Synthesis and Processing of Graft Copolymers from Cornstarch and Methyl Acrylate: Physical and Mechanical Properties

Starch-g-poly(methyl acrylate) (S-g-PMA), containing 40-65% PMA, was prepared with ceric ammonium nitrate (CAN) initiation in a 2-gallon reactor. CAN initiator was added either in one portion or portionwise. Graft copolymers were characterized with respect to % acetone-extractable polymer (largely PMA homopolymer), PMA content of the graft copolymer, and M_w of PMA grafts. Normal cornstarch as well as waxy and high amylose cornstarches were used in the grafting reaction. Conversions of monomer to polymer were nearly quantitative. Continuous plastic ribbons for tensile testing were prepared by extrusion processing. Tensile properties varied with the method used for CAN addition (i. e., single portion vs. portion-wise) and depended upon the particular starch variety used in the graft polymerization reaction. Since water acts as a plasticizer for starch, samples extruded at high moisture content exhibit higher % elongation (%E) values than the same polymers extruded at low moisture. Values for %E also increase with higher percentages of PMA in the graft copolymer.     

A New Design Paradigm for Smart Windows: Photocurable Polymers for Quasi‐Solid Photoelectrochromic Devices with Excellent Long‐Term Stability under Real Outdoor Operating Conditions

A new photoelectrochromic device (PECD) is presented in this work proposing the combination of a WO₃‐based electrochromic device (ECD) and a polymer‐based dye‐sensitized solar cell (DSSC). In the newly designed architecture, a photocurable polymeric membrane is employed as quasi‐solid electrolyte for both the ECD and the DSSC. In addition, a photocurable fluoropolymeric system is incorporated as solution‐processable external protective thin coating film with easy‐cleaning and UV‐shielding functionalities. Such new polymer‐based device assembly is characterized by excellent device operation with improved photocoloration efficiency and switching ability compared with analogous PECDs based on standard liquid electrolyte systems. In addition, long‐term (>2100 h) stability tests under continuous exposure to real outdoor conditions reveal the remarkable performance stability of this new quasi‐solid PECD system, attributed to the protective action of the photocurable fluorinated coating that effectively prevents photochemical and physical degradation of the PECD components during operation. This first example of quasi‐solid PECD systems paves the way for a new generation of thermally, electrochemically, and photochemically stable polymer‐based PECDs, and provides for the first time a clear demonstration of their true potential as readily upscalable smart window components for energy‐saving buildings.     

2D van der Waals Heterojunction of Organic and Inorganic Monolayers for High Responsivity Phototransistors

Van der Waals (vdW) heterostructures composing of organic molecules with inorganic 2D crystals open the door to fabricate various promising hybrid devices. Here, a fully ordered organic self-assembled monolayer (SAM) to construct hybrid organic–inorganic vdW heterojunction phototransistors for highly sensitive light detection is used. The heterojunctions, formed by layering MoS₂ monolayer crystals onto organic [12-(benzo[b]benzo[4,5]thieno[2,3-d]thiophen-2-yl)dodecyl)]phosphonic acid SAM, are characterized by Raman and photoluminescence spectroscopy as well as Kelvin probe force microscopy. Remarkably, this vdW heterojunction transistor exhibits a superior photoresponsivity of 475 A W⁻¹ and enhanced external quantum efficiency of 1.45 × 10⁵%, as well as an extremely low dark photocurrent in the pA range. This work demonstrates that hybridizing SAM with 2D materials can be a promising strategy for fabricating diversified optoelectronic devices with unique properties.     

Selfishness in secure internet of things networks: 6TiSCH case study

Wireless Networks - Performance and communication security in the Internet of Things (IoT) area draw a major concern for both academic and industrial communities. Indeed, an emerging number of IoT...     

Mobile tele-echography: user interface design.

Ultrasound imaging allows the evaluation of the degree of emergency of a patient. However, in some instances, a well-trained sonographer is unavailable to perform such echography. To cope with this issue, the Mobile Tele-Echography Using an Ultralight Robot (OTELO) project aims to develop a fully integrated end-to-end mobile tele-echography system using an ultralight remote-controlled robot for population groups that are not served locally by medical experts. This paper focuses on the user interface of the OTELO system, consisting of the following parts: an ultrasound video transmission system providing real-time images of the scanned area, an audio/video conference to communicate with the paramedical assistant and with the patient, and a virtual-reality environment, providing visual and haptic feedback to the expert, while capturing the expert's hand movements. These movements are reproduced by the robot at the patient site while holding the ultrasound probe against the patient skin. In addition, the user interface includes an image processing facility for enhancing the received images and the possibility to include them into a database.     

Image registration using log-polar mappings for recovery of large-scale similarity and projective transformations.

This paper describes a novel technique to recover large similarity transformations (rotation/scale/translation) and moderate perspective deformations among image pairs. We introduce a hybrid algorithm that features log-polar mappings and nonlinear least squares optimization. The use of log-polar techniques in the spatial domain is introduced as a preprocessing module to recover large scale changes (e.g., at least four-fold) and arbitrary rotations. Although log-polar techniques are used in the Fourier-Mellin transform to accommodate rotation and scale in the frequency domain, its use in registering images subjected to very large scale changes has not yet been exploited in the spatial domain. In this paper, we demonstrate the superior performance of the log-polar transform in featureless image registration in the spatial domain. We achieve subpixel accuracy through the use of nonlinear least squares optimization. The registration process yields the eight parameters of the perspective transformation that best aligns the two input images. Extensive testing was performed on uncalibrated real images and an array of 10,000 image pairs with known transformations derived from the Corel Stock Photo Library of royalty-free photographic images.     

Probing stress effects in HfO2 gate stacks with time dependent measurements

Effects of constant voltage stress (CVS) on gate stacks consisting of an ALD HfO₂ dielectric with various interfacial layers were studied with time dependent sensing measurements: DC I–V, pulse I–V, and charge pumping (CP) at different frequencies. The process of injected electron trapping/de-trapping on pre-existing defects in the bulk of the high-κ film was found to constitute the major contribution to the time dependence of the threshold voltage (V_t) shift during stress. The trap generation observed with the low frequency CP measurements is suggested to occur within the interfacial oxide layer or the interfacial layer/high-κ interface, with only a minor effect on V_t.     

High‐Mobility ZnO Thin Film Transistors Based on Solution‐processed Hafnium Oxide Gate Dielectrics

The properties of metal oxides with high dielectric constant (k) are being extensively studied for use as gate dielectric alternatives to silicon dioxide (SiO₂). Despite their attractive properties, these high‐k dielectrics are usually manufactured using costly vacuum‐based techniques. In that respect, recent research has been focused on the development of alternative deposition methods based on solution‐processable metal oxides. Here, the application of the spray pyrolysis (SP) technique for processing high‐quality hafnium oxide (HfO₂) gate dielectrics and their implementation in thin film transistors employing spray‐coated zinc oxide (ZnO) semiconducting channels are reported. The films are studied by means of admittance spectroscopy, atomic force microscopy, X‐ray diffraction, UV–Visible absorption spectroscopy, FTIR, spectroscopic ellipsometry, and field‐effect measurements. Analyses reveal polycrystalline HfO₂ layers of monoclinic structure that exhibit wide band gap (≈5.7 eV), low roughness (≈0.8 nm), high dielectric constant (k ≈ 18.8), and high breakdown voltage (≈2.7 MV/cm). Thin film transistors based on HfO₂/ZnO stacks exhibit excellent electron transport characteristics with low operating voltages (≈6 V), high on/off current modulation ratio (～10⁷) and electron mobility in excess of 40 cm² V^?1 s^?1.     

Condition assessment of EPDM composite insulators using FTIRspectroscopy

Two new sampling and analysis techniques for assessing the condition of EPDM (ethylene-propylene diene monomer) composite insulators are presented. Polymer oxidation is assessed by removing small amounts of surface polymer by swabbing with xylene and analyzing this material by FTIR (Fourier transform infrared) emission spectroscopy. A measure of the amount of surface chalking is obtained by scraping a small amount of degraded surface material with a blade and analyzing by FTIR absorption spectroscopy. Numerical indices quantifying the amount of oxidation and surface chalking are obtained by calculating the ratios of absorption or emission peak heights in the infrared spectra. These indices are named the oxidation index and the chalking index. Three types of field-aged 275 kV EPDM composite insulators are investigated and the results from the new techniques compared with analyzes by XPS (X-ray photoelectron spectroscopy) with good agreement. It is found that for two types of insulator that the oxidation index is increased in regions near the HV conductor