she holds an assistantship at
the Department of Mathematical Analysis of Ghent University and is a member of the Clifford Research Group. Her main interests
are function theory and functional analysis for functions with values in Clifford algebras. The research covers generalized
Fourier transforms, orthogonal polynomials and multi-dimensional wavelets.
Frank Sommen received a diploma degree in mathematics from Ghent University, Belgium, in 1978, a Ph.D. degree in mathematics from the
same university in 1980, and a habilitation degree in mathematical analysis in 1984. From 1978 until 1999 he was at the National
Fund for Scientific Research (Flanders). Since 2000 he holds a Research professorship at Ghent University. His main interests
are function theory and functional analysis for functions with values in quaternion and Clifford algebras. The research covers
Clifford distributions, generalized Fourier, Radon and Hilbert transforms, orthogonal polynomials and multi-dimensional wavelets,
algebraic analysis, hyperfunctions and radial algebra. 相似文献
8.
9.
通过对地杂波O.94μm激光后向反射率的测试,获取不同入射角的多背景后向反射率测试数据。通过对测试数据的分析处理提供特征信息,为激光探浏器设计提供依据。 相似文献
10.
利用硫酸软骨素(chondroitin sulfate,CS)在云母基底上通过浇铸法制备的自组装膜为基底,诱导草酸钙在其上的凝集生长。发现当硫酸软骨素的浓度为1.Omg/ml时在该膜体系中可形成规整的周期性草酸钙环状沉淀。这种有序的环状结构可能是耗散结构的一种具体表现形式。利用原子力显微镜(atomic forcemicroscope,AFM)和傅立叶红外光谱仪对这种结构进行了表征,实验结果显示合适浓度下形成的CS膜在一定程度上可以抑制草酸钙的凝集结晶,表明高分子基质与无机离子间强烈的相互作用对无机盐的成核结晶有显著影响,为探讨结石的形成与抑制提供了一定的实验依据。 相似文献