A 2D Full-Band Monte Carlo Study of HgCdTe-Based Avalanche Photodiodes

This work presents a numerical simulation study of HgCdTe-based avalanche photodetectors (APDs). The two-dimensional model used is based on a full-band Monte Carlo approach in which the electronic structure is computed using a nonlocal empirical pseudopotential model with spin–orbit corrections. The carrier–phonon scattering rates have been computed from first principles using a rigid pseudo-ion model. The most attractive feature of these devices is the potential for single-carrier ionization when electrons are used as the primary injection carrier. For this reason, this work focuses on two front-illuminated (electron-injection) device structures: a planar diffused PIN structure and a planar diffused PN photodiode with guard rings. To predict the performance of these APDs, the electron multiplication gain has been studied as a function of the position where photogenerated carriers are injected and as a function of the curvature of the p-type diffusion region. We find that, in the diffused PIN structure, the limited lateral spatial extent of the high-electric-field region leads to a reduction of the multiplication gain from the center of the device to the periphery. Furthermore, the higher the curvature, the more abruptly the gain decreases. For the simple PN structure, we find that the presence of the guard rings removes the high electric field from the surface and induces a more gradual roll-off of the gain from the center of the device to the periphery.     

Estimation of the mass of powder trapped at collision during ball milling from the kinetics of the mechanically activated decomposition of Ag oxalate

The present work aims at providing a direct experimental estimate of the amount of powder trapped at each collision during the mechanical processing by ball milling. Attention has been focused on the mechanochemical reactivity of anhydrous Ag oxalate powders, prepared by mixing Ag nitrate and Na oxalate aqueous solutions, and then filtering and drying the white precipitate formed. Suitable amounts of such powders were mechanically processed with a single milling ball. The mechanical processing induced the gradual decomposition of Ag oxalate into Ag and carbon dioxide. The process was followed by gravimetric analyses, and its kinetics related to individual collisions. It is shown that the decomposition process follows a simple exponential kinetics, which allows the identification and evaluation of an apparent rate constant. This can be regarded as a measure of the amount of powder trapped at each collision, which is roughly equal to 0.41 mg.     

Predicting mode-II delamination suppression in z-pinned laminates

A finite element model for predicting delamination resistance of z-pin reinforced laminates under the mode-II load condition is presented. End notched flexure specimen is simulated using a cohesive zone model. The main difference of this approach to previously published cohesive zone models is that the individual bridging force exerted by z-pin is governed by a specific traction-separation law derived from a unit-cell model of single pin failure process, which is independent of the fracture toughness of the unreinforced laminate. Therefore, two separate traction-separation laws are employed; one represents unreinforced laminate properties and the other for the enhanced delamination toughness owing to the pin bridging action. This approach can account for the so-called large scale bridging effect and avoid using concentrated pin forces in numerical models, thus removing the mesh-size dependency and permitting more accurate and reliable computational solutions.     

Complexity‐reduced in the hydroclimatological modelling of aquifer's discharge

Climate variability induces considerable interannual fluctuations in spring discharge, especially in mountain areas, where groundwater is recharged mainly by rain and snow melt. This study presents the discharge climatological model (DISCLIM), which was developed to test a complexity‐reduced approach to perform historical reconstruction in the lack of physical assumptions. The Mount Cervialto aquifer (Southern Italy) is the test site, where a powerful karst spring is monitored since the 1920s and is very sensitive to climatic conditions. DISCLIM incorporates seasonal precipitation and climate indicators only. Despite its simplicity, DISCLIM has been able to well estimate the yearly fluctuations of discharge hydrological, explaining about 90% of the interannual variability at the calibration stage, and more than 80% at validation stage. This means that DISCLIM can be easily used for estimating the discharge in historical times, when no all the hydrological balance data are available for the purpose.     

An efficient HARQ scheme for applications in multicast communication systems

This paper deals with the performance evaluation and optimization of an efficient hybrid automatic repeat request (HARQ) scheme suitable for applications delivered over lossy multicast communication channels. In particular, different from previously investigated strategies, this paper proposes a modified HARQ scheme based on the symbol combining principle (MHARQ‐SC) where multiple copies of a same packet are consecutively transmitted at each transmission opportunity. By considering as the performance metrics, the mean packet delivery delay, and the energy consumption per information packet, this paper presents suitable performance evaluation and optimization strategies tailored for multicast communications. For the sake of comparisons, it has been also analyzed, under the same operational conditions, the performance of different HARQ schemes optimized for multicast communications. Numerical results have been provided to validate the proposed performance evaluation and optimization approaches in the case of the MHARQ‐SC scheme. An important result devised here is that the reported analytical results clearly highlight the performance gain of the proposed strategy in comparison with all the other considered alternatives. Copyright © 2013 John Wiley & Sons, Ltd.     

Effect of lithium intercalation on the photovoltaic performances of photovoltachromic cells

In the last few years, a new class of smart multifunctional photoelectrochemical devices has been attracting the interest of several academic institutions and industrial companies: photovoltachromic cells, combining the features of photoelectrochromic cells with those of dye‐sensitized solar cells. Here, we report the results of a detailed electrochemical analysis aiming at investigating the electrochemical behavior of these complex photoelectrochemical devices. In particular, we have been focused on the effect of Li⁺ ions displacement during the coloration of the electrochromic tungsten oxide on the performances of the photovoltaic unit. As we had previously observed striking differences between the performances of the barely photovoltaic mode (with the tungsten oxide in the bleached state) and the photovoltachromic mode (with the tungsten oxide in the colored state), we thus attempted to provide a reasonable physical interpretation to the observed phenomena. Copyright © 2013 John Wiley & Sons, Ltd.     

The Roles of Coenzyme Q in Disease: Direct and Indirect Involvement in Cellular Functions

Coenzyme Q (CoQ) is a key component of the respiratory chain of all eukaryotic cells. Its function is closely related to mitochondrial respiration, where it acts as an electron transporter. However, the cellular functions of coenzyme Q are multiple: it is present in all cell membranes, limiting the toxic effect of free radicals, it is a component of LDL, it is involved in the aging process, and its deficiency is linked to several diseases. Recently, it has been proposed that coenzyme Q contributes to suppressing ferroptosis, a type of iron-dependent programmed cell death characterized by lipid peroxidation. In this review, we report the latest hypotheses and theories analyzing the multiple functions of coenzyme Q. The complete knowledge of the various cellular CoQ functions is essential to provide a rational basis for its possible therapeutic use, not only in diseases characterized by primary CoQ deficiency, but also in large number of diseases in which its secondary deficiency has been found.