Skin nanostructural features determine suture biomechanics

The stress state surrounding wounds in the skin plays an important role in the healing process; it affects the tissue strength, its aesthetic, and its resistance to infections. In this paper, the collagen fibril and elastin matrix damage mechanics following suture point application is investigated at the nanoscale; to this purpose, a model has been developed, which accounts for the architectural and mechanical features of the tissue components. Results indicate that the force displacement caused by the suture point application curve initially stiffens and subsequently softens. Softening occurs due at first to the enlargement of the elastin matrix damaged area and second to the collagen fibril disruption. Three regions may be identified: the first one, (0-0.38 N) refers to skin withstanding the force both in the collagen and elastin components; the second one (0.38-0.75 N) concerns the mechanism of elastin matrix damage; in the last one (>0.75 N), the collagen fibrils also fail. Accordingly, by properly choosing the number of suture points, it is possible to define the optimal suture points number for a given wound closure force.     

Distributed Belief Revision

In this paper, a distributed approach to belief revision is presented. It is conceived as a collective activity of a group of interacting agents, in which each component contributes with its own local beliefs. The integration of the different opinions is performed not by an external supervisor, but by the entire group through an election mechanism. Each agent exchanges information with the other components and uses a local belief revision mechanism to maintain its cognitive state consistent. We propose a model for local belief revision/integration based on what we called: Principle of Recoverability. Computationally, our way to belief revision consists of three steps acting on the symbolic part of the information, so as to deal with consistency and derivation, and two other steps working with the numerical weight of the information, so as to deal with uncertainty. In order to evaluate and compare the characteristics and performance of the centralized and of the distributed approaches, we made five different experiments simulating a simple society in which each agent is characterized by a degree of competence, communicates with some others, and revise its cognitive state. The results of these experiments are presented in the paper.     

A minimum-time control strategy for torque tracking in permanent magnet AC motor drives

A minimum-time torque control strategy for permanent-magnet AC motor drives is presented. The proposed technique neither requires the solution of a HJB-type equation, which would be practically unfeasible, nor uses Pontryagin's maximum principle. Instead, the solution is obtained by an ad hoc procedure based on the computation of reachability and controllability sets. In principle, the optimal control strategy can be carried out by iteratively solving a fourth-degree polynomial equation. For its efficient implementation, an algorithm based on Sturm sequences is suggested. The sequence of online operations required by the algorithm for a given tolerance on the optimal time is illustrated. The method has been tested on a laboratory prototype. Experimental results show the effectiveness of the technique.     

Dissimilar Resistance Spot Welding of Q&P and TWIP Steel Sheets

Dissimilar resistance spot welding of twinning induced plasticity (TWIP) and quenching and partitioning (Q&P) steel grades has been investigated by evaluating the effects of clamping force, welding current, and welding time on the microstructure, shear tension strength, and fracture of welded samples. The spot welding of TWIP and Q&P steels promotes the occurrence of an asymmetrical weld nugget with a greater dilution of TWIP steel because of its lower melting temperature and thermal conductivity. As a result, weld nuggets exhibit an austenitic microstructure. TWIP steel undergoes a grain coarsening in the HAZ, whereas Q&P steel undergoes some phase transformations. Welded samples tend to exhibit higher shear tension strength as they are joined at the highest welding current, even though an improper clamping force can promote excessive metal expulsion, thereby reducing the mechanical strength of the welded joints. Shear tension welded samples failed through interfacial fracture with partial thickness fracture mode for a low welding current, while partial thickness with button pull fractures were observed when a high welding current was used. The weld spots predominantly failed at the TWIP side. However, as TWIP steel can work harden significantly in the more resistant welded joints, the failures occur, instead, at the Q&P side.     

A new route to graphene starting from heavily ozonized fullerenes: Part 3 – an electron spin resonance study

It is shown that graphite oxide (GO) and both heavily ozonized C₆₀ and C₇₀ fullerenes, known as “fullerene ozopolymers,” are paramagnetic materials with a very strong electron spin resonance (ESR) signal at room temperature. When thermally annealed, the paramagnetic centers are gradually lost in large part. This occurs at 350°C in the case of GO, while for fullerene ozopolymers, a higher temperature is required, reaching the same results in the end. The half-width of ESR signal is linked to the distribution of paramagnetic centers. Once again, striking analogies were found in the half-width of the ESR signal measured on GO and fullerene ozopolymers, at least in the temperature range of 25–450°C. Similarly, the same g-factor values, which are diagnostic for understanding the chemical nature of paramagnetic centers, were found on both GO and fullerene ozopolymers in all ranges of temperature considered.     

Trends of night-time hourly cloud-cover values over Manila Observatory: ground-based remote-sensing observations using a digital camera for 13 months

ABSTRACT

Night-time cloud detection provides data sets of cloud-cover percentage. Although night-time cloud-cover data sets from satellite-based instruments are common, these data sets do not have relatively high temporal resolution. To quantify local temporal cloud-cover variability and to attain long-term cloud-cover measurements, ground-based instruments would be the appropriate apparatus. In this study, a digital camera is used to continuously gather images of the night sky at 5-min intervals over Manila Observatory (14.64° N, 121.07° E). For the first time in Manila, ground-based remote-sensing data gathered from October 2015 to October 2016 are analysed for hourly cloud cover. The results indicate that wet season has relatively higher cloud-cover values (median >40%) as compared to the dry season (median <40%). Moreover, cloud-cover values are observed to decrease during the night. For the wet season, August having the highest cloud-cover values has the highest value of change of hourly cloud-cover percentage (?0.82% h^?1). For the dry season, February having the lowest cloud-cover values has the highest value of change of hourly cloud-cover percentage (?1.04% h^?1).     

Polyynes Production in a Solvent-Submerged Electric Arc Between Graphite Electrodes. III. Chemical Reactivity and Stability Toward Air, Ozone, and Light

Since polyynes are easily accessible with the submerged electric arc synthesis between graphite electrodes, the chemical behavior of polyynes solutions in different solvents has been explored. It has been found that surprisingly the polyynes solutions, with polyynes having up to 16 carbon atoms arranged in a chain, are stable in air over 1 week time in the dark. These solutions react relatively slowly with ozone while add rapidly and completely bromine. The polyynes solutions are instead quite easily photolyzed under the action of UV radiation both in air and under N₂. Two different light sources were used in the study: a low pressure mercury lamp emitting almost a monochromatic radiation at 254 nm and an high pressure mercury lamp emitting in a broad wavelength range in the ultraviolet. With the former monochromatic light source, it has been demonstrated the possibility to perform a selective photolysis of selected polyynes in a mixture of homologous series.     

Structural Analogies and Differences Between Graphite Oxide and C60 and C70 Polymeric Oxides (Fullerene Ozopolymers)

A brief survey of the chemical structural analogies and differences between graphite oxide and fullerene ozopolymers or polymeric fullerene oxides (PFO) is presented. Graphite oxide is the product of oxidation of graphite prepared with strong oxidizing agents while PFO is the products formed by prolonged ozonation of C₆₀ or C₇₀ in solution. Notwithstanding the different starting substrates and oxidation conditions, elemental analyses, FT-IR spectroscopy and ¹³C-NMR spectroscopy suggest a very similar chemical structure for graphite oxide and PFO. A further analogy is the possibility to perform reduction or oxidation reactions on both substrates considered. Graphite oxide and PFO have also in common the ability to act as ion exchangers and as metal ion binders. Even the thermal behavior is comparable. However, X-ray powder diffraction has confirmed that graphite oxide still has a layered structure derived from graphite but with the graphene sheets at much bigger distance from each other due to the intercalation of oxidized groups and solvent molecules, while PFO do not show at all any sign of layered structure either from the X-ray spectra and also by its behavior in solution which is strikingly different from that shown by graphite oxide.