STRUCTURE REPRESENTATION OF THE SPECIFIC FRACTIONS FROM PINGSHUO COAL

Basic data of four fractions, PM₁, PM₆, PM₇and PM₈, derived from Pingshuo bituminous coal were obtained by ultimate analyses, mean molecular weight measure, GC/MS, ¹³C-NM R, ¹H-NM R and FTIR technigues. A method of calculating the average molecular parameters of the fractions is introduced. Based on the calculated parameters, the molecular structure models of the fractions of PM₆, PM;and PM₈are constructed. Significant structural information about the saturated hydrocarbon and aromatic hydrocarbon with heteroatom groups is given also.     

微机模拟处理pH络合滴定法研究——Ⅱ.终点确定方法和最佳实验条件模拟估计程序

本文利用简便的滴定过程模型,确立了微机模拟处理实验数据,方便、准确地求解络合滴定等当点的方法。设计了最佳实验条件模拟估计程序。该法测定Zn~(2+),Pb~(2+),Cu~(2+),Fe~(3+)结果的相对误差Δ<1％。pH=6-7时,测定Ca~(2+)的相对误差为-1.61％;σ<0.001mmol,(N=5)。     

坑道用水下堵漏剂的研制

坑道水下堵漏剂的研制包括F－1、F－2和F－3型。其中F－1是一种有机堵漏剂，它可以在水中固化；F－2是一种无机防水堵漏剂，施工方便；F－3是速凝型，它可在瞬间固化，能对坑道的涌水口进行堵漏。     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

Application of artificial neural networks to the analysis of two‐dimensional fluorescence spectra in recombinant E coli fermentation processes

A two‐dimensional (2D) spectrofluorometer was used to monitor various fermentation processes with recombinant E coli for the production of 5‐aminolevulinic acid (ALA). The whole fluorescence spectral data obtained during a process were analyzed using artificial neural networks, ie self‐organizing map (SOM) and feedforward backpropagation neural network (BPNN). The SOM‐based classification of the whole spectral data has made it possible to qualitatively associate some process parameters with the normalized weights and variances, and to select some useful combinations of excitation and emission wavelengths. Based on the classified fluorescence spectra a supervised BPNN algorithm was used to predict some of the process parameters. It was also shown that the BPNN models could elucidate some sections of the process's performance, eg forecasting the process's performance. Copyright © 2005 Society of Chemical Industry     

Plasma properties of laser-ablated St target in air

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Experimental Study on Energy Consumption of Combined Conventional and Dehumidification Drying

Conventional drying, dehumidification drying, and combined conventional-dehumidification drying of wood were experimentally studied in this article. The results showed that the energy consumption in the dehumidification drying is the least but its drying time is the longest. The energy consumption in the combined drying is more than that in the dehumidification drying but less than that in the conventional drying, and the drying time is half of that in the dehumidification drying. The advantages of the combined conventional and dehumidification drying are discussed from the experiments results.     

Study of the Mössbauer effect on rare-earth borided surface layers on pure iron

Journal of Materials Science Letters -     

用于氢化的铜铬氧化物催化剂的研究

通过铜铬氧化物催化剂用于豆油的选择氢化,研究了制备方法及氢化条件对催化剂活性的影响.在所用的五种催化剂中,以Adkins法制备的催化剂活性最好,碳酸氢铵法次之.文中还对催化剂焙烧气氛、焙烧温度、焙烧时间、铜铬原子比对催化剂活性的影响以及氢化温度、催化剂用量、搅拌速度、氢流速等对反应的影响进行了较详细的讨论.