Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

SA299钢冷脆行为的研究

某锅炉厂生产的锅炉汽包,在冬季制造过程中发生破裂,汽包材料为 SA299钢,对断口的初步分析发现为脆性解理断口,据此认为是冷脆破坏。本文依据冷脆特征温度 Tc 的概念对 SA299钢的冷脆行为进行了细致的分析。     

依纳Ⅴ型牵伸机构的优化设计

对细纱机依纳Ⅴ型牵伸机构进行了优化设计，通过在后牵伸区增加一附加压力棒，对牵伸效果有了较大幅度的提高，并对其产生的毛羽增多的弊病采取了有效措施。     

Effect of the absence of lipoxygenase isoenzymes on the storage characteristics of rice grains

Three varieties of paddy rice with and three varieties without lipoxygenase (LOX) isoenzymes were stored at room temperature, in dark conditions for 42 months. Insect damage and viability were investigated during that time. Varieties without LOX-1,2 and their offspring were screened with a rapid method of estimating LOX isoenzymes, and subjected to an accelerated-ageing experiment. The results indicated that in varieties without LOX-1,2, after long storage, rice quality was normal, but for varieties with LOX-1,2, rice quality deteriorated. With increase of storage time, the germination rate of the seed of most varieties decreased greatly except for varieties without LOX-1,2 where there was almost no change in the germination rate. In varieties without LOX-1,2 and their offspring, after an accelerated ageing experiment the germination rate of some varieties changed slowly, but with others, the germination rate changed quickly. This indicated that a definitive factor, which influenced the life of seeds, may be the loss of LOX-1,2. During storage, there was also a significant difference in the degree of insect damage. In varieties without LOX-3 insect damage was lower, but in varieties with LOX-3 insect damage was higher. Therefore, the absence of LOX-3 may be very important in insect resistance in rice grain.     

日毛绒狗信息重组价值增

一只毛绒狗的故事 “大红狗”是正流行在日本京都白领女性圈子里的一款玩具。它选用毛巾布料，因此手感良好，据宣传称它的红色能够刺激脑细胞，使人充满活力，所以兼具一定的医疗保健作用。很多白领女性都喜欢将它摆放在办公室的写字台上，而现在东京都三鹰市内各大商店正以2100日元（含税）的价格热销中。     

扬州芍药

研究扬州芍药的栽培简史,明确扬州芍药的历史地位,通过对扬州芍药现状的了解,提出积极措施,努力恢复扬州芍药的园艺地位.     

徽派园林的保护、继承与创新

文章从对中国江南古典园林中重要的一支——徽派园林的现状分析出发,提出了对徽派园林保护和利用的方向和策略,阐述了对徽派园林加以继承和创新的意义和方法。     

Synthesis and aqueous solution behaviors of sodium sulfonate‐terminated dendritic poly(ester‐amine)

Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO₃) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, ¹H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

连轧管机轧辊轴承的调整、维护及保养

本文介绍了应用于MPM连轧机轧辊上的四列圆锥滚子轴承的结构特性及其调整、维护、保养，旨在提高轴承的使用寿命。     

高速列车风量控制式通风系统的探讨

介绍了能够减轻乘坐高速列车时产生的耳朵不适感的风量控制式通风系统，该系统通过检测车内外的压力来控制进排气量，并且由模拟计算证实，该系统能够控制车内压力的波动，满足高速列车的舒适性需要。