重芳烃轻质化催化剂n（Ni）/n（Ni+Mo）的优化与分析

以β分子筛为载体,在保持金属总负载量不变的情况下,采用等体积浸渍法制备了4种不同n（Ni）/n（Ni+Mo）的催化剂。分别采用X射线衍射（XRD）、比表面积测试（BET）、氨程序升温脱附（NH₃-TPD）、氢程序升温还原（H₂-TPR）、氢程序升温脱附（H₂-TPD）和热重-差热分析（TG-DTG）等方法对催化剂进行了表征。结果表明,4种催化剂的酸量和酸强度相近,在n（Ni）/n（Ni+Mo）等于基准+0.2时,Mo与载体之间的相互作用最弱,其氢气吸附量最多且积炭量最少;采用某炼厂重整C₁₀⁺ 重芳烃对4种催化剂进行评价,结果表明n（Ni）/n（Ni+Mo）等于基准+0.2催化剂具有最优的催化活性和稳定性。上述结果表明,影响重芳烃轻质化催化剂活性和稳定性的关键因素是催化剂氢气吸附量的多少,氢气吸附量越多金属表面的溢流氢效应越明显,积炭前驱体被溢流氢及时消除,从而保护了催化剂的加氢活性中心不被积炭覆盖,有助于催化剂在较高活性下保持稳定。     

Synthesis and characterization of poly acrylic acid/graphite oxide nanocomposite

1　INTRODUCTIONOrganic intercalatedlayeredsolidshavebeenstudiedbyscientistsindifferentfieldsformanyyearsbecauseoftheirnew physicalandchemicalpropertiessuchaselectricalproperties[1] ,mechanicalproper ties ,thermalbehavior[2 ] ,surfaceandinterfacialproperties[3] .Graphiteoxide (GO)hasbeenstudiedformany years ,itsstructuralmodel[4 6 ] ,formationprocessandkinetics[7,8] havebeenstudiedindetail.IthasbeenreportedthatGOpossessesC OHande poxidefunctionalgroups[9] whichmakegraphiteox ideeasilyabs…     

扫描电镜在质量事故分析中的应用

应用扫描电镜断口分析、能谱定性分析、光学显微形貌测试等方法 ,针对公司重要产品因细小裂纹而连续四炉产品全部报废的重大质量事故 ,分析了引起报废裂纹缺陷的性质及产生原因。结果表明 :缺陷主要是大量集聚分布的脆性Al2 O3 夹杂及其裂纹 ,属原材料缺陷 ,是冶炼时氧化还原工艺控制不当 ,或加Al量不均匀所致。据此立即采用了相应调整和改进冶炼工艺措施 ,有效消除了原始缺陷 ,迅速提高了产品质量和效益。     

Flow stress and softening behavior of wrought magnesium alloy AZ31B at elevated temperature

1　INTRODUCTIONThewroughtmagnesiumalloyshaveexcellentspecificstrengthandstiffness ,machinability ,dampcapacity ,dimensionalstability ,lowmeltingcostsandare ,hence ,veryattractiveinsuchapplicationsasau tomobile ,aviation ,electronicandcommunicationin dustry[16 ] .Investigationsontheflowstressandsofteningbehaviorofmagnesiumalloysathigherformingtem peratureandstrainratehavebeenanimportantsub jectinwroughtmagnesiumalloysforming[710 ] .InthispapertheflowstressandsofteningbehaviorofAZ31Bdeform…     

STUDY OF INTERFACES AND SURFACES OF YBa_2Cu_3O_(7-x)-Ag

Interfaces and surfaces of YBa_2Cu_3O_(7-x)(YBCO)-Ag have been studied by SEM-EDXand AES.No effect of Ag on 123 structure in X-ray diffraction pattern was observedfor 0.4 mol Ag doped YBCO.AES analysis indicated that Ag segregated on surfaceof YBCO and resulted in decrease of YBCO-metal lead resistance.In addition,solutionand segregation of Ag as elemental state were often appeared on interfaces and surfacesof high temperature annealed YBCO,whether elemental Ag or compound Ag_2O andAgNO_3 adopted as doping material.     

印刷线路板电镀废水综合治理

简述线路板电镀废水中氰、铜氨、油墨废水治理方法和混合废水综合治理工艺流程及原理。     

飞剪机定尺控制系统的PID调节

介绍了飞剪机的定尺控制系统,给出了定尺控制系统的结构框图,对控制系统的PID调节器运用试凑法进行了参数整定。     

模式飞剪剪切能力分析

通过对热轧精整厚板生产线模式飞剪剪切力在线测试,结合理论计算分析了飞剪的剪切能力,同时采用有限元对刀片和刀架强度、变形进行计算分析,指出现有飞剪存在的问题,为下一步改造提供依据.     

Preparation and mechanical properties of Fe_3Al/Al_2O_3 nano-/micro-composite

1　INTRODUCTIONAlumina(Al2 O3)ceramicsareoftenconsideredforstructuralapplications,duetotheirpropertiesofhighhardness ,chemicalandwearresistanceandgoodmechanicalpropertiesatroomandhightemperature .Thewellknownlimitationfortheseceramics ,how ever ,istheverylowtoughness .Recentstudieshaveshownsignificantimprovementsinmechanicalprop erties ,includingtoughness ,byaddingductilesecondphaseparticles ,suchasNi,Al,MoandCu[14 ] .Anincreaseof 80 % 333%inthefracturetoughnesshasbeenreportedforAl2 O3…     

铁精矿粒度对球团强度的影响

以大红山、曼南坎和滇滩等精矿的粒度以及膨润土用量和润磨时间为因子,以生球落下强度、生球爆裂温度、预热球抗压强度和焙烧球抗压强度为评价指标,进行了五因子二次回归组合实验研究。结果表明:随着铁精矿小于0.074mm粒级含量的增加,生球爆裂温度下降,预热球和焙烧球抗压强度提高;当铁精矿小于0.074mm粒级含量小于75%(质量分数)时,生球落下强度逐渐上升,当小于0.074mm粒级含量为75%时,生球落下强度达到最大值,之后有下降趋势。并不是铁精矿粒度越细球团强度就会越好,铁精矿粒度还应该满足一个合适的粒度组成。