The strut arch in using of steel road bridges mainly in Germany – trends of developments into the last 50 years. By the presentation is given a survey about the development of the designing the arch construction for steel road bridges inclusive the constructive details. In the detail are considerd the suspensions with their connections, the cross‐sections of the arch, springing arch, arch model and the roadway‐constructions into different phases. At last of the investigation are presented some typical erection‐examples. 相似文献
There have been numerous attempts to correlate results obtained by gas chromatography-mass spectrometry (GC-MS) to alternative techniques such as immunoassays and bioassays for the analysis of dioxins in environmental samples. In spite of these efforts, uncertainties about the performance of these methods remain. Following a series of performance studies of various dioxin assays, an in-depth evaluation of sample extracts from the Procept Rapid Dioxin Assay was conducted to provide users with a clearer understanding of the differences in the assay's results compared to traditional mass spectrometry. Two powerful analytical techniques [high-resolution mass spectrometry (HRMS) and two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS)] were used to provide a unique perspective about the assay's underlying analytical performance. HRMS analyses demonstrated that the target dioxin and furans were consistently captured in the assay's extracts. TOFMS analyses revealed that interferents in the sample extracts resulting from inconsistencies in the sample preparation process appear to be the primary factor contributing to the assay's imprecision. The conclusion of this research was the assay results cannot be expected to correlate directly with HRMS and should only be utilized as a screening technique (e.g., to identify the relative ranking of contamination, to determine if samples are above/below threshold levels, or to monitor a cleanup) for environmental matrices such as soil and sediment. 相似文献
In the paper various issues in personal satellite communications are addressed. Basic geostationary and non‐geostationary
satellite constellations are considered. The narrowband and wideband characterization of the mobile satellite channel and
related system implications are discussed. Satellite diversity is presented as a measure to overcome signal shadowing. The
capacity of TDMA and CDMA multiple access is estimated, taking into account co‐channel interference. Various network issues,
such as mobility management, radio resource management, call control, routing, and network integration are addressed. Finally,
some regulatory and political issues are mentioned which may be most relevant for market development and financial success
of satellite personal communication systems.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
We investigated the growth of intermetallic compounds in Cu/Ni/Au/PbSn solder joints. The substrates that we investigated had been Au plated by one of two different techniques. The Au finish thicknesses ranged from 0.25 to 2.6 μm. After solder renew, structural examinations using optical and electron microscopy of cross-sectioned solder joints revealed the growth of Ni3Sn 4 at the solder/Ni interface after reflow. Solder joints with thicker layers of Au annealed in Ar gas at a temperature of 150°C for up to 450 h, displayed an appreciable growth of Au0.5Ni 0.5Sn4 at the Ni3Sn4/solder interface. Previous investigators correlated growth of a Au-Sn alloy with the degradation of the mechanical properties of the solder joint. The determination of the stoichiometry of the Au0.5Ni0.5 Sn4 phase provides some understanding of why this phase grew at the Ni3Sn4/solder interface, as Sn, Au and Ni are all readily available at this interface. The growth of this ternary alloy is also consistent with trends observed in the kinetics of formation of solder alloys 相似文献
Heterodyne instruments at millimeter and submillimeter wavelengths often use wideband fixed-tuned frequency multipliers, in conjunction with broadband power amplifiers driven by frequency synthesizers, as the local oscillator (LO) source. At these frequencies the multipliers use Gallium Arsenide (GaAs) based Schottky varactor diodes as the nonlinear element, and like most other harmonic generators are susceptible to spurious signal interference. The state-of-the-art LO sources at these wavelengths use high power MMIC amplifiers at the initial stages, and are used to drive the subsequent multiplier stages to have enough LO power to pump the mixers. Because of the high input power environment and the presence of noise in the system, the multipliers become vulnerable to spurious signal interference. As the spurious signals propagate through the receiver system, they generate inter-modulation products which might fall in the passband of the heterodyne instrument and seriously degrade its performance. In this paper spurious signal response of solid-state frequency multipliers at millimeter and submillimeter wavelengths is investigated. Results of numerical harmonic balance simulations and laboratory experiments, which were found to show good agreement, are presented here. 相似文献
In cold region environments, ice‐jam floods (IJFs) pose a severe risk to local communities, economies, and ecosystems. Previous studies have shown that both climate and regulation affect IJF probabilities, but their relative impacts are poorly understood. This study presents a probabilistic modelling framework that couples hydrologic and hydraulic models to assess the relative role of regulated and naturalized flows on ice‐affected backwater staging. The framework is evaluated at an IJF‐prone town on the Peace River in western Canada, which has been regulated since 1972. Naturalized flows were generated for the comparison, and ice‐affected backwater profiles were calculated along jams of varying length and location and for different combinations of model parameters and boundary conditions. Results show significant differences in backwater staging (~2 m for a return period of T = 1:10 year) between two study time periods (1973–1992 vs 1993–2012) as compared with two different hydraulic flow conditions (regulated vs naturalized), suggesting a larger role of climate than regulation in backwater staging. However, regulation was found to offset flood risk during the 1973–1992 period and exacerbate flood risk during the 1993–2012 period. 相似文献
An efficient and convenient method for the synthesis of dibenzo[c,h]acridine derivatives via electrophilic cycloisomerisation mediated by methanesulfonic acid has been developed. This method provides the desired acridines in moderate to very good yields introducing various substituents in positions 2 and 6 as well as on the dibenzo[c,h]acridine scaffold. Photophysical and electrochemical properties have been investigated for selected products by UV/Vis and CV measurements which have been verified by DFT calculations.
Cellulose-based packaging materials are currently the most commonly used food packaging materials due to their light weight, stability and affordable price. However, the use of recycled paper and board adds to the risk that undesirable substances migrate into the packed goods, since contaminants are not completely removed during the recycling process and can accumulate in the final product. The only available fast and practical solution that can be used to reduce the migration of these substances is the application of functional barriers in the packaging. The applied barriers are currently mostly synthetic, which either serve only a moderate barrier function and/or have the disadvantage that it is often more complex and expensive to recycle the resulting packaging material. The aim of this project is to evaluate different bio-based or biodegradable polymers with regards to their barrier properties. Due to the fact that the transport phenomena are mainly driven by (gas phase) migration, methods based on gas chromatography (GC), including GC coupled with mass spectrometry (GC-MS) and flame ionization detection (GC-FID), GC-FID coupled online with high pressure liquid chromatography (HPLC-GC-FID), and comprehensive GCxGC-MS were used to qualify and quantify the migrated substances. This use of a wide range of different methods and instruments yielded excellent results, allowing us to comprehensively characterize the biopolymers and their barrier function. 相似文献